学科分类
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54 个结果
  • 简介:ThenatureofbondinginthetitlecompoundshasbeenstudiedbyusingCASSCFandFOCItechniques.ThegroundstatesofPtCandPtNarefoundtobe1Σ+and2Πstatearisingprimarilyfrom:…1σ22σ21π41δ43σ2and…1σ22σ21π41δ43σ22π1configurationrespectivelyandbothofwhichformtriplebond(ones,twoπbonds),butthebondofPtCismuchstrongerthanthatofPtN.

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  • 简介:Theelevatedtemperaturetensileexperimentshavebeencarriedoutonthemagnesiumalloyandresultsindicatethatthemagnesiumalloyhasexcellentsuperplasticproperty.Gleebe-1500testingmachinewasusedinthediffusionbondingexperimentonthesuperplasticmagnesiumalloy.Then,theshearstrengthofthejointsunderdifferentconditionsisobtainedthroughsheartestingandtheoptimumprocessingparametersforthediffusionbondingareachieved.Bymetallurgicalmicroscopeandscanningelectronmicroscope(SEM),itisrevealedthatthemicromechanismofdiffusionbondingistheslideofgrainboundariescausedbythegrowthofgrainsandatomdiffusionofthesuperplasticmagnesiumalloy.

  • 标签: 超塑性镁合金 扩散结合 微观结构 剪切应力
  • 简介:Theinfluenceofsiliconsliceflatnessonbondingtechnologyandtherelationbetweenaforeignparticleandresultingbubblearequantitativelypresentedbytheelastictheory.ItisdemonstratedexperimentallybyX-raydoublecrystaldiffractometryandinfraredimager.

  • 标签: BONDING TECHNOLOGY SILICON material FLATNESS Double
  • 简介:TheZrcoatingwasdepositedontitaniumsurfaceusingthemagnetronsputteringtechnique.EffectsofZrcoatingonmicrostructureandmechanicalpropertiesofporcelainfiredtotitaniumhavebeeninvestigated.Theresultsshowthatinterdiffusionofelementsoccursduringporcelainfiring,andtheZrcoatingcaneffectivelyprotecttitaniumsurfacefromexcessoxidation.ThestrengthofbondzonewithZrcoatingdepositedfor1hourreaches29.7MPa,whichhasincreasedby26.4%ascomparedwiththatofbondzonewithoutcoating(23.5MPa).

  • 标签: 瓷器 锆涂层 焊接强度
  • 简介:Afteraconciseintroductionofhydrogenbondingeffectsinsolute-soluteandsolute-solventbonding,thedesignofpolymericadsorbentsbasedonhydrogenbonding,selectivityinadsorptionthroughhydrogenbonding,andcharacterizationofhydrogenbondinginadsorptionandseparationwerereviewedwith28references.

  • 标签: 聚合吸收剂 吸性 分离
  • 简介:Theceramicsettingbindersobtainedbymeansoftherawmixmechano-chemicalprocessing(mechanicaldispersionandchemicalinteractionprocessescombination),usedforbondingrefractoryconcretes,becomemoreavailablewithasubsequentincreasedinterestintheirpropertiesbecausetheydevelopinitialstrengthduringaheatupoftheunitswithin8-10h,incontrastto24hafterplacementforhighAl2O3cements(HAC).Thisstrengthdevelopmentenableshightemperatureprocessingunitstoberelinedwithminimumturnaroundtime,thusprovidingafavoredcost/performanceratio.Thepresentpaperidentifiesthepredominantphosphatephasesresponsiblefordevelopinggoodmechanical-strengthpropertiesofzirconiaandaluminaconcretesbondedwithmechano-chemicalbinders.Itsetsoutthecolloidandcrystallinephasesresultedfrominterphaseinteractionthatprovidethebasisforhighconcentratedbondingsuspensions(HCBS)technologyusefultotherefractoryindustry.

  • 标签: REFRACTORY concrete CERAMIC SETTING BINDER mechano-chemical
  • 简介:Thevacuumdiffusionbondingoftitaniumalloytotin-bronzehasbeenstudiedandthefeasibilityandappropriateprocessingparametershavebeeninvestigated.Themaximumtensilestrengthofthejointsis168MPa,andafirmjointisobtained.ThemicrostructureofdiffusionbondedjointhasbeenobservedbySEM.X-rayandEPMA,andthemainfactorsaffectingdiffusionbondinghavebeenanalyzed.TheintermetalliccompoundsTi2CuandTiCuwereformedneartheinterface.Thewidthandquantityoftheintermetalliccompoundincreaseswiththeincreaseofthebondingtime.Theformationoftheintermetalliccompoundsresultsinembrittlementofthejointandthepoorjointproperties.

  • 标签: 钛合金 锡青铜合金 扩散结合
  • 简介:在二固体之间的一个结合的接口上的非线性的边界条件一纵或砍水平嘘,在正常发生下面的波浪被探索。由使用秒顺序不安方法,非线性的春天模型严厉地在小厚度的限制被开发到波长比率。数字结果同意很好,准确答案由连续边界条件获得了。为纵的波浪的非线性的春天模型被测量钢或铝底层的楔形的结合结构的非线性验证。试验性的结果表明上述模型是相当精确的,当到粘合剂的adherend的阻抗比率增加,模型变得更精确。

  • 标签: 非线性边界条件 弹簧模型 粘接界面 实验 非线性弹簧 数值模拟
  • 简介:ThehydrogenbondpercentageanditstemperaturedependenceofthethreeTPUsamplessynthesizedfrompolytetrahydrofuran,4,4-diphenylmethanediisocyanate,N-methyldiethanolamineor1,4-butanediolwerestudiedbymeansofIRthermalanalysis.TheenthalpyandtheentropyofthehydrogenbonddissociationweredeterminedbytheVantHoffplot.

  • 标签: THERMOPLASTIC POLYURETHANE elastomers IR thermal analysis
  • 简介:Theadsorptionisothermsofcaffeinefromaqueoussolutionontothreehydrogendonatingadsorbents-hydroxypolystyrene,polystryene-azo-pyrogallol,andD72resin-weremeasured.TheadsorptionenthalpiescalculatedfromtheisothermsaccordingtotheClausisu-Clapeyronequationwere-24-36kJ/mol,-32-37kJ/mol,and-19-24kJ/molrespectively.Thesevaluesimpliedthattheadsorptionprocesseswerebasedonhydrogenbonding.Furthermore.themechanismoftheadsorptionofcaffeineontoD72resinwasstudiedbyIRspectraandthesmallmolecularmodelexperiments,andtheresultsshowedthattheadsorptionofcaffeineontohydrogendonatingadsorbentswasbasedonhydrogenbonding.

  • 标签: 吸附 咖啡因 氢键键合吸附剂
  • 简介:Twohydrogen-bondingadsorbents-macroporouscrosslinkedpoly(P-nitrostyrene)andpoly(p-vinylbenzylamide)-weresynthesized,andtheadsorptionpropertyofphenolfromcyclohexanesolutionontotheadsorbentswasstudied,ThedifferentialadsorptionheastsforvariedadsorptioncapacitiescalculatedfromtheadsorptionisothermsaccordingtotheClaperyron-Clausiusequationlayintherangeofhydrogenbondenergy(8-50kJ/mol),Theadsorptioncapaccityofo-nitrophenolincyclohexanewasmochlessthanthatofphenolunderthesamecondition.Theadsorptioncapacityofphenolfromcyclohexaneontopolyacrylonitrilewasmuchlessthanthatontopoly(p-nitrostyrene)orpoly(p-vinylbenzylamide),Alltheseresultsrevealedthatadsorptionofphenolfromcyclohexanebypoly(p-nitrostyrene)orpoly(p-vinylbenzylamide)isbasedonhydrogen-bonding.

  • 标签: 氢键键合吸会剂 苯乙醚 吸附
  • 简介:Factorsinfluencingbondingstrengthoflaminatedbamboostripslumber(LBSL)wereinvestigatedinthispaper.Inordertofindanoptimizedtechnology,thispaperinvestigatedhowthethicknessofbamboostrips,theassemblyorientationofbamboocurtain,thetypeofadhesives,aswellascouplingagenttreatmentofbamboocurtainaffectedthebondingstrength.Thefollowingconclusionsweredrawn:1)Thethinnerthethicknessofthebamboostrips,thebiggerthebondingstrengthofLBSL;2)Theassemblyor...

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  • 简介:BondingofAl2O3tocuisperformeddirectlyusingTifoilattemperatureof1273K.Themicrostructureofthejointinterfaceisinuestigatedthroughscanningelectronmicroscope(SEM),electron.probemicroanalysis(EPMA)andX-raydiffraction(XRD).theeffectoftheinitialtifoilthicknessonthereactionlayerthicknessandthejointStrengthareinvestigated.

  • 标签: ALUMINA active BRAZING INTERFACIAL reaction joint
  • 简介:Wehavestudiedtheelectronic,bondingandenergeticcharacteristicsoftheFe-Sibinarysystemusingthetight-bondingextendedHuckelmethod.AmongtheFe-Sibinarycompounds,FeSihasthemostsymmetricgeometricarrangementinthecrystalstructure.Italsopossessesthelargestcohesiveenergyperatom.ThiscorrelatestothefactthatFeSiisthemoststablecongruently-meltingcompoundinthebulkphasediagram.Anestimateofinteractionenergiesbetweendifferentatomsisalsogiven.

  • 标签: FE-SI BINARY system BONDING EXTENDED Huckel
  • 简介:Possibilitiesforenhancementofcatalyticreactionratebycombiningphasetransfercatalysisandhydrogenbondingofthecatalystwiththesubstrateandreagentwerestudied.Aphasetransfercatalystlibrarywithsixtypolystyrene-supportedquaternaryammoniumsaltcatalystswassynthesized.ThereductionofacetophenonebyNaBH4wasusedastheprobingreactiontoselectouttheostactivecatalystinthelibrarybyusingiterativemethod.whichwasthegel-typetriethanolamineaminsatingstronglyasicanionexchangeresinwiththecrosslinkingdegereeof2%Ahydrogenbondingassistedcatalyticmechanismwasproposedtoexplainthehighcatalyticactivityofthecatalyst.

  • 标签: 离子交换树脂 相变 晶体 组合化学
  • 简介:Theliquid-filmsolution-diffusionbondingofZCuBe2.5alloyswasconductedusingCu-basedalloypowders.Thetensilestrengthofthebondingtimedecreasesandtheinterfacemigrationvelocityincreasesbondingtime,thethicknessofdiffusionlayerincreaseswiththeincreaseoftemperaturegradient,andthistendencybecomesmoreremarkablewiththeprolongingofbondingtime.

  • 标签: 扩散焊接 温度梯度 压焊时间 液态膜 铜合金
  • 简介:Thebondingofsteelplatetoaluminumliquidwasconductedusingrapidsolidification.Theinfluenceofdiffusiontimeoninterfacialstructurewasstudied.Theresultsshowedthatundertheconditionof750℃forthetemperatureofaluminumliquidand200℃forthepreheattemperatureofsteelplate,whendiffusiontimewasshorterthan4.3s,therewasonlyFe-Alsolidsolutionattheinterface.Whendiffusiontimewaslongerthan4.3s,Fe-Alcompoundbegantoformattheinterface.TherelationshipsbetweendiffusiontimetandthicknessofFe-AlcompoundlayerHareH=-9.72+2.62t-0.08t^2(4.3s≤t≤15s)andH=2.79+0.647t=0.033t^2(t>15s).

  • 标签: 焊接 快速凝固 结构 扩散时间