Twohydrogen-bondingadsorbents-macroporouscrosslinkedpoly(P-nitrostyrene)andpoly(p-vinylbenzylamide)-weresynthesized,andtheadsorptionpropertyofphenolfromcyclohexanesolutionontotheadsorbentswasstudied,ThedifferentialadsorptionheastsforvariedadsorptioncapacitiescalculatedfromtheadsorptionisothermsaccordingtotheClaperyron-Clausiusequationlayintherangeofhydrogenbondenergy(8-50kJ/mol),Theadsorptioncapaccityofo-nitrophenolincyclohexanewasmochlessthanthatofphenolunderthesamecondition.Theadsorptioncapacityofphenolfromcyclohexaneontopolyacrylonitrilewasmuchlessthanthatontopoly(p-nitrostyrene)orpoly(p-vinylbenzylamide),Alltheseresultsrevealedthatadsorptionofphenolfromcyclohexanebypoly(p-nitrostyrene)orpoly(p-vinylbenzylamide)isbasedonhydrogen-bonding.