简介:Surfaceeffectsonthepersistencelengthofquasi-one-dimensionalnanomaterialsareinvestigatedbyusingthetheoryofsurfaceelasticityandthecore–shellmodelofnanobeams.Asimpleandunifiedexpressionisprovidedtodeterminethepersistencelengthofnanowiresandnanotubeswithanyregularpolygonalcross-sections.Itisdemonstratedthatsurfaceeffectshaveadistinctinfluenceonthepersistencelengthwhenthecharacteristicsizesofmaterialsshrinktonanometers.Thisworkishelpfulnotonlyforunderstandingthesize-dependentbehaviorofnanomaterialsbutalsoforthedesignofdevicesbasedonnanotubesornanowires.
简介:Amicrofluidicsystemwasdevelopedforthesynthesisoftrigonalselenium(t-Se)nanowires,whichwascomposedofaglassmicrochipcoupledwithapoly(methylmethacrylate)(PMMA)microchip.Intheglassmicrochip,amorphousselenium(a-Se)colloidwaspreparedbyreducingseleniousacidwithanexcessamountofhydrazineatatemperatureof100℃.InthecoupledPMMAmicrochip,a-Sewastransformedintomorestablet-Seseedsviasonicationatroomtemperature.Theresidencetimeofthereactantsinbothmicrochipswasoptimizedbyvaryingthedimensionandlengthofthemicrochanneleach.Thet-Senanowireswereformedbyanisotropicgrowthofseleniumcrystalliteduringsonicationandagingundertheassistanceofβ-cyclodextrin(β-CD).Variousstagesofthenanowires'growthwereinvestigated.Theas-synthesizedproductswerecharacterizedbypowderX-Raydiffraction(XRD),Ramanspectroscopy,scanningelectronmicroscopy(SEM),transmissionelectronmicroscopy(TEM)andselected-areaelectrondiffraction(SAED).
简介:ThemagnetizationreversalmechanismsforNinanowireswithdifferentdiameterswereinvestigatedbymi-cromagneticsimulations.Theresultsshowthatthereversalmechanismsaresignificantlydependentonthediameterofwire.Forverythinwires,thereversaloccursbypseudo-coherentrotation.Withincreasingdiam-eter,magnetizationreversaltakesplaceviadifferentnucleation(thetransversedomainwallandthevortexdomainwall)andsubsequentpropagation.Thereasonoftransitionfromthetransversedomainwalltothevortexdomainwallisgivenbyanalyticalstudies.Withfurtherincreaseofthediameter,thereversalnucleardomainwallbecomestundish-shapedform.Asthediameterincreases,thewidthofwallbecomeslarger.
简介:这研究的目的是用作为矩阵树脂作为传导性的fillers和修改环氧基树脂的organosilicone树脂经由solvothermal方法准备的银nanowires开发传导性的粘合剂。电的传导性的粘合剂和机械性质上的银nanowires/flakes的增加的效果被调查。与有银薄片fillers的常规传导性的粘合剂相比,有银nanowiresfillers的传导性的粘合剂的过滤阀值是10?%近似降低。然而,银nanowires的内容的进一步的上升没在传导性的粘合剂的电的传导性的改进上有明显的影响。传导性的粘合剂的传导性、机械的性质能由增加银nanowires是兼容的,哪个传统的银传导性的粘合剂reach.Graphical不能提炼银nanowires,舒适形态学经由alcohothermal准备了方法被介绍进传导性的粘合剂作文。它能被发现尽管存在,发现银nanowires在传导性的粘合剂相当被重叠crosslinking到某程度,然而,银nanowires不出现凝块的现象。有传导性的fillers能展出有利电、机械的性质的银nanowires的传导性的粘合剂。
简介:传导性的Au-biopolymercomposites在象神经织物那样的织物工程有有希望的应用新生。在这研究,丝绸丝心蛋白nanofibers被调整丝绸在水的答案形成自己组装进程然后为Aunanowire用作模板制造。我们由重复播种周期执行了Au种子的合成因为若干次Au的密度在nanofibers上播种以便增加。在无电的plating以后,浓密地装饰了种子种了进跟随丝绸nanofiber充满在粒子之间的差距并且最后形成一致连续nanowires的不规则地塑造的粒子的Au。Au丝绸丝心蛋白nanowires的传导性的性质被学习与当前电压(IV)测量。典型欧姆的行为被观察,它在神经织物新生加亮他们的潜在的应用。
简介:Waveguidingpropertiesofsilicananowiresinvariousenvironmentsarestudiedbysolvingtheeigenvalueequationsofacircularcross-sectionwaveguidenumericallyincylindricalcoordinates.Thesingle-modecondition,propagationconstants,poyntingvectorandpowerdistributioninsideandoutsidesilicananowirearecalculated.Theresultsshowthatsilicananowiresinwater,comparedwithsilicananowiresinair,havehigherfractionoftheevanescentfields.Duetothesensitivitytosurroundingenvironment,silicananowiresareverysuitableforsensingelements,whichcanbeusedtoimplementasingle-modefiberopticevanescentwavesensingelementofhighlysensitiveandaccuratemeasurement.
简介:Thisstudydemonstratesanovelapproachforrapidsynthesisofsilver(Ag)nanowiresinducedbyvanadiumtrioxide(V2O3)particlesinaqueoussolutionatroomtemperature.Silvernanowireshaveanaveragediameterof20nmandlengthuptoafewmicrometersbyparametricoptimization.ThemicrostructureofthesilvernanowireswascharacterizedbyTEM,HRTEM,SEM,andXRDtechniques.Theopticalpropertyoftheas-preparedproductwasmeasuredbyultraviolet-visible(UV-vis)spectroscopy.ThepossiblegrowthmechanismofAgnanowiresviaorientedattachmentofAgnanocrystalswasdiscussed.Thepresentapproachshowsseveraluniquefeaturessuchasrapid(afewminutes),reproducibleandhigh-yieldreactionwithnoneedofanymodifiers.V2O3rodswerereportedforthefirsttimetobeusedforsynthesisofsilvernanowires,playingmultiplerolesasreducingagent,template,andcatalyst.Thesilvernanowiresproducedarepromisingforopticalapplications(e.g.,SERS)duetotheirroughsurface.
简介:Nanowireshavebeenprovedtobeexcellentcandidatesforfuturenanodevicesfortheiradvantagesofbeingthesmallestchargecarrier,enablingabundantchoiceofmaterials,andrelatedsize,surfaceandquantumeffects.Nanowiresthusplayimportantroletounderstandthephysicalphenomenabetweenmacro-scaleNewtonworldandthemicro-scalequantummechanicalworld.Ourgroupisamongthefewpioneersinearly1998'sindevelopingmethodsforsynthesisofsiliconnanowires,andextendingthenanowiresynt...
简介:Silvernanowires(AgNWs)withdiameterof90--150nmandlengthof20--50μmweresuccessfullysynthesizedbyapolyolprocess.Grapheneoxide(GO)waspreparedbyHummersmethod,andwasreducedwithstronghydrazinehy-drateatroomtemperature.Theflexibletransparentconductivefilms(TCFs)werefabricatedusingthemixedcelluloseeater(MCE)asmatrixandAgNWsandreducedgrapheneoxide(rGO)asconductivefillersbytheimprovedvacuumfiltrationprocess.Then,theoptical,electricalandmechanicalpropertiesoftheAgNWs-rGOfilmswereinvestigated.TheresultsshowthatfortheAgNWs-rGOfilmproducedwiththedepositiondensitiesofAgNWsandrGOas110mg.m2and55mg·m^-2,theopticaltransmissionat550nmis88.4%withRsaround891Ω·sql,whereastheopti-caltransmissionfortheAgNWs-rGOfilmwithdepositiondensitiesofAgNWsandrGOof385mg·m^-2and55mg·m^-2is79.0%at550nmwithRsaround9.6Ω·sql.ThereislittleovertincreaseinRsoftheAgNWS-rGOfilmaftertapetestsfor200times.ThebendingtestresultsindicatethatthechangeinRsofAgNWs-MCEfilmislessthan2%evenafter200cyclesofcompressiveortensilebending.TheexcellentmechanicalpropertiesoftheAgNWs-rGOfilmcanbeattributedtotheburyingofAgNWsandrGOatthesurfaceofMCE.
简介:Magnesiumoxide(MgO)nanowiresweresynthesizedonthegold-coatedSi(100)andMgO(100)substratesatlowertemperature(600℃)bypulsedliquidinjectionmetalorganicchemicalvapordeposition(MOCVD).Thegoldcatalystcouldbefoundonthetipsofnanowires,whichpresentsthevapor-liquid-solid(VLS)growthmechanism.Reactivespecies(oxygenormagnesium)havestrongeffectsonthegrowthofnanowires.Abundantreactivespecieskilltheverticallyalignednanowirestoberandomlyalignedonesorevenchangetheverticalgrowthmodetothehorizontalgrowthmodewithsurface-parallelnanowires.Usually,nanowireswithlargeraspectratio(>10,aspectratio=length/diameter),higherdensity(>500/μm2)andsmallerdiameter(≤20nm)canbeeasilysynthesizedwithlongerinjectionperiod(≥2s),smallerinjectionmass/period(≤4.6mg)andsuitableoxygenpartialpressure(2.4Torr).
简介:Afacilecatalysis-freemethodwasutilizedtosynthesizefunctionalneodymiumhexaboride(NdB6)nanowiresofsinglecrystalusingNdpowdersandBCl3asstartingmaterials.TheXRDpatternconfirmedthatasinglephaseNdB6couldbeobtained.Raman-spectraelucidatedtheactivevibrationalmodesofthehexaborides.TheTEMimagesclearlyshowedthatthehexaboridesweresubmicroninsizewithacubicmorphology.Thefieldemissionoftheseone-dimensionalNdB6nanowiresshowedalowfieldemissionturn-on(5.55V/μmatacurrentdensityof10μA/cm2),andhighcurrentdensitywithafieldenhancementfactorof1037.TheemissioncurrentdensityandtheelectricfieldfollowedtheFowler-Nordheim(F-N)relationship.Thegoodperformanceforfieldemissionwasattributedtothesingle-crystallinestructureandthenanowiregeometry.
简介:ZnOnanowiresdepositedonSisubstrateswerepreparedbythermalevaporationofamixtureofZnOandcarbonpowder.Agionswithanenergyof63keVandadoseof5×1015ions/cm-2wereimplantedintotheas-preparedZnOnanowires.Afterionimplantation,theAg-implantedZnOnanowireswereannealedinairatdifferenttemperaturesfrom600℃to1000℃.Effectsofionimplantationandthermalannealingonthestructuralandphotoluminescent(PL)propertiesoftheZnOnanowireswereinvestigatedbytransmissionelectronmicroscopy(TEM),selectedareaenergydispersiveX-rayspectroscopy(SAEDX),X-raydiffraction(XRD),andfluorescencespectrophotometry.TEM,HR-TEM,andSAEDXanalysesdemonstratedthatefficientdopingofAgwasachievedbyionimplantationandthesubsequentannealingprocess.XRDpatternsrevealedthatthehexagonalwurtzitestructureofZnOnanowireswasmaintainedafterionimplantation.PhotoluminescentemissionsofZnOnanowiresweredecreasedsignificantlybyAgimplantationbutcouldberecoveredbythermalannealing.ThemechanismoftheinfluenceofionimplantationandannealingonthePLintensitywasassessed.
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简介:Recently,theirradiationeffectsinnanomaterialshavebeenahottopicinnanoscience.Althoughirradiationinduceddamageshavebeenstudyingforalongtime,verylimitedresearchhasbeenperformedonthedamagesinducedbyMeV-energyheavyionsingoldnanowires(NWs).Inthiswork,wereportastudyoftheirradiationeffectsonsinglecrystallinegoldNWs,whicharefabricatedelectrochemicallyintheetchediontracktemplates.Theas-preparedgoldNWsontheAu/CusubstratewerecharacterizedbySEMafterdissolvingthepolycarbonate(PC)template,asshowninFig.1(a).GoldNWswithdiametersfrom20to90nmwerefabricatedtostudythesizedependenceofirradiationdamageinducedbytheheavyions.ToguaranteethatthedifferentNWscouldobtainthesameirradiationfluence,theNWswithdifferentdiametersweremixedtogetherandtransferredtotheTEMgrid,asshowninFig.1(b).