简介:SiliconoxynitridewasaddedinshapedAl2O3-SiC-Crefractorymaterialtoimprovetheslagresistanceinthispaper.Optimumaddingquantityofsiliconoxynitridepowderwasalsostudied.TheresultsshowthattheslagresistanceofAl2O3-SiC-Cshapedrefractoryisimprovedwhen2%or3%Si2N2Oisadded.AreasonableamountofSi2N2OaddedintoAl2O3-SiC-Cshapedrefractorycanproducesiliconoxideintotheslag,whichcanimprovetheviscosityofslagandpreventtheslagerosionandpenetration.
简介:Thecorrosionofrefractoriesresultsfromreactivetransport,namely,transportofagentsandchemicalreactionsoftheseagentswithimpregnatedmedium.Ononehand,thetransportinvolveseitherdiffusionorimpregnationdependingonthestateofthecorrosiveagentsandthemicrostructureofthehostmedia.Ontheotherhand,chemicalreactionsmaybeverynumerousandcomplex.ThisstudyfocusedonthereactiveimpregnationofAl2O3-CaOslagintoporoushighaluminarefractory.Thetransportpropertiesoftherefractorymaterialwereidentifiedbymeansofadedicatedcapillaryrisingtest.ChemicalreactionsbetweenthesolidhighaluminaskeletonandAl2O3-CaOslaginvolvesuccessivedissolution/precipitationmechanismsformingaluminatesoflime.Contrarytothethermodynamicpropertiesofthebinarysystem,thekineticsofthesesolid/liquidreactionsisnotwellknown.Corrosiontestsassociatedwiththequenchingmethod,XRDanalyseswereperformedforabetterunderstandingofthekinetics.Theresultsofthisstudyopenupacouplingapproachforpredictingthecorrosionwearofrefractory.
简介:InordertoimprovethemechanicalpropertiesofSiO2aerogel-glassfibercomposites,effectsofdifferentsolvents(cyclohexane,n-hexane,ethanol,acetone)anddifferentdispersingmodes(planetaryballmilling,ultrasonicdispersionandmechanicalstirring)anddispersingduration(10-40min)onthedispersionofchoppedalkali-freeglassfiberbundleswerestudiedtodeterminethebestdispersionprocess.Onthisbasis,thematerialswerebatchedaccordingtothemassfractionofSiO2aerogelpowdertochoppedalkalifreeglassfiberbundlesof90:10,andacertainamountofzincoxidelight-screeningagentandphenolicresinbinderwereadded.SiO2aerogelglassfibercompositespecimenswerepreparedbydirectaddingchoppedalkalifreeglassfiberbundlesandpre-dispersedchoppedalkalifreeglassfiberbundles,respectively.Thecoldcrushingstrengthandthethermalconductivityatdifferentsurfacetemperatures(300,400,500and600℃,respectively)ofthespecimensweremeasured.Theresultsshowthat:(1)theoptimumdispersionprocessofchoppedalkali-freeglassfiberbundlesisusingethanolassolventandmechanicalstirringfor30min;(2)pre-dispersionofchoppedalkali-freeglassfiberbundleshaslittleeffectonthethermalconductivityofSiO2aerogel-glassfibercompositesbutcanimprovethecoldcrushingstrength.
简介: