简介:Self-lubricatingcoatingshavebeenwidelyusedtoreducefrictioninmovingmachineassemblies.However,thetribologicalperformanceofthesecoatingsisstronglydependentontheservicetemperature.Inthispaper,anextensivereviewpertainingtotheinfluenceofoperatingservicetemperatureontribologicalperformanceofself-lubricatingcoatingshasbeencarriedout.Basedontheeffectivelubricatingtemperaturerange,theself-lubricatingcoatingsdevelopedinthepasthavebeendividedintothreegroups:lowtemperaturelubricantcoating(from-200℃toroomtemperature),moderatetemperaturelubricantcoating(fromroomtemperatureto500℃)andhightemperaturelubricantcoating(〉500℃).Ideasconcerningpossiblewaystoextendtheoperatingtemperaturerangeofself-lubricatingcoatingshavebeenpresentedasfollows:hybridizedtribologicalcoating,adaptivetribologicalcoatings,anddiffusionratelimitedsolidlubricantcoating,inaddition,anewself-lubricatingcoatingformulationforpotentialapplicationatawideoperatingtemperaturerangehasbeenproposed.
简介:Thetechnologyofactivationbyaddingfewactivators(<1%)toincreasetheamountofblendsincementwasinvestigated.Theresultsshowthatouteractiva-tionhasaremarkableeffectonimprovingthephysicalpropertiesofslagcement,flyashcementandvolcaniccement.Forexample,thecompressivestrengthwasincreasedby5-10MPa.Morever,theapplicationofactivationisbeneficialtogrind-aiding,earlystrengthandwater-reducingetc.
简介:钛氧化物(TiO2)上的Ag簇的形成nanoparticles被完成由selfassembly过程和锻烧。获得的nanoparticles被X光检查描绘衍射(XRD),传播电子显微镜学(TEM),和紫外可见光谱学(紫外力),并且常规技术(XRD,TEM并且紫外力)被用来在TiO2表面上识别Ag粒子。结果证明Ag-TiO2粒子能被使用改进苯乙烯氧化物的epoxidation的催化活动。苯乙烯氧化物作为由把Ag-TiO2nanoparticles用作催化剂的氧化剂是有H2O2的催化反应的主要产品。苯乙烯氧化物的高催化的activitity能在80el是可获得的被锻烧在1000
简介:Byanalogueexperimentofexhaustgas,thesensitivecharacteristicsoftitaniatoair/fuelratiowasinvestigated.Theeffectsofsomeimpuri-tiesontheelectricconductivityofTiO2,thedeviationof(A/F)cfrom(A/F)sinnonequilibriumgassystemandtheself-catalyticoxidationofTiO2wereexplainedrespectively.Theeffectsofca-talyst,porosityandthicknessofsensorelementontheresponsetimewasalsoanalyzed.
简介:Themoisturetransportincrackedcement-basedmaterialswasinvestigatedwithprioritybynumericalsimulation.Thecrackedcement-basismaterialwastreatedastwocomponentssystem,includingthecracksandcementitiousmortar.Themassbalancebetweenthewaterinthecracksandinthecementmortarwasconsidered.Fromthemodelingresults,itwasseenthatthewaterorvaporfilledthecrackimmediatelywhenthecrackedcementitiousmortarwasputintocontactwiththewaterorvapor.Thewater/vaporpenetratesintothemortarfromthecracksurfaces,aswellastheexternalsurfaceexposedintheoutsidecondition.Theexistenceofcracksincreasesthepenetrationofwater/vaporintothecementitiousmortar.Asthebasisforstudyingtheself-healingincrackedconcrete,thesimulationonmoisturetransportprovidedimportantinformationaboutthewaterdistributionandmovementinsidethecrackedconcrete.
简介:LeachingexperimentsonmetakaolinshowthatthefinalAlextractionratioreachedinabatchreactionisstrikinglyinfluencedbytheinferiorporestructuregeometryofthemetakaolinpellets.Bycalciningkaolinparticlesadheredinlowhumiditystate,avarietyofmetakaolinpellet,insidewhichalargeopeningsstructuredeveloped,hasbeenprepared.Thestructureremarkablybenefitsleachantiontransference,so,thevarietyhashighacidleachingreactivity,evencoarseasthepelletsare,itsaluminumextractedratiostillhasalinearrelationshipwithleachingtime,andtheleachingkineticsismaintainedzeroorderuptoasignificantconversiondegree.ArevisedPellet-ParticleModelhasbeendevelopedtointerpretthestructureinfluenceonAlextractionratio.
简介:Inthispaperforsavingenergytwodifferentburningmethodsofcementclinkerformationhavebeenstudied.Oneistherapidburningmethodandtheotherisordinaryburningmethodsimulatingrotarykiln,andtheyarecomparedbythekineticpointofview.Theresultrevealsthattheactivationenergyofrapidburningismuchlowerthanordinaryburning.Forlookingintothecause,themainrawmaterial—limestonewasburntbythesametwomethodsandthestructureofproductCaOhasbeendetected.ItcanbefoundthatthemicrostructureofCaOproducedbyrapidburningislooser;latticesconstantsaregreater;crystaldefectsaremoreandparticlesizeissmallerthanthatproducedbyordinaryburning.Thesecausethechemicalreactionmoreactive.Sotheactivationenergyofclinkerformationofrapidburningismuchlowerthanthatoftheordinaryburning.
简介:Inthiswork,compressive,flexuralandsplittensilestrengthtogetherwithcoefficientofwaterabsorptionofhighperformanceself-compactingconcretecontainingdifferentamountofFe2O3nanoparticleshavebeeninvestigated.ThestrengthandthewaterpermeabilityofthespecimenshavebeenimprovedbyaddingFe2O3nanoparticlesinthecementpasteupto4.0wt%.Fe2O3nanoparticleasaforeignnucleationsitecouldaccelerateC-S-HgelformationasaresultofincreasedcrystallineCa(OH)2amountespeciallyattheearlyageofhydrationandhenceincreasethestrengthofthespecimens.Inaddition,Fe2O3nanoparticlesareabletoactasnanofillersandrecovertheporestructureofthespecimensbydecreasingharmfulporestoimprovethewaterpermeability.Severalempiricalrelationshavebeenpresentedtopredicttheflexuralandthesplittensilestrengthofthespecimensbymeansofthecorrespondingcompressivestrengthatacertainageofcuring.Acceleratedpeakappearanceinconductioncalorimetrytests,moreweightlossinthermogravimetricanalysisandmorerapidappearanceofpeaksrelatedtohydratedproductsinX-raydiffractionresultsindicatethatFe2O3nanoparticlesupto4wt%couldimprovethemechanicalandthephysicalpropertiesofthespecimens.
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