简介:ThispaperreportstheuseofAufilmstoimprovetheperformanceofthestackedsolidoxidefuelcell(SOFC)basedonthecharacterizationoftheinterfaceandtheadhesionbetweentheelectrodesoftheSOFCsandtheAgpaste.Thespecimensweremanufacturedtoperformtheexperimentasfollows.ASiO2waferwitha300mmnotchwasattachedtotheelectrodesofaSOFCbyaAgpasteandAufilm,whichweredepositedontheelectrodesbysputteringfor1minor5mindepositiontimeandannealedat300Cfor1h.Thefour-pointbendingtestwasperformed,whichresultedintheformationofanextendedcrackatthetiponthewafernotch,andthecrackpropagationwasobservedusingastereomicroscopeequippedwithacharge-coupleddevice(CCD).Consequently,theinterfacialadhesionenergyandtheeffectoftheAufilmbetweentheeachelectrodeandtheAgpastecanbeevaluated.Onthecathode,theinterfacialadhesionenergywithoutAufilmwas2.59J/m2(uppervalue)andtheadhesionenergyincreasedto11.59J/m2(uppervalue)and15.89J/m2(lowervalue)withtheAufilm.Ontheanode,theinterfacialadhesionenergywithoutAufilmwas1.74J/m2(uppervalue),whichincreasedto11.07J/m2(uppervalue)and14.74J/m2(lowervalue)withtheAufilm.Inaddition,theinterfaceareaswereanalyzedbyscanningelectronmicroscopy(SEM)andenergydispersivespectroscopy(EDS)toestimatetheinterfacedelamination.
简介:Itisawellknownfactthatmagnaticcryoto-explosion,asaspeeialformofmagmatismunderthenear-surfacecondition,hasacloseconncctionwithcdogcnicmctaldcposits,particularlywiththoseofporphyrytyPe,suchaSporphyryCu-Mo,Pb-Zn,W-SnandUdcposits’However,onlyinrcccntyearsbavetheChineseoregeologistsandpetrologistsgivenin
简介:Ithaslongbeenacontroversyaboutthesourceofore-formingmaterialsofAu-Agpolymetallicdepositsbothinmetallogenictheoryandinore-searchingpractice.IntermsofalargewealthoftheisotopicstatisticsdatafromIndosinian-YanshanianendogenicoredepositsinnorthernHebei(generallyreferringtotheareasalongthenorthernpartofTaihangMountainsandnorthernHebei,thesamebelow),itisconsideredthattheore-formingmaterialscamefromthedeepinterioroftheEarth,whichhadmigratedthroughplumestotheEarthsurfacewhileex-periencedmulti-stageevolutionandthenemplacedprogressivelyinfavorablestructurallocitoformores.Theirisotopedatashowthat559sulfurisotopicdatafrom40oredepositsare,forthemostpart,withintherangeof-5‰-5‰,withahighdegreeofhomogenization,indicatingthatthesulfurisderivedmainlyfrommagma;200leadisotopedatafrom37oredepositsindi-catethattheore-formingmaterialsareprincipallyofmantlesourcethoughsomecrust-sourcema-terialwasinvolved;96oxygen,hydrogenandcarbonisotopedatafrom34oredepositsillustratethattheore-formingfluidsaredominatedbymagmaticwaterwhileothersourcesofwaterwouldbeinvolved.Itmaythereforebeseenthattheformationofendogenicdepositshasnothingtodowiththestrata.
简介:本文利用XRF金标样的多元素回归方程,对Pt、Pd的荧光强度进行修正,修正后的荧光强度当作Au、Ag的荧光强度代入回归方程中,利用计算机编程计算铂制品中的Pt、Au、Pd、Ag、Cu、Ni等6种元素的含量.该法测定的准确度优于0.5%,适用于Pt的测定范围为85%~99.92%,具有无损、快速、准确、可靠等优点.
简介:CrystallineTiO2(P25)andisolatedtitanatespeciesinaZSM-5structure(TS-1)weremodifiedwithAuandAg,respectively,andtestedinthegas-phasephotocatalyticCO2reductionunderhighpurityconditions.Thenoblemetalmodificationwasperformedbyphotodeposition.LightabsorbancepropertiesofthecatalystsareexaminedwithUV–Visspectroscopybeforeandaftertheactivitytest.Inthegas-phasephotocatalyticCO2reduction,itwasobservedthatthecatalystswithAgnanostructuresaremoreactivethanthosewithAunanostructures.Itisthusfoundthattheenergeticdifferencebetweenthebandgapenergyofthesemiconductorandthepositionoftheplasmonisinfluencingthephotocatalyticactivity.Potentially,plasmonexcitationduetovisiblelightabsorptionresultsinplasmonresonanceenergy,whichaffectstheexcitationofthesemiconductorpositively.Therefore,anoverlapbetweenbandgapenergyofthesemiconductorandmetalplasmonisneeded.
简介:Strongearthquakeactivityalovertheworldandstrong┐moderateearthquakeactivitywithinandnearChina(June~August,1995)PEI-SHANCHEN(陈培...
简介:Tadpole-shapedAunano-particleswithcontrollabletailsaresuccessfullyfabricatedbysimplyusinglaserfragmentationofseparatedAunano-spheresinliquid.Theoptimumlaserpowerdensities(1.5–3GW∕cm~2)canenablepartoftheindividualAunano-spheretobere-melted,released,andultra-rapidlyrecondensed/crystallizedontheoutsideoftheoriginalregion.Wefindthatthelengthofthetailinatadpole-shapedAunano-particlesignificantlyincreasesfromabout10to25nmbyincreasingthelaserpowerdensity.Benefitingfromtheuniquestructuralfeatures,thelocalizedsurfaceplasmonresonance(LSPR)absorptionspectraofthetadpole-shapedAunano-particlesbecomebroaderbyincreasingthetaillength.Moreover,theLSPRabsorptionbandalsoexhibitsanoticeableredshiftfromabout520to650nm.Ourresultsprovideaconvenientandvaluablestrategytofabricatednovelanisotropic-shapednano-structureswithfascinatingproperties.
简介:Quartzcrystalmicrobalance(QCM)andcyclicvoltammetry(CV)wereusedtocharacterizethemonolayerofcytochromec(Cytc),whichwasadsorbedongoldfilmmodifiedwithalkanethiolmixedmonolayer.AdirectcomparisonofproteinsurfacecoveragescalculatedfromQCMandcyclicvoltammetricmeasurementsillustratesthattheratiooftheelectroactiveCytctothetotalsurface-confinedCytcis34%,whichsuggeststhattheorientationisamainfactoraffectingtheelectroactivityofCytc.Moreover,surfaceplasmonresonance(SPR)measurementcombinedwithCV'insitu'wasusedtoinvestigatetheconformationalchangeofCytcintheredoxprocess.Besides,Aunanoparticles(AuNPs)wereadsorbedonthesurfaceofCytc.TheresultindicatesthatAuNPspromoteelectrontransferbetweenCytcandthegoldelectrode,andSPRresultsuggestsAuNPsenhanceSPRsignal.
简介:传导性的Au-biopolymercomposites在象神经织物那样的织物工程有有希望的应用新生。在这研究,丝绸丝心蛋白nanofibers被调整丝绸在水的答案形成自己组装进程然后为Aunanowire用作模板制造。我们由重复播种周期执行了Au种子的合成因为若干次Au的密度在nanofibers上播种以便增加。在无电的plating以后,浓密地装饰了种子种了进跟随丝绸nanofiber充满在粒子之间的差距并且最后形成一致连续nanowires的不规则地塑造的粒子的Au。Au丝绸丝心蛋白nanowires的传导性的性质被学习与当前电压(IV)测量。典型欧姆的行为被观察,它在神经织物新生加亮他们的潜在的应用。
简介:摘要NPS新生产技术又称为精益生产模式。该生产模式由于先进的理念,以及丰富的生产实践与管理技巧,成功的运作情况,在国内各行业内迅速展开,也吸引了许多资深管理者和学者的注意力与研究。本文就光学冷加工行业的特殊性与NPS实施的可行性进行了一些探讨,以及一些应用实例,希望能给传统光学冷加工行业提供一些借鉴。
简介:在氩气气氛下,将Ag2O与石墨通过机械活化或热还原反应生成Ag,对其等温还原过程的动力学进行研究。结果表明,采用Johnson-Mehl-Avrami模型能合理地解释Ag2O与石墨经机械活化和热还原合成Ag的过程。采用相同的模型来研究机械活化和热还原反应合成Ag的动力学时,机械活化还原过程中的Avrami指数比热还原的要高;热还原和机械活化过程中的晶核长大机制分别是扩散控制和界面控制。