学科分类
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113 个结果
  • 简介:利用角分辨紫外光电子谱对乙烯和乙炔气体在Ru(1010)表面的吸附及与K的共吸附的研究结果表明:当衬底温度超过200K,乙烯即发生脱氢反应,σCH和σCC能级均向高结合能方向移动。在室温下,σCH和σCC能级位置与乙炔在Ru(1010)表面的吸附时的分子能级完全一致。乙烯发生脱氢反应后的主要产物为乙炔。衬底温度从120K到室温,Ru(1010)表面上乙炔的σCH和σCC能级均未发现变化。室温下乙炔仍然可以在Ru(1010)表面以分子状态稳定吸附。在有K的Ru(1010)表面上,室温时σCC谱峰几乎。碱金属K的存在促进了乙炔的分解。

  • 标签: C2H2 C2H4 K Ru(1010) 共吸附 UPS
  • 简介:AnovelfittingprocedureisproposedforabetterdeterminationofH2rovibrationaldistributionfromtheFulcher-abandspectroscopy.WehaverecalculatedthetransitionprobabilitiesandtheresultsshowthattheydeviatefromFranck-Condonapproximationespeciallyforthenon-diagonaltransitions.Wealsocalculatedthecompletesetsofvibrationallyresolvedcrosssectionsforelectronimpactd3∏u-X3∑gtransitionbasedonthesemi-classicalGryzinskitheory.AnexampleofexperimentalstudyconfirmsthatcurrentapproachprovidesatoolforabetterdiagnosticsofH2rovibrationaldistributioninelectronicgroundstate.

  • 标签: 低温等离子体 转振激发 氢气分子 Fulcher-α波段分光镜
  • 简介:Moleculardynamicssimulationswereperformedtostudytheinteractionbetweenatomichydrogenandsiliconcarbide.Inthepresentstudy,wefocusontheeffectofthesurfacetemperatureonHinteractingwithsiliconcarbide.ThesimulationresultsshowthattheretentionofHatomsinthesampledecreaseslinearlywithincreasingsurfacetemperature.ThedepthprofileanalysisshowsthatthesampleismodifiedbyHbombardment,andthedensityofHatomsisgreaterthanthoseofSiandCatomsneartheinterfaceregionbetweentheH-containingregionandthebulk.However,nearthesurfaceregionthedensitiesofH,SiandCatomsarealmostequivalent.Inthemodifiedlayer,thebondsconsistofSi-CandSi-HandC-H.ThefractionofSi-Cbondsisthegreatest.OnlyafewC-Hbondsarepresent.

  • 标签: 相互作用 SIC 温度效应 分子动力学模拟 MD 表面温度
  • 简介:Ahighlyreliableinterfaceofself-alignedbarrierCuSiNthinlayerbetweentheCufilmandthenano-porousSiC:H(p-SiC:H)cappingbarrier(k=3.3)hasbeendevelopedinthepresentwork.Withtheintroductionofself-alignedbarrier(SAB)CuSiNbetweenaCufilmandap-SiC:Hcappingbarrier,theinterfacialthermalstabilityandtheadhesionoftheCu/p-SiC:Hfilmareconsiderablyenhanced.AsignificantimprovementofadhesionstrengthandthermalstabilityofCu/p-SiC:H/SiOC:Hfilmstackhasbeenachievedbyoptimizingthepre-cleanstepbeforecap-layerdepositionandbyformingtheCuSiN-likephase.ThiscaplayeronthesurfaceoftheCucanprovideamorecohesiveinterfaceandeffectivelysuppressCuatommigrationaswell.

  • 标签: 界面粘结强度 热稳定性 SIOC 膜表面 等离子体处理 堆栈
  • 简介:Thedeviceofacetyleneproductionbyhydrogen(H-)plasmapyrolysiscoalisexaminedanddevelopednotonlyforstudyingtheapplicationoflowtemperatureplasmabutalsoforstudyingthecleanuseofcoal.Thepower-supplycontrolsystemisusedtoensuresupplyingasteadyenergytogenerateandmaintaintheplasmaelectricarcofthedevice.Thehardwareconfigurationandthesoftwaredesignofthesystemaredescribedinthispaper.Verifiedbyexperiments,thissystemcanmeettherequirementsofreal-timeperformance,reliabilityandextensibilityforthedevice.

  • 标签: 电源控制系统 氢等离子体 高温分解 乙炔
  • 简介:该出版物中提出的要求用以确保核电厂调试与运行的安全,这些要求是基于过往经验与技术现状提出和建立的,并遵循《核能安全基本原则》中提出的安全目标与原则。该出版物涉及从核电厂调试、运行到核燃料清除这一过程,其中包括核电厂的维护和改造。同时该出版物不适用于退役过程本身,但涉及核电厂退役前的准备阶段,并对退役过程提出了额外的要求。与此同时,本刊物将常规运行、预期运行事件以及事故情况考虑在内。

  • 标签: 核电厂安全 核电厂调试 核电厂退役 常规运行 事故情况 技术现状
  • 简介:Neutralbeaminjection(NBI)isrecognizedasoneofthemosteffectivemeansforplasmaheating.A100slongpulseneutralbeamwith30keVbeamenergy,10Abeamcurrentanda100slongpulsemodulatingneutralbeamwith50keVbeamenergy,16AbeamcurrentwereachievedintheEASTneutralbeaminjectoronthetest-stand.ThepreliminaryresultssuggestthatEAST-NBIsysteminitiallypossesstheabilityoflongpulsebeamextraction.

  • 标签: 中性束注入器 EAST 长脉冲 提取 等离子体加热 脉冲调制
  • 简介:IntheframeworkoftheITER,qualificationtests,thefirstChinaTFconductorsample(CNTFl)wastestedattheSULTANfacility.ThesamplewasmadeoftwoTFconductorsectionsmanufacturedfromidenticalinternalstannumstrandsprovidedbytheOxfordSuperconductingtechnologycompany(OST).Inordertoevaluatetheconductorperformance,thecurrentsharingtemperature(Tcs)wasmeasuredatspecifiedelectromagneticloadcyclingsteps.BothconductorsectionsoftheCNTFlsampleshowedidenticalperformance.Tcswas7.2Kbeforecyclingloading,and6.9Kevenafter950cycles,withoutsignificantdegradation,whichsubstantiallyexceedstheITERrequirementof5.7K.ThetestsoftheCNTFlconductorsampleshowedthattheelectromagneticcyclicloadexhibitedanegligibleeffectontheconductorperformance.Thecouplingtimeconstant8forAClosswas214msand71.52msbeforeandafterthecyclingload,respectively.Thetestresultsofthesamplearecomparedwiththestrandperformanceandparametermodelanalysis.

  • 标签: 样品分析 国际热核实验堆 测试 纵场线圈 中国 ITER计划
  • 简介:利用扩展X射线吸收精细结构技术对用化学共沉淀法制备的非晶和纳米ZrO2·15%Y2O3体系进行了研究。分析结果显示,在从非晶态向纳米结构晶化的过程中,最近邻的Zr-0配位层的配位数和键长没有发生明显的改变,说明300℃温度处理的样品已经形成的900℃温度处理相同的最近邻局域结构。而对于Zr-Zr(Y)配位层,随着晶粒尺寸的减小,配位数明显降低,键长显著缩短,具有比Zr-O配位层更大的无序。这些结果表明晶粒尺寸的变化对于较远配位层的影响要比对最近邻的影响大得多。

  • 标签: ZrO2 Y2O3 EXAFS 晶化 配位数 键长
  • 简介:利用XRD、TPR和EXAFS等手段考察了焙烧温度对Cu/MnO2/ZrO2催化剂性能影响,结果表明,随着焙烧温度增加,铜的配位环境发生变化,铜和锰之间相互作用增强,有效地防止铜组分在还原及反应过程中聚集长大,从而使催化剂活性显著增加,当催化剂经过高温焙烧,催化剂活性由于ZrO2结晶和铜的聚集而降低。

  • 标签: Cu/MnO2/ZrO2催化剂 焙烧温度 活性测试