简介:Photoisomerization(trans-cis)ofazoaromaticcompoundshasbeeninvestigatedextensivelyusingabsorptionspectroscopysince1950s[1].Byirradiationwithlightofwavelengthλ1orλ2,thegeometricconfigurationoftheazobondinazobenzenebasedcompoundscanbereversiblyswitchedfromtranstocis.Thetwostateshavedistinctabsorptionspectra.Thisfeaturewouldallowreversiblestorageofdataonthebasisofcisandtransstateswiththeaidofλ1andλ2.However,thecisstateisthermodynamicallyunstablewithrespecttothetransstate,thereforeathermalrelaxationprocessoccursinthedark(atroomtemperature).Thisthermalback-reactionstronglylimitsthelifetimeofthecisstate,anditisinfluencedbythesubstituentR1andR2,catalysts,temperature,andenvironment(solventpolarity,typeofpolymermatrix)[2].
简介:Thestarch/D,L-lactidegraftcopolymersweresynthesizedbyreactingD,L-lactidewithcornstarchinN,N-dimethylacetamide(DMAM)inthepresenceoftriethylamine(NEt3)andanhydrouslithiumchloride.TheeffectofreactiontimeandthemolarratioofD,L-lactidetoglucosestructuralunitofstarchonmonomerconversion(C%),graft(G%)andgraftefficiency(GE%)werestudied,TheC%,G%andGE%couldapproach37.3%179.7%and68.0%,respectivelywhenthemolarratioofD,L-lactidetoglucosestructuralunitofstarchis10:1andthegraftcopolymerizationwascarriedoutat80-85℃for4hrundernitrogenatmosphere.TheFouriertransformsinfra-red(FTIR)spectroscopy.differentialscanningcalorimetry(DSC)andX_raydiffraction(XRD)spectroscopywereusedinordertocharacterizethegraftcopolymers.FTIRspectrashowthatabsorptionbandat1740cm^-1confirmedtheformationofesterbond,indicatingthestarch/D,L-lactidegraftcopolymerswereproduced,theDSCcharacteristicresultsshowthemeltingtemperatureofthegraftcopolymerwereelevatedslightlyasthemolarratioofD,L-lactidetoglucosestructuralunitsofstarchincreasedandtheX-raydiffractionspectrashowthesynthesizedgraftcopolymerswereamorphous.Thedegradabilityofgraftcopolymerwastestedwiththeaidofacid,alkaliandmicrobesuchasbacillussubtilisandstaphylococcusaureus.Theresultsofwaterrsistanceshowthegraftcopolymerproducedcanbeusedasacomponentofimpermeablecoatingforcardboard.
简介:Afreestandingfilmofpolyanilineaslargeas18cm×18cm×0.002cmcanbeobtainedbyevaporationofasolutionofthechemicallysynthesizedbaseinNMP.Itsstructurewasexaminedbytheelementalanalysis,IR,U.V.-visiblespectra,XPS,DSC,SEMandX-rayscatteringanditsconductingbehavioraswellaselectrochemicalpropertieswerestudied.Resultsshowthatthecomposition,structureofmainchain,physicalpropertiesofthefreestandingfilmofpolyanilmeissimilartothatofthepowder.However,somedifferencesinitselectronicstructure,conductivityatroomtemperatureandpotentialofredoxcouplebetweenthefleestandingfilmandpowderareobserved,whichmaybeduetocross-linkingofthefilmofpolyaniline.
简介:FLASHatDESY,Hamburg,Germanyisthefirstfree-electronlaser(FEL)operatingintheextremeultraviolet(EUV)andsoftx-raywavelengthrange.FLASHisauserfacilityprovidingfemtosecondshortpulseswithanunprecedentedpeakandaveragebrilliance,openingnewscientificopportunitiesinmanydisciplines.Thefirstcallforuserexperimentshasbeenlaunchedin2005.TheFLASHlinearacceleratorisbasedonTESLAsuperconductingtechnology,providingseveralthousandsofphotonpulsespersecondtouserexperiments.Probingfemtosecond-scaledynamicsinatomicandmolecularreactionsusing,forinstance,acombinationofx-rayandopticalpulsesinapumpandprobearrangement,aswellassingle-shotdiffractionimagingofbiologicalobjectsandmolecules,aretypicalexperimentsperformedatthefacility.WegiveanoverviewoftheFLASHfacility,anddescribethebasicprinciplesoftheaccelerator.Recently,FLASHhasbeenextendedbyasecondundulatorbeamline(FLASH2)operatedinparalleltothefirstbeamline,extendingthecapacityofthefacilitybyafactoroftwo.
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简介:我们考虑形式\的上下文无关语法(G=\{f\tof^{b_1+b_2+1}g^{a_1+a_2},g\tof^{b_1}g^{a_1+1}\}\),在哪儿一i和bi是易于某些确实条件的整数。如此的语法G产生三角形的数组{T(n,k)}<潜水艇class=“a-plus-plus”>0kn令人满意一种三术语的复发关系。许多组合序列能这样被产生。让T<潜水艇class=“a-plus-plus”>n(x)=<潜水艇class=“a-plus-plus”>k=0<啜class=“a-plus-plus”>nT(n,k)x<啜class=“a-plus-plus”>k。关于G基于微分操作员,我们定义线性操作员P的一个序列n以便Tn+1(x)=Pn(Tn(x))。使用由于Borcea和Br在multivariate多项式上保存线性操作员的真实稳定性的描述?nd?訤?X
简介:Vibrationofacircularmembraneincontactwithafluidhasextensiveapplicationsinindustry.Thenaturalvibrationfrequenciesfortheasymmetricfreevibrationofacircularmembraneincontactwithaboundedincompressiblefluidarederivedinthispaper.Consideringsmalloscillationsinducedbythemembranevibrationinanincompressibleandinviscidfluid,thevelocitypotentialfunctionisusedtodescribethefluidfield.Twoapproachesareusedtoderivethefreevibrationfrequenciesofthesystem,whichincludeavariationalformulationandanapproximatesolutionemployingtheRayleighquotientmethod.Agoodcorrelationisfoundbetweenfreevibrationfrequenciesevaluatedbythesemethods.Finally,theeffectsofthefluiddepth,themassdensity,andtheradialtensiononthefreevibrationfrequenciesofthecoupledsystemareinvestigated.
简介:REGULARITYOFTHEFREEBOUNDARYINELECTROCHEMICALMACHININGPROBLEMYuanGuangwei(InstituteofAppliedPhysicsandComputationalMathematics...
简介:Astrikeresetoptionisanoptionthatallowsitsholdertoresetthestrikepricetotheprevailingunderlyingassetpriceatamomentchosenbytheholder.Thepricingmodeloftheoptioncanbeformulatedasaparabolicvariationalinequalityandtheoptimalresetstrategyisthefreeboundary.ThesmoothnessofthefreeboundaryinsomecaseswasshowedinourarticlepublishedinJDE.Wewouldproveitssmoothnessintheothercaseinthispaperbyageneralizedcomparisonprincipleforthevariationalinequality.
简介:Synthesisofsuperabsorbentofstarch-graft-poly(patassiumacrylate-co-acrylamide)hasbeenstudiedbyinversesuspensionpolymerization.Inthispaper,theeffectsofreactionconditions,suchas,monomericconcentration,theamountofcross-linkingagent,ratioofwatertooil,reactiontemperatureandthebestconditionbeingabletoobtainthesphericalresinwereinvestigated.Experimentsshowthatthewater-absorbingresinisstrongandcapableofresistingpressureofretainwater.Itkeepstheshapeofparticlesafterabsorbingwater.Aftermixingwithsoil,itdoesnotbecomesticky,andthecoosstructurecanbetterretainair.Itjustfitagricultureandforest.Inaddition,thermogravimetricanalysisrevealedthesuperiorthermalstabilityofthegraftedproduct,anditslargesizeparticlesalsoreducesriskofairpollution.
简介:我们考虑在位于没有规模的网络的联合振荡器的synchronizability上聚类系数的效果。聚类系数瞄准一个高度聚类的没有规模的网络模型,的价值的分析结果Holme-Kim模型被获得,并且在网络synchronizability之间的关系和聚类的系数被报导。Thesimulation结果强烈建议那越多聚类网络,越poorerthesynchronizability。
简介:Anewmeshfreemethodproposedbytheauthorswaspresented,inwhichthederivativesateachnodewereconstructedusingwholederivativeformulasthroughthenodesselectedaroundthenodeusinglocalCartesianframeinanautonomousmanner,sothatwithoutanyelementitcouldbeconsideredasacompletelymeshfreemethod.Themethodwastestedwithanumericalexample,andreliablesolutionwasobtainedwithhighaccuracyandefficiency.
简介:Thevibrationisoneoftheimportantfactorsaffectingimagingqualityofconventionalremotesensingimagingbecausetherelativemotionbetweentheimagingsystemandthetargetcanresultinthedegradationofimagingquality.Theinfluenceofthevibrationofthedetectorinthetestpathonreflectiveghostimaging(RGI)isinvestigatedtheoreticallyandexperimentally.Weanalyzetheeffectsofthevibratingamplitudeandvelocity.Theresultsdemonstratethatthemicrovibrationsofthebucketdetectorhavealmostnoimpactontheimagingresolutionandsignal-to-noiseratio(SNR)ofRGI,i.e.,thedegradationofimagingqualitycausedbythevibrationofthedetectorcanbeovercometosomeextent.Ourresultscanbehelpfulforremotesensingimaging.