简介:Thetechnologyofactivationbyaddingfewactivators(<1%)toincreasetheamountofblendsincementwasinvestigated.Theresultsshowthatouteractiva-tionhasaremarkableeffectonimprovingthephysicalpropertiesofslagcement,flyashcementandvolcaniccement.Forexample,thecompressivestrengthwasincreasedby5-10MPa.Morever,theapplicationofactivationisbeneficialtogrind-aiding,earlystrengthandwater-reducingetc.
简介:Byanalogueexperimentofexhaustgas,thesensitivecharacteristicsoftitaniatoair/fuelratiowasinvestigated.Theeffectsofsomeimpuri-tiesontheelectricconductivityofTiO2,thedeviationof(A/F)cfrom(A/F)sinnonequilibriumgassystemandtheself-catalyticoxidationofTiO2wereexplainedrespectively.Theeffectsofca-talyst,porosityandthicknessofsensorelementontheresponsetimewasalsoanalyzed.
简介:LeachingexperimentsonmetakaolinshowthatthefinalAlextractionratioreachedinabatchreactionisstrikinglyinfluencedbytheinferiorporestructuregeometryofthemetakaolinpellets.Bycalciningkaolinparticlesadheredinlowhumiditystate,avarietyofmetakaolinpellet,insidewhichalargeopeningsstructuredeveloped,hasbeenprepared.Thestructureremarkablybenefitsleachantiontransference,so,thevarietyhashighacidleachingreactivity,evencoarseasthepelletsare,itsaluminumextractedratiostillhasalinearrelationshipwithleachingtime,andtheleachingkineticsismaintainedzeroorderuptoasignificantconversiondegree.ArevisedPellet-ParticleModelhasbeendevelopedtointerpretthestructureinfluenceonAlextractionratio.
简介:Inthispaperforsavingenergytwodifferentburningmethodsofcementclinkerformationhavebeenstudied.Oneistherapidburningmethodandtheotherisordinaryburningmethodsimulatingrotarykiln,andtheyarecomparedbythekineticpointofview.Theresultrevealsthattheactivationenergyofrapidburningismuchlowerthanordinaryburning.Forlookingintothecause,themainrawmaterial—limestonewasburntbythesametwomethodsandthestructureofproductCaOhasbeendetected.ItcanbefoundthatthemicrostructureofCaOproducedbyrapidburningislooser;latticesconstantsaregreater;crystaldefectsaremoreandparticlesizeissmallerthanthatproducedbyordinaryburning.Thesecausethechemicalreactionmoreactive.Sotheactivationenergyofclinkerformationofrapidburningismuchlowerthanthatoftheordinaryburning.
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简介:Fibrestressofglassfibrereinforcedpolymericcopmositesonloadisdeterminedbyusingopticalfibreasmodelfiberandbymeansoflaserinterferencemethod.Inaddition,theoriginationoffibrestressduringmouldingprocessofcompositesandtherelationbetweenfiberstressofloadedcompositesandexternalstressareexamined.Theexperimentsshowthatfibrestressisrelatedtomolecularstructureofinterfacialmaterialsandstructureofinterfaciallayers.Whenstressistransferredfrommatrixtofibre,eachinterfaciallayerhasdifferentstressgradientanddeformability.Thispropertycanbecharacterizedbyintroducinganinterfacialstresstransfercoefficientktothetwo-phasemodel.
简介:ThesecondaryhardeningreactionisaccompaniedwithprecipitationoffinecarbidesinhighCoNiultrahighstrengthsteel.Thecrystalstructureoftheprecipitatingcarbidesisunambiguouslydeterminedbymicrobeamdiffractionintransmissionelectronmicroscopy.Itisidentifiedthattheneedle-shapedcarbidesareM2Cwithahexagonalstructure.TheconcentrationofsubstitutionalalloyingelementsinthecarbidesquantifiedbyenergydispersiveX-rayspectroscopy(EDS)alsosupportstheresultabove.ThespatialstructureofM2CisidenticalwithL'3type.Metalatomsareinaclosepackedhexagonalstructure,thecarbonatomspartlydistributewithrandomintheoctahedralintersticesandthefillingprobabilityislessthan1/2.Particularattentionwaspaidtotherelationshipofneedle-shapedcarbides/ferritematrixatsecondaryhardeningpeaktemperedat482℃for5h.Observationbyhighresolutiontransmissionelectronmicroscopy(HRTEM)confirmsthatcarbideswithblack-whitecontrastarefullycoherentwithferriteandhaveindividualcrystalstructure,andthecoarsenedcarbideswithmoirefringearepartiallycoherentwithmatrix.TheorientationrelationshipbetweenM2CandferritematrixisdirectlyobservedandidentifiedwiththewellestablishedP-Srelationship[001]α//[111]c.
简介:Bycalculatingtheelectronstructuresofthephasesthatphosphor,sulfurandalloyingelementsdissolvinginγ-Fe,thereasonwhyalloyingelementscanbringcenterlinesegregationincontinuouscastingslab(CCS)withnA,thenumberofelectronsonthestrongestcovalentbonds,andthestructureformationfactorSwereinvestigated,andanelectronstructuralcriteriontocontrolandtoeliminatethecenterlinesegregationwasadvanced.Basingonthis,theelectronstructuresofapartofrareearthphosphidesandsulfidesarecalculated,thephysicalmechanismthatrareearthelementscancontrolthesegregationofphosphorandsulfurisanalyzed,andthecriterioniswellverified.
简介:Sheetmetalformingiswidelyappliedtoautomobile,aviation,spaceflight,ship,instrument,andapplianceindustries.Inthispaper,basedonanalyzingtheshortcomingofgeneralfiniteelementanalysis(FEA),theconceptionofparametricfiniteelementanalysis(PFEA)ispresented.Theparametricfiniteelementanalysis,artificialneuralnetworks(ANN)andgeneticalgorithm(GA)arecombinedtoresearchthoroughlyontheproblemsofprocessparametersoptimizationofsheetmetalforming.Theauthorprogramstheoptimizationschemeandappliesitinaresearchofoptimizationproblemofinsidesquareholeflangingtechnologicalparameters.Theoptimizationresultcoincideswellwiththeresultofexperiment.Theresearchshowsthattheoptimizationschemeoffersagoodnewwayindiedesignandsheetmetalformingfield.
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简介:Withtheaidofthelatestfiberopticsensingtechnology,parametersinthecureprocessofthermosettingresin-matrixcomposite,suchastemperature,viscosity,voidandresidualstress,canbemonitoredentirelyandefficiently.Inthispaper,experimentresultsofviscositymeasurementincompositecureprocessinautoclaveusingfiberopticsensorsarepresented.Basedonthesensedinformation,acomputerprogramisutilizedtocontrolthecureprocess.Withthistechnology,thecureprocessbecomesmoreapparentandcontrollable,whichwillgreatlyimprovethecuredproductsandreducethecost.
简介:Theimplantedionrange,thedepthprofileandthefilmsttuctureoftheimplantedlayerwerestudied;thecarrierconcentrationandthemobilityweremeasured;theconductivitymechanismofthefilmimplantedFeintoAl2O3ceramicwasdiscussed.TheconclusionisthattheimplantedFe2+ionsmoveintoAl2O3latticeandreplaceAl3+toformsubs-titutionimpuritiessothattheionimplantedlat-tice,ascomparedwiththeoriginalone,presentsaneffectivenegativechargewhichformsanegativechargecenter.Avacancyisboundarroundit,andanacceptorisintroducedintheforbiddenband.
简介:Tostudytheosteogenicabilityoftissue-engineeredboneconstructedbycompoundingzinc-sin-teredbovinecancellousbonewithrabbitmarrowstromalcells(MSCs)invivo,thezinc-sinteredbovinecancellousboneofbeta-tricalciumphosphate(TCP)typewaspreparedbysinteringthefreshcalfcancellousbonetwiceandthenloadingitwithzinc-ion.TherabbitMSCswerecultured,inducedandseededontothezinc-sinteredbovinecan-cellousbones.Thetissue-engineeredboneswerethenimplantedintotherabbits'bockmuscles.Thenewlyformedbonetissueswereobservedbyhistologicalmethodsandtheareasofnewosseoustissuesweremeasuredattheendofthe4thand8thweek.Thezinc-sinteredbovinecancellousbonesalonewereimplantedontheothersideascontrol.TheosteogenicactivityofMSCswasidentifiedbyalkalinephosphatase(ALP)stainingandcalcificationnodchi-nalizarinstaining.Attheendof4thweek,asmallamountofnewbonetissueswasobserved.Attheendof8thweek,thereweremanynewlyformedbonematuretissues.Moreover,theareaofthelatterwassignificantlylargerthanthatoftheformer(P<0.01),whileinthecontrolgrouptherewasnonewboneformation.Thetissue-engi-neeredbone,whichwasconstructedbycombiningzinc-sinteredbovinecancellousbonewithMSCs,hassatisfactoryosteogeniccapabilitiesinvivo.
简介:Anovelsolubleπ-conjugatedpolymer,poly[(3-acetylpyrrole-2,5-diyl)p-(N,N-dimethylamino)azobenzylidene](PAPDMAABE),wassynthesizedbycondensationof3-acetylpyrrolewith4-aldehyde-4'-dimethylaminoazobenzene(ADMAA).ThechemicalstructureofPAPDMAABEwascharacterizedbyFouriertransforminfraredspectroscopy(FTIR),1H-NMR,andUV-Vis-NIRspectra.Transmissionelectronmicroscope(TEM)analysisforPAPDMAABEindicatesthatpartofPAPDMAABEisincrystalstate,duetotheshort-rangeorderofthepolymer.Thermogravimetricanalysis(TGA)curveshowsthatthepolymerhasgoodthermalstabilityanditsdecompositiontemperatureis248℃.TheopticalbandgapofPAPDMAABEobtainedfromtheopticalabsorptionspectrumisabout1.73eV.Theresonantthird-ordernonlinearopticalpropertyofPAPDMAABEat532nmwasstudiedusingdegeneratefour-wavemixing(DFWM)technique.Theresonantthird-ordernonlinearopticalsusceptibilityofthepolymerisabout7.48×10-8esu.
简介:Withpositronannihilationradiationonedimensionangular-correlationdevice,itismeasuredthatpositronannihilationradiationonedimensionangular-correlationcurvesofpolycrystalsodiumionconductorNa5Y1-xCrxSi4O12(NYCS)system.Afterelectronmomentumdistributioncurvesarenormalized,linearparametersarecalculated.TheparametersH,WandSshowthechangeofNa+ionvacancyconcentrationinNYCSseriessamples.TheresultsshowthatparametersH,WandSofonedimensionangular-correlationcurvesofthosesamplesvarygreatlywithCr2O3contents.WithCr2O3contentincreasing,HandSparametersincrease,butWdecreases,andreachesextremesatx=0.05;thenwithCr203addingcontinually,parametersHandSdecreasegradually,parameterWincreasesgradually.Thisshowsthat,inaddtiontoCr2O3,theconductivityhascloserelation