Synthesis of Poly （3-acetylpyrrolyl methine） with Azobenzene Side Groups and Study on Its Third-order Nonlinear Optical Property-中国期刊网

摘要 Anovelsolubleπ-conjugatedpolymer,poly[(3-acetylpyrrole-2,5-diyl)p-(N,N-dimethylamino)azobenzylidene](PAPDMAABE),wassynthesizedbycondensationof3-acetylpyrrolewith4-aldehyde-4'-dimethylaminoazobenzene(ADMAA).ThechemicalstructureofPAPDMAABEwascharacterizedbyFouriertransforminfraredspectroscopy(FTIR),1H-NMR,andUV-Vis-NIRspectra.Transmissionelectronmicroscope(TEM)analysisforPAPDMAABEindicatesthatpartofPAPDMAABEisincrystalstate,duetotheshort-rangeorderofthepolymer.Thermogravimetricanalysis(TGA)curveshowsthatthepolymerhasgoodthermalstabilityanditsdecompositiontemperatureis248℃.TheopticalbandgapofPAPDMAABEobtainedfromtheopticalabsorptionspectrumisabout1.73eV.Theresonantthird-ordernonlinearopticalpropertyofPAPDMAABEat532nmwasstudiedusingdegeneratefour-wavemixing(DFWM)technique.Theresonantthird-ordernonlinearopticalsusceptibilityofthepolymerisabout7.48×10-8esu.

1M. Singh;P. Aghamkar;S. Duhan. Enhancement of Second- and Third-Order Nonlinear Optical Susceptibilities in Magnetized Semiconductors.物理,2008-09.
2XIHongxia;LIANGZhaoxi. SYNTHESIS OF NEW ORGANIC／INORANIC HYBRID MATERIAL CONTAINING 4—NITRO—4‘—HYDROXY AZOBENZENE AND ITS SECOND—ORDER NONLINEAR OPTICAL PROPERTIES.高分子化学,2000-11.
3GAOChao;WUHong-cai;YIWen-hui;LIBao-ming;SUNJian-ping;MENGLing-jie. Big Third-order Nonlinear Optical Properties of Two Poly [ （3-alkylthiophene-2, 5-diyl ） - （ benzylidenequinomethane-2, 5-diyl ）] Derivatives.物理电子学,2005-02.
4朱志超;李忠安;李倩倩;曾琪;李振;叶成;秦金贵. Convenient Synthesis and Enhanced Second-order Nonlinear Optical Property of a Novel Hyperbranched Polymer.化学,2007-02.
5余荣民;卢绍芳;陈红兵;黄小荥;黄建全;吴柏昌;司金海. Rational synthesis, structural characterization and the third-order nonlinear optical properties of two new M-Cu-S (M = Mo or W) clusters.化学,1999-01.
6Lan-Qing Zhou;Yan-Bang Zhang;Teng-Fei Yan;Ying Li;Guo-Zhi Jia;Huai-Zhe Xu;Xin-Hui Zhang. Third-Order Nonlinear Optical Response near the Plasmon Resonance Band of Cu2-xSe Nanocrystals.物理,2017-01.
7Wei Yan,An-kuo Li Chain-shu Hsu Zhi-cheng Zhang Mei-xiang Wan. SYNTHESIS AND CHARACTERIZATION OF POLY(PYRROLYL METHINE).高分子化学,2001-05.
8Weimin Wang Yuqiang Feng Anli Zheng. ON THE HYERS-ULAM STABILITY OF A THIRD-ORDER NONLINEAR DIFFERENTIAL EQUATION.基础数学,2015-04.
9TIECHENG WANG;XIANGDONG ZHANG. Improved third-order nonlinear effect in graphene based on bound states in the continuum.物理,2017-06.
10A.M.A. Abou-E1-Ela;A.I. Sadek;A.M. Mahmoud;E.S. Farghaly. STABILITY OF SOLUTIONS FOR CERTAIN THIRD-ORDER NONLINEAR STOCHASTIC DELAY DIFFERENTIAL EQUATIONS.基础数学,2015-03.

Synthesis of Poly （3-acetylpyrrolyl methine） with Azobenzene Side Groups and Study on Its Third-order Nonlinear Optical Property

来源期刊

相关推荐

同分类资源更多

相关关键词

Synthesis of Poly （3-acetylpyrrolyl methine） with Azobenzene Side Groups and Study on Its Third-order Nonlinear Optical Property

来源期刊

相关推荐

同分类资源 更多

相关关键词

同分类资源更多