简介:四lanthanide协作建筑群,也就是[行(2,3-DClBA)3(5,5-dmebipy)(H2O)]2(Ln=Sm(1),Eu(2),Dy(3),惊讶(4));2,3-DClBA=2,3-dichlorobenzoate;5,5-dmebipy=5,5-dmethylbipyridine)被元素的分析,红外线的光谱学和单个水晶X光检查衍射综合并且描绘。调查结果显示建筑群3是一个dinuclear分子,并且中心Dy3+是八坐标的。每个dinuclear单位能被H债券和卤素卤素相互作用连接。建筑群2的光性质建议了Eu3+离子的典型强烈排出物。热分析证明建筑群在三分解了步:协作水然后第一被失去中立ligand5,5dmebipy被失去,最后,2,3-DClBAligand被失去。
简介:TheextractionofCe(Ⅳ)inH2SO4/H3PO4systemwasinvestigatedsystematicallyusingbifunctionalionicliquidextractants(Bif-ILES)[A336][P507],[A336][P204]and[A336][C272]inn-heptane.TheeffectsofH2SO4concentration,extractantconcentrationandsalting-outagentconcentrationwereobservedindetail.TheextractionmechanismofCe(Ⅳ)inH2SO4/H3PO4systemwasobtained.ThecomparisonwithotherextractantssuchasCyanex923,TBPwasalsostudied.Thermodynamicfunctionsoftheextractionreactionwerecalculated,showingthattheextractionwasanexothermicprocess.TheseparationofCe(Ⅳ)fromRE(Ⅲ)andTh(Ⅳ)wasalsoinvestigated.TheresultindicatedthatCe(Ⅳ)couldbeselectivelyextractedinthissystem.CePO4nanoparticleswereobtainedintheprocessofstrippingusingH2O2inH2SO4/H3PO4system.X-raydiffraction(XRD),scanningelectronmicroscopy(SEM)andspectroscopywereadoptedforthecharacterizationofthesample.
简介:ThisstudyresearchestheeffectsoftherefiningtreatmentonthemicrostructureandthemechanicalpropertiesofH13mandrelsteelandcomparestheseeffectswiththoseoftheconventionaltreatment.Theresultsindicatethatbothcarbideparticlesandgrainswererefined,carbideparticleswereuniformlydistributedbytherefiningtreatment,andtherefore,thestrengthandtoughnessofH13mandrelsteelwereimproved.Rapidcoolingafterthesolutiontreatmentmayinhibitintra-granularprecipitationofcarbideparticles,whichisfavorabletoenhancingtoughness.Consequently,high-performanceH13mandrelsteelcanbeproducedbyproperrefiningtreatment.
简介:Thedifferencesofreductionbehaviorsbetweenironorelumpandpelletswerestudiedbyconductinglowtemperaturereductiondegradation,staticloadreductionanddroplettests.Thesetestssimulatedtheconditionsofreductiontemperatureandhydrogen-containinggasinCOREX.Duetoitsdensestructureandlowporositycomparedwithpellets,lumporepossessespoorreductiondegradationindex(RDI)andslowerreductionrateinearlyandmediumreactionstages,showingsignsoflowerstrength,lowersofteningandmeltingtemperatures,aswellasawidermeltingzoneandhigherΔP.Thatprovidessomebasistoexplainthephenomenaofdifferentialpressurerise,metallizationdeclineandmorestickingaftertheusageoflumporeinCOREXplant.
简介:Opticalmicroscope,stereomicroscope,scanningelectronicmicroscope(SEM)andmechanicalpropertytestingwereusedtoresearchtheeffectsofdifferentquenchingtemperaturesonthemicrostructureandmechanicalpropertiesoftheH13mandrelsteel.Theresultsindicatethatfollowinganincreaseinthequenching,thedegreeofalloyingisenhancedduetothecarbidesdissolvinggraduallyinaustenite,whichimprovesthehardenabilityofthespecimens,aswellastheirroomandhigh-temperaturestrength.Atthesametime,thefracturetoughnessincreasesduetotheincrementofthemartensitenumberandtheinterparticledistanceofthecarbides.However,extremelycoarsegrainandmartensitecandecreasetheimpacttoughness.Optimalperformancecanbeobtainedafterquenchingat1060℃anddoubletemperingat620℃.Consequently,theservicelifeoftheH13mandrelsteelisextendedsignificantly.
简介:通过对耐大气腐蚀钢SPA—H的成分设计、冶炼过程及轧制过程的控制,生产出尺寸公差、表面质量及各项性能都符合JISG3125—1987标准要求的SPA—H钢带。