简介：Athree-dimensionalmathematicalmodelofthecombustionofpulverizedcoalandcokehasbeendeveloped.Themodelisappliedtotheblowpipe-tuyere-raceway-cokebedregioninanironmakingblastfurnaceinonecomputationaldomain,whichincludestwoparts:pulverizedcoalcombustionmodelintheblowpipe-tuyere-racewaycavityandthecoal/cokecombustionmodelinthesurroundingcokebed.Theeffectsofcoalpropertiesareexaminedcomprehensively,intermsofcoalburnoutandgasspeciesdistributions.TheresultsindicatethatusingacoaloffineparticlesizeorhighVMcontentcouldimproveburnoutandwouldaffectthegascompositionconsiderably.Theburnoutisexaminedintwoways:comparedwithburnoutalongtuyereaxis,burnoutovertheracewaysurfaceisamoresensitiveandsensibleparametertodescribetheamountofunburntcharenteringthecokebed.Themodelisusefulforexaminingtheflow-thermo-chemicalcharacteristicsofthepulverizedcoalinjection(PCI)processundervariousconditionsinablastfurnace.

简介：Aconoscopicholography-based3Dmeasurementsystemforanalyzingthedefectsonthesurfaceofsteelplateswasintroducedinthispaper.Thehardware,whichisautomatedthroughsoftware,performssamplingofthesteelplatesurface.Throughthesoftwareinterface,point-clouddataofthesteelplatesurfaceareobtainedandreconstructedtoforma3Dimageofthesteelplatesurface.Thesoftwareallowsautomaticanalysisofsteelplatesurfacedefectsthroughidentificationofthebulgesanddepressions.Inaddition,thesoftwarecanalsoautomaticallycalculatethedefectinformation,suchasthedeepestpoint,volume,openingarea,openinglength,andsoon,therebydeterminingthedefectsize.Theresultsdeterminedbythis3Dmeasurementsystemwerefoundtobeingoodagreementwiththeactualvalues.

简介：四lanthanide协作建筑群，也就是[行(2,3-DClBA)3(5,5-dmebipy)(H2O)]2(Ln=Sm(1),Eu(2)，Dy(3)，惊讶(4))；2,3-DClBA=2,3-dichlorobenzoate；5,5-dmebipy=5,5-dmethylbipyridine)被元素的分析，红外线的光谱学和单个水晶X光检查衍射综合并且描绘。调查结果显示建筑群3是一个dinuclear分子，并且中心Dy3+是八坐标的。每个dinuclear单位能被H债券和卤素卤素相互作用连接。建筑群2的光性质建议了Eu3+离子的典型强烈排出物。热分析证明建筑群在三分解了步：协作水然后第一被失去中立ligand5,5dmebipy被失去，最后，2,3-DClBAligand被失去。

简介：ThephaseandmorphologytransformationduringthehydrothermaltreatingprocessofY2O3wasevaluatedwithX-raydiffcrcnce(XRD),scanningelectronmicroscopy(SEM),transmissionelectronmicroscopy(TEM),particlesizeandspecificsurfaceareadetermination.TheresultsshowedthatthecubicY2O3didnottransferintohexagonalY(OH)3inpurewater.Therefore,purehexagonalY(OH)3withnanotubeandmicrorodmorphologieswereobtainedbyhydrothermaltreatingY2O3at150℃for12hin15mlof2mol/LNaOHsolutionwithandwith-outPVAorPEGItwassuggestedthatthecharacteristicpreferentialgrowthofY(OH)3wasattributedtothestructureanisotropyofhexahedronY(OH)3.TheadditionofPVAorPEGcouldpromotetheformingprocessofnanotubesbyselectiveadsorptionondifferentcrystalplanes,whichalteredthegrowthratealongdifferentdirectionsandresultedinthediffusionlimitofconstructingionsinthecentertopofrods.Finally,Y(OH)3:EuandY2O3:Eunanotubeswerealsosynthesizedbyusingthismethod,andtheirphotoluminescencepropertieswereevaluated.

简介：Thesolutionreactionmechanisms,composition,donoratoms,propertiesofcoordinatelinkandstabilityofthecomplexesonthesystemsofadrenalinewithNa3+,Gd3+andTm3+havebeenstudiedbypH-potentiometrictitrationandelectronicspectroscopy.Adrenalineperturbsthef-felectronictransitionofNd3+andTm3+sothattheabsorptionspectraoftheircomplexesareshiftedtowardlongerwavelengths.Theabsorptionspectraofthecomplexesformedbythethreef-blockelementionswithadrenalineareshiftedtowardshorterwavelengthswiththeincreaseofPHinΔγ=350～650nm

简介：云南驰宏锌锗股份有限公司会泽铅锌矿是我国一个千米深井矿山，其下属8号矿体采深已达1200余米，矿体赋存条件复杂，地应力高，导致微地震活动频发。本文根据微震监测数据及井下开采活动，对微震活动的时空分布、诱发模式以及预测预报进行了研究。结果表明：微震活动的时空分布主要与开采活动及地质构造有关，根据发生位置、震级大小、破坏特征可将微地震的诱发模式分为应变破裂、矿柱冲击以及断层滑移破裂三类，阐述了各自的发生机制。提出以地震学参数一活动率∑N／Δt、视体积VA、能量指数EI的时间序列曲线来预测矿震灾害，并对其物理意义及破坏过程中可能出现的特征进行了理论分析，现场应用后证明：地压灾害发生前，活动率∑N／Δt及视体积VA急剧增加，能量指数EI突然降低。

简介：YbAl3(BO3)4crystalofgoodopticalqualitywasgrownbythefluxmethod.ThestructureofYbAl3(BO3)4crystalwasdeterminedbysingle-crystalX-raydiffraction.TheexperimentshowsthatYbAl3(BO3)4belongstothedoubleborateswithatrigonalstructure.ThespacegroupisR32anditsunitcellconstantsweremeasuredtobea=0.92965nm,c=0.72129nm,V=0.53673nm3,Z=3.Thetransmittancespectraweremeasured.Thecut-offofYbAl3(BO3)4crystalis216nm,andtherearetwoabsorptionpeakslocatedat940and975nmfrom190nmto2600nm.ThethermalpropertiesofYbAl3(BO3)4crystalwerestudiedforthefirsttime.Theaveragethermalexpansioncoefficientsweredeterminedtobe2×10-6/℃,9.5×10-6/℃alonga-andc-direction.ThespecificheatofYbAl3(BO3)4crystalwasmeasuredtobe0.6695J·(g·℃)-1atroomtemperature.AllresultsindicatethattheYbAl3(BO3)4crystalisanexcellentstoichioimetriclasermaterial.

简介：在达到一定勘查程度的金矿区,有条件的合理利用部分D级储量作为矿山建设依据,可以减少投资风险,保障黄金生产稳步发展。

简介：Er3+-Tm3+-Yb3+tri-dopedBaMoO4phosphorsweresynthesizedbyco-precipitationtechniqueandcharacterizedbyX-raydiffractionanalysis,absorptionstudyandfieldemissionscanningelectronmicroscopyanalysis.Upconversionaswellasdownconversionluminescencestudieswereperformedbyusingnearinfrared（980nm）andultraviolet（380nm）excitations.Energyleveldiagram,pumppowerdependenceandcolourcoordinatestudywereutilizedtodescribethemulticolorupconversionemissionproperties.Undersingle980nmdiodelaserexcitationthedualmodesensingbehaviourisrealizedviaStarksublevelsandthermallycoupledenergylevelsoftheTm3+andEr3+ionsinthepreparedtri-dopedphosphors.AcomparativefluorescenceintensityratioanalysisforintegratedemissionintensitiesarisingfromtheStarksublevels{1G4（a）and1G4（b）}andthermallycoupledenergylevels{2H11/2and4S3/2}oftheTm3+andEr3+ions,respectivelywascarriedoutinthepreparedtri-dopedBaMoO4phosphors.ThemaximumsensitivityforthermallycoupledenergylevelsoftheEr3+andStarksublevelsoftheTm3+ionwasreported.Thedevelopedphosphorscouldbeusefulinthedisplaydevicesandopticalthermometricapplications.

简介：本文采用高温团相反应合成TCaTiO3∶Pr3+红色发光材料、报道了Pr3+激活的CaTiO3的光谱特征及长余辉特性，并与CaS∶Eu的光谱特性及长余辉进行了比较。CaTiO3∶Pr3+将是一种具有广泛用途的新材料

简介：介绍了武山铜矿中段运输系统原3m3底侧卸矿车的设计特点。结合生产实际状况，对3m3底侧卸矿车在运行过程中出现的问题进行了分析，总结产生故障的原因，针对性的提出改进措施。现场使用表明，通过改进后，取得了良好效果，满足了矿山生产的需要。

简介：Eu3+activatedSr1–xEuxZrO3(x=0.01–0.04)phosphorwithperovskitestructurewassuccessfullysynthesizedbyusingcombustionmethod.Thestructure,morphologyandopticalpropertiesofthematerialwerecharacterizedbyX-raydiffraction,scanningelectronmicroscopyandfluorescencespectrometry.TheXRDresultsindicatedthatcrystalsofSrZrO3:Eu3+belongstotetragonalperovskitesystem.ThephosphorcouldbeeffectivelyexcitedbyUVlightandtheemissionspectraresultsindicatedthatreddish-orangeluminescenceofSrZrO3:Eu3+duetomagneticdipoletransition5D0→7F1at593nmwasdominant.Thus,thepreparedphosphorshowedremarkableluminescentpropertieswhichfindapplicationsinfieldemissiondisplay(FED)andplasmadisplaypanel(PDP)devices.

简介：以奥氏体再结晶型控制轧制和未再结晶型控制轧制相结合的轧制工艺生产的Q345D钢板,其组织均匀、晶粒细小、性能良好,特别是低温韧性较好,达到了控制轧制的目的。

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简介：Calciumtitanatedopedwithpraseodymiumwaspreparedthroughsolidstatereactionanditexhibitedintenseredemissionat612nm.Phosphorswerecharacterizedforphotoluminescence,thermo-luminescenceandafterglowemissions.Studyofeffectsofrareearthsonphotoluminescenceaswellasafterglowintensitywasreported.Presenceofgadoliniumenhancedluminescence.Presenceofsomemonovalentionsenhancedbothafterglowandphotoluminescenceemission.Thermo-luminescenceglowcurveswereanalyzedand...

简介：在石灰窑大修过程中对石灰窑存在的薄弱环节采取了一些改进措施，建造新型石灰窑可以从根本上扭转公司石灰生产的被动局面。

简介：Er~（3＋）andLa~（3＋）codopedY_2O_3nanocrystallinepowdersweresynthesizedbygelcombustionmethodandcharacterizedwiththermalanalysis,X-raydiffraction（XRD）,transmissionelectronmicroscopy（TEM）,high-resolutionTEM（HRTEM）techniquesandfluorescencespectroscopy.Afterbeingcalcinedat1200oC,the（Y_（1–x）La_x）_2O_3：Er~（3＋）powderswereconfirmedtobecubicY_2O_3phasewiththecrystallinegrainsizeintherangeof20–40nm.TheEr~（3＋）emissionat1.53μmfromthe~4I_（13/2）→~4I_（15/2）transitionwasobserved,whichwasfoundtobeenhancedbyintroducingLa~（3＋）ions.SuchenhancementcouldbeattributedtotheadjustmentofEr~（3＋）ions＇localenvironmentbythecodopingofLa~（3＋）ions,leadingtotheincreasedgroundstateabsorptioncrosssectionofEr~（3＋）ions.

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简介：Duetotheremarkablemagnetoresistance(MR)effectonperovskite-typemanganite,magnetoelectronicsandspintronicshavebecomeattractivesubjectsofexperimentalandtheoreticalinvestigationsfortheapplicationpurpose.(La0.9Nd0.1)2/3Ca1/3Mn1-xFexO3(x=0,x=0.05)werepreparedsuccessfullybysol-gelmethod.Thestructure,magneticproperties,andtransportpropertiesofthecompoundswereinvestigated.Themagnetoresistanceeffectdependsonthecompositionandthetemperature.XRDpatternsshowthatthecompoundisasinglephasepolycrystalwithpseudocubicstructure.Alargenegativeisotropicmagnetoresistanceeffectinthesampleswereobservedatlowtemperatureregion.ThemaximumMRofthesampleswas77%and97%,respectively.Itwasmostlikelyduetothescatteringorthetunnelingtransportofspin-polarizedcarriersinlatticeunderstrongmagneticfield.

简介：InordertosensitizetheluminescenceofEu3+ionsinheavymetalglass,zincleadborateglasssamplescontainingvariousconcentrationsofEu3+andTb3+ionswerepreparedtostudytheTb3+toEu3+non-radiativeenergytransferphenomena.EnergylevelstructuresofTb3+andEu3+ionswereplottedtoshowtheexcitationandenergytransferroutes.EfficientenergytransferfromTb3+toEu3+wasobservedandstudiedqualitativelyintermsofdopingconcentrations.Thesensitizationturnedouttobelesseffectivethanexpected.FurtherstudiestocharacterizetheoxidationofTb3+intotetravalentstateandtoexaminethemechanismofenergytransferareproposed.