简介:ImportanceofMetal-OxideSupportWettingandinteractionsonUnderstandingofPhysicalandChemicalBehavioursofSupportedMetalCatalystsLi...
简介:Onthebasisoftheexperimentalworkofadhesion(W)data,theadhesionbetweentransitionmetalcar-bidesandpureliquidmetalswhichdonotreactwithcarbidesisstudied.Inviewofgreatscatteringoftheex-perimentalvaluesofW,acriticalanalysisoftheseresultsisperformed.TheselectedWvaluesfor9copper/carbidesystemsand6metal/TiCsystemsareusedtodiscussthevarioussuggestionsconcerningthemechanismofadhesionandtoevidencetheroleofthevalenceelectronsofthebothcarbideandmetalontheinteractionsbetweenmetalsandcarbides.Theinteractionsbetweenametalandacarbideareessentiallymetal-licinteractions,resultingfromtheoverlappingofthevalenceelectronsatthemetal/carbideinterface.
简介:Accordingtothespecificationofsuperalloy-stainlesssteelarcbrazingandcharacteristicofthebasemetal,abestfillermetalwhichhasrelativelowermeltingpoint,nicewettability,goodweldforming,andadequateshearstrengthwasresearched.TheexperimentresultsshowthatwettabilityofCuFeMnonthestainlesssteelisverypoor,concomitantwithamassofpurplesootduringtheweldingwhichdeterioratestheworkingcondition.CuSiMnhasthebestwettabilityonboththesuperalloyandstainlesssteel,butthereremainsalotofpitandslagonthesurfaceoftheweldbead.Copper-basedsolderhasthehighestmeltingpointanditswettabilityandclearancefillabilityareweakerthanCuSi3.WettabilityandclearancefillabilityoftheCuSi3arethebestinallthecandidatefillermetals,anditsweldissmoothnessandhashighershearstrength.Foritscomprehensiveability,CuSi3isselectedasthefinalfillermetal.
简介:Recoveryprocessesofsecondaryresourcesusuallyencounterproblemsbecauseofthediversecompositionsofwastes.Toenhancetheapplicabilityoftraditionalhydrometallurgicalprocesstowardsecondaryresources,theadjustmentofcomponentsisnecessary.Intraditionalhydrometallurgicalseparation,precipitationandcomplexationareextensivelyused.However,theircombinationasaspecificmetalseparationmethodhasnotyetbeenstudiedindetail.Thisapproachisverypromisingforsolvingproblemscausedbychangeablecomponentsduringrecyclingprocessesofsecondaryresources.Thispaperreviewstheeffectsofprecipitationandcomplexationinmetalseparationprocesses,andametalseparationmethodsystemof‘‘complexation–precipitation’’developedtoadjustthecomponentsofsecondaryresourcesisintroduced.
简介:金属涂的cenospheres广泛地在工业被使用了。不同涂层方法导致不同典型金属电影。由化学涂层的cenosphere上的金属电影不看起来很光滑,展出积累的金属和表面上的大头针洞并且离开某点uncoated。同时,金属电影紧没被吸收到cenospheres上并且是容易的开脱皮。然而,磁控管劈啪作响准备的金属电影是紧缩的,光滑并且在大头针洞外面。这部电影有好亲密关系到cenosphere表面。甚至当cenosphere被压碎时,如此的电影不用它分开。两个都,金属电影给一样的XRD模式,显示金属的水晶结构由这二个方法拍摄是一样。化学涂层是一个复杂过程并且有害环境,而是它适合极其细小的粉末涂层(粒子尺寸能是不到2)。磁控管劈啪作响的方法是环境的友好并且快速工作,但是这个方法要求特殊设计的设备并且不为极其细小的粉末工作。如果粒子尺寸是不到30,涂层过程是难的继续。
简介:Nb-bearingslagfromBaotouhotmetalwaschlorinatedinthesolidstatewithmoltenCaCl2undervacuum,96~98%MnOorFeObeingthusvolatilized.Byreducingthechloridizedresidueunderadditionofflux,ferroniobiumwithabout60%Nbwassuccessfullymade.KineticstudyofchlorinationofsyntheticMnO-Nb2O5-SiO2andFeO-Nb2O5-SiO2slagsystemswasconducted,andanon-reactingcoremodelforthedemanganificationwithfreeuseofactivitywasformulatedandtherate-controllingstepwasexplained.
简介:MoS_2,MoSe_2andWSe_2thinflakeswerefabricatedbythestandardmicromechanicalcleavageprocedures.ThethicknessandtheopticalcontrastoftheatomicthindichalcogenideflakesonSiO_2/Sisubstratesweremeasuredbyatomicforcemicroscopy(AFM)andspectroscopicellipsometer.Arapidandnondestructivemethodbyusingreflectionspectrawasproposedtoidentifythelayernumberof2DlayeredtransitionmetaldichalcogenidesonSiO_2(275nm)/Sisubstrates.Thecontrastspectraof2DnanosheetswithdifferentlayernumbersareinagreementwiththeoreticalcalculationsbasedonFresnel'slaw,indicatingthatthismethodprovidesanunambiguousandnondestructivecontrastspectrafingerprintforidentifyingsingle-andfew-layeredtransitionmetaldichalcogenides.Theresultswillgreatlyhelpinfundamentalresearchandapplication.