学科分类
/ 1
18 个结果
  • 简介:Wettingandspreadingprocesseswhichinvolvesurfactantsolutionsarewidelyusedinnumerousindustrialandpracticalapplicationsnowadays.Theperformanceofdifferentnon-ionicsurfactantsmayvarysignificantlyandsofarsuperspreadersolutionsshowthemostpromisingspreadingability.Theadditionoftrisiloxanesurfactantstowaterwasproventoenhancewetting,evenonhydrophobicsurfaces,onwhichconventionalsurfactantsseemtohavelittleornoeffect.Althoughtheseextraordinarysurfactantshavebeenextensivelystudiedoverrecentyears,completeunderstandingoftheirunderlyingmechanismsandasuitablemathematicalmodelarestilllacking.Herewepresentapossibleexplanationfortheimpressiveperformanceoftrisiloxane,whichiscomparedtowettingenhancementofaconventionalsurfactant.Additionally,wewillexplainwhythehydrophobicityofthesurfaceisacrucialfactorforthespreadingphenomenon.LightwillbealsoshedontheeffectofthepHofthesolutiontowhichsurfactantsareadded.Finally,wewillinvestigatelong-termeffectsofthewaterenvironmentontrisiloxanewettingabilityanddiscussifageingmaysignificantlyaffecttheirperformance.

  • 标签: HYDROPHOBICITY superspreading SURFACTANTS WETTING
  • 简介:Biologicaltinystructureshavebeenobservedonmanykindsofsurfacessuchaslotusleaves,whichhaveaneffectonthecolorationofMorphobutterfliesandenhancethehydrophobicityofnaturalsurfaces.Weinvestigatedthemicro-scaleandnano-scalestructuresonthewingsurfacesofinsectsandfoundthatthehierarchicalmultipleroughnessstructureshelpinenhancingthehydrophobicity.Afterexamining10ordersand24speciesofflyingPterygotaninsects,wefoundthatmicro-scaleandnano-scalestructurestypicallyexistonboththeupperandlowerwingsurfacesofflyinginsects.Thetinystructuressuchasdenticleorsetaeontheinsectwingsenhancethehydrophobicity,therebyenablingthewingstobecleanedmoreeasily.AndthehydrophobicinsectwingsundergoatransitionfromCassietoWenzelstatesatpitch/sizeratioofabout20.Inordertoexaminethewettingcharacteristicsonaroughsurface,abiomimeticsurfacewithmicro-scalepillarsisfabricatedonasiliconwafer,whichexhibitsthesamebehaviorastheinsectwing,withtheCassie-Wenzeltransitionoccurringconsistentlyaroundapitch/widthvalueof20.

  • 标签: INSECT WING SUPERHYDROPHOBICITY MIMICRY hierarchical structure
  • 简介:Itiswellknownthatsurfaceroughnesshasaveryimportanteffectonsuperhydrophobicity.TheWenzelandCassie-Baxtermodels,whichcorrespondtothehomogeneousandheterogeneouswettingrespectively,arecurrentlyprimaryinstructionsfordesigningsuperhydrophobicsurfaces.However,theparticulardropshapethatadropexhibitsmightdependonhowitisformed.Awaterdropcanoccupymultipleequilibriumstates,whichrelatetodifferentlocalminimalenergy.Insomecases,bothequilibriumstatescanevenco-existonasamesubstrate.Thustheapparentcontactanglesmayvaryandhavedifferentvalues.WediscusshowtheWenzelandCassie-Baxterequationsdeterminethehomogeneousandheterogeneouswettingtheoretically.Contactangleanalysisonhierarchicalsurfacestructureandcontactanglehysteresishasbeenputspecificattention.Inparticular,westudytheenergybarrieroftransitionfromCassie-BaxterstatetoWenzelstate,basedonexistingachievementbypreviousresearchers,todeterminethepossibilityofthetransitionandhowitcanbeinterpreted.Ithasbeendemonstratedthatsurfaceroughnessandgeometrywillinfluencetheenergyrequiredforadroptogetintoequilibrium,nomatteritishomogeneousorheterogeneouswetting.

  • 标签: SUPERHYDROPHOBIC surface contact ANGLE WETTING TRANSITION
  • 简介:Wehavecarriedoutanexperimentalstudyofliquiddropimpactonsuperhydrophobicsubstratescoveredbyacarpetofchemicallycoatednano-wires.Themicro-structureofthesurfaceissimilartosomebiologicalones(Lotusleafforexample).Inthissituationthecontactanglecanthenbeconsideredasequalto180degrees,withnohysteresis.Duetoitsinitialinertia,thedropexperiencesaflatteningphaseafterithitsthesurface,takingtheshapeofapancake.Onceitreachesitsmaximallateralextension,thedropbeginstoretractandbouncesback.Wehaveextractedthelateralextensionofthedrop,andweproposeamodelthatexplainsthetrend.Wefindalimitinitialvelocitybeyondwhichthedropprotrudesintothenano-wirecarpet.Wediscusstherelevanceofpracticalissuesintermsofself-cleaningsurfacesorspray-cooling.

  • 标签: SUPERHYDROPHOBIC SURFACES DROP IMPACT
  • 简介:Naturalsurfaceswithsuperhydrophobicpropertiesoftenhavemicroorhierarchicalstructures.Inthispaper,thewettingbehavioursofasingledropletonbiomimeticmicrostructuredsurfaceswithdifferentroughnessparametersareinvestigated.Atheoreticalmodelisproposedtostudywettingtransitions.Theresultsoftheoreticalanalysisarecomparedwiththoseofexperimentindicatingthattheproposedmodelcaneffectivelypredictthewettingtransition.Furthermore,anumericalsimulationbasedonthemesoscaleLatticeBoltzmannMethod(LBM)isperformedtostudydynamiccontactangles,contactlines,andlocalvelocityfieldsforthecasethatadropletdisplaysonthemicrostructuredsurface.Asphericalwaterdropletwithrs=15μmfallsdowntoabiomimeticsquare-postpatternedsurfaceundertheforceofgravitywithaninitialvelocityof0.01m·s-1andaninitialverticaldistanceof20μmfromdropletcentretothetopofpots.Inspiteofahigherinitialvelocity,thedropletcanstillstayinaCassiestate;moreover,itreachesanequilibriumstateatt≈17.5ms,whencontactangleis153.16°whichisslightlylowerthanthepredictionofCassie-Baxter’sequationwhichgivesθCB=154.40°.

  • 标签: BIOMIMETIC WETTING BEHAVIOURS ROUGHNESS surfaces contact
  • 简介:Inthenaturalworld,plantsandanimalshaveevolvedovertimetobestadapttotheenvironment.Theyinteractveryeffectivelywiththesurroundingenvironmentbyexchangingenergiesandmassflowacrosstheircuticlesofspecificmicrostructuresandfunctionstoachieveperfectenergybalance.Suchdifferentfunctionsmayincludethelimitationofuncontrolledlossofwater,protectionfromsolarradiation,microeffectofinducedturbulenceonflowdragreduction,defenceagainstpathogens,changingsurfacewettabilityandhydropho-

  • 标签:
  • 简介:AnaggregatestabilitytestandasimulatedrainfalltestwereconductedonfourrepresentativeUltisolsfromsoutheasternChina.Thesoilsselected,withclaycontentsrangingbetween117and580gkg-1,werederivedfromshaleandQuaternaryredclay.Thestabilityofaggregates(2–5mmindiameter)obtainedfromthesoilsamplesweredeterminedbytheLeBissonnaismethod.Fordeterminationofinfiltration,runoff,anderosion,thesoilsampleswerepackedin30cm×60cmtrays,wettedatratesof2,10,and60mmh-1,andthenexposedtosimulatedrainfallat60mmh-1for1h.Theresultsindicatedthatbothaggregatestabilityandslakingcausedbyfastwettingincreasedwithincreasingclaycontent.Theeffectofwettingrate(WR)oninfiltrationandsealformationvariedwithclaycontents.Inthesoilwithlowclaycontent(sandyloam),theinfiltrationratewasaffectedslightlybyWRduetolowaggregatestabilityandslaking.Inthesoilswithmediumclaycontent(siltclayloamandclay),WRaffectedinfiltrationsignificantlyduetothehighaggregateslakingforce.Inthesoilwithhighclaycontent,theeffectofWRoninfiltrationwassignificant,butnotasevidentasinthesoilswithmediumclaycontent,whichmayberelatedtohighaggregatestabilitybywettingpartiallycompensatingforslakingforce.TheeffectofWRonsoillosswassimilartothatofrunoff,butmorepronounced.ThefindingsfromthisstudyindicatedthattherelationshipbetweenwettingrateandclaycontentshouldbeconsideredwhenpredictinginterrillerosioninUltisols.

  • 标签: 粘土含量 润湿率 侵蚀 中国
  • 简介:小总数(LWA)的影响在总数以及具体渗透附近在化学界限水和浆糊的毛孔结构上预先弄湿被调查。结果显示出那,在干燥LWA有的早年龄在它附近的稠密的浆糊的形成上的重要效果并且改进具体不能渗透的性质或状态。然而,prewettedLWA在以后的年龄有强壮的释放水的效果,它在它附近增加浆糊的水和度,并且让邻近的浆糊与低孔和更好的孔开发结构,而且,具体不能渗透的性质或状态能被改进。这被建议至于有低耐久性要求的水泥,没有预先弄湿的LWA只要,处理能被使用满足新鲜水泥的可使用性要求,水泥的好不能渗透的性质或状态能也被获得。至于有高耐久性要求的水泥,prewettedLWA应该被使用,并且只要,预先弄湿的时间应该被扩大可能,以便优化具体结构在长期,并且改进具体耐久性。

  • 标签: 混凝土耐久性 渗透性 轻集料 润湿 高耐久性混凝土 骨料
  • 简介:Directseededriceispromisingalternativetotraditionaltransplanting,butrequiresappropriatecropandwatermanagementtomaintainyieldperformanceandachievehighwaterproductivity.Presentstudyevaluatedtheeffectofseedprimingandirrigationoncropestablishment,tillering,agronomictraits,paddyyield,grainqualityandwaterproductivityofdirectseededriceinalternatewettinganddrying(DSR-AWD)incomparisonwithdirectseededriceatfieldcapacity(DSRFC).Seedprimingtreatmentswereosmo-primingwithKCl(2.2%),CaCl2(2.2%)andmoringaleafextracts(MLE,3.3%)includinghydro-primingascontrol.Amongthetreatments,seedosmo-primedwithMLEemergedearlierandhadhigherfinalemergence,followedbyosmo-primingwithCaCl2.TilleringemergencerateandnumberoftillersperplantwerethehighestforseedprimingwithCaCl2inDSRAWD.Totalproductiveandnon-productivetillers,paniclelength,biologicalandgrainyields,harvestindexwerehighestforseedprimingwithMLEorCaCl2inDSR-AWD.Similarly,grainquality,estimatedintermsofnormalgrains,abortiveandchalkygrains,wasalsothehighestinDSR-AWDwithMLEosmo-priming.BenefitcostratioandwaterproductivitywasalsothehighestinDSR-AWDforseedprimingwithMLE.Inconclusion,seedprimingwithMLEorCaCl2canbesuccessfullyemployedtoimprovethedirectseededriceperformancewhenpracticedwithalternatewettinganddryingirrigation.

  • 标签: 水分生产率 种子引发 干湿交替 直播水稻 性能 单株分蘖数
  • 简介:TheternarycompoundbariumaluminosilicateBaAl2Si2O8,knownascelsian,anon-wettingadditivethatincreasesthecorrosionresistanceofrefractorymaterialsagainstmoltenaluminum,wasincorporatedintothematrixofahigh-aluminalowcementcastableafteritssynthesisusingbariteandalowcostsourceofaluminaandsilica.Thispaperpresentstheinfluenceofthisphaseonthewettingangleformedbetweenliquidaluminumalloyandsolidrefractorycastablesurface.

  • 标签: 耐火材料 润湿角 熔融铝 添加剂 腐蚀 低水泥浇注料
  • 简介:NanocrystallineanataseTiO2filmswithindiumtinoxide(ITO)coatedglassasthefilmsubstratewerefabricatedthroughspin-coatingtechnique.TheTiO2pasteswerepreparedwithsodiumdodecylbenzenesulfonate(DBS)modifiedTiO2nanocrystals,synthesizedbysol-hydrothermalprocessesinadvance,togetherwithdifferentamountsofpolyethyleneglycol(PEG)macromolecules.Theas-preparedfilmsweremainlycharacterizedbyultraviolet-visible(UV-Vis)spectroscopy,fieldemissionscanningelectronmicroscopy(FE-SEM)andwatercontactangle(WCA)measurement.EffectsoftheadditionofDBSandPEGonthewettingperformanceoftheresultingfilmsandrelevantmechanismswereprincipallyinvestigated.Theresultsshowthattheas-preparedfilmdisplayssuper-hydrophilicpropertyafterco-additionofDBSandPEGalthoughitisnotexposedtoultravioletlightpriortotheWCAmeasurement.Thisappealingresultismainlyattributedtotheproducedmicroandnanometer-scalehierarchicalsurfacestructurewithuniformlydispersedmicropapillae.EachpapillawasmadeupofagreatnumberofTiO2nanoparticles.ThepossibleformationmechanismsrelatedtotheDBSamphiphilicpropertyofthecharacteristicsurfacewerealsosuggested.Moreover,theresultingfilmalsoexhibitsconsiderabledurabilityinthesuperhydrophilicity,whichisveryusefulforpracticalapplicationinself-cleaning,anti-fogging,andbacteria-resistantfields.

  • 标签: TiO2薄膜 润湿性能 PEG 场发射扫描电子显微镜 加入量 二氧化钛薄膜
  • 简介:由于短链perfluoroalkyl组的非结晶的性质,使用短链perfluoroalkyl稳定免费精力聚合物是的低表面一项挑战性的任务。在这研究,我们poly准备一系列随机的共聚物(perfluorohexylethylmethacrylate)-co-poly(stearylacrylate)(P13FMA-co-PSA)并且poly堵住共聚物(perfluorohexylethylmethacrylate)-b-poly(stearylacrylate)(P13FMA-b-PSA),并且系统地在表面上调查顺序结构的效果和氟化的共聚物的13FMA的内容免费精力和表面重组。静态/动态的接触角度角度测定法和水/油抵抗性分析证明随机的聚合物P13FMA-co-PSA不能完成低表面免费精力和低表面重组同时。相反为块共聚物P13FMA-b-PSA,两低表面免费精力和低表面重组同时被获得。X光检查光电子光谱学(XPS)的结果,动态接触角度角度测定法和微分扫描热量测定(DSC)揭示上述性质。当连续SA链提高SA片断的crystallinity时,连续13FMA片断改进表面氟的符号密度,并且进一步妨碍perfluoroalkyl组的表面重组。因此,P13FMA-b-PSA比P13FMA-co-PSA展出氟的符号原子和更好结构的稳定性的更高的利用效率。

  • 标签: 甲基丙烯酸酯 聚合物性能 含氟共聚物 序列结构 低表面自由能 X射线光电子能谱
  • 简介:Soldersizeeffectonearlystageinterfacialintermetalliccompound(IMC)evolutioninwettingreactionbetweenSne3.0Age0.5Cusolderballsandelectrolessnickelelectrolesspalladiumimmersiongold(ENEPIG)padsat250Cwasinvestigated.TheinterfacialIMCstransformedfrominitialneedle-androdtype(Cu,Ni)6Sn5tododecahedron-type(Cu,Ni)6Sn5andthentoneedle-type(Ni,Cu)3Sn4attheearlyinterfacialreactionstage.Moreover,theseIMCtransformationsoccurredearlierinthesmallersolderjoints,wherethedecreasingrateofCuconcentrationwasfasterduetotheCuconsumptionbytheformationofinterfacial(Cu,Ni)6Sn5.Onthermodynamics,thedecreaseofCuconcentrationinliquidsolderchangedthephaseequilibriumattheinterfaceandthusresultedintheevolutionofinterfacialIMCs;onkinetics,largersolderjointshadsufficientCufluxtowardtheinterfacetofeedthe(Cu,Ni)6Sn5growthincontrasttosmallersolderjoints,thusresultedinthedelayedIMCtransformationandtheformationoflargerdodecahedron-type(Cu,Ni)6Sn5grains.Insmallersolders,nospallingbuttheconsumptionof(Cu,Ni)6Sn5grainsbytheformationof(Ni,Cu)3Sn4grainsoccurredwheresmallerdiscrete(Cu,Ni)6Sn5grainsformedattheinterface.

  • 标签: Size effect LEAD-FREE SOLDER INTERFACIAL REACTION