简介:Themicroscopiceffectivechargesinmirrornuclei51Mnand51Feareinvestigatedwiththeparticle-vibrationcouplingmodelbasedontheself-consistentSkyrme-Hartree-Fockandcontinuumrandom-phase-approximationapproaches.Theisovectorpartsarepredictedtobearound0.15,andtheprotoneffectivechargesarearound1.25e,whichislessthantheempiricalvalueofeeffp=1.5e.Themicroscopiceffectivechargesinneutronrich51Mnareabout10%lessthanitsprotonrichmirror.TheseeffectivechargesarecombinedwiththeshellmodeltocalculatethereducedelectricquadrupoletransitionprobabilityB(E2)valuesin51Mnand51Fe.ItturnsoutthatthemicroscopiceffectivechargeshavewellreproducedtheB(E2)valuesanditsratiointheterminatingstates.
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简介:以正硅酸乙酯[Si(OC2H5)4,TEOS]和甲基三乙氧基硅烷[CH3Si(OC2H5)3,MFES]为前驱体,通过共水解法和两步法制备出两种不同的甲基改性氧化硅凝胶,在北京同步辐射光源(BSRF)小角X射线散射(SAXS)站测量了凝胶的散射强度,计算了凝胶的平均粒径、两相间比表面积等参数,在此基础上分析了凝胶的分形特征,发现存在两个尺度上的分形结构,分别对应于从SiO2原生颗粒到一次团聚体和从一次团聚体到簇团两种尺度。辅以透射电子显微镜(TEM)观测,证实由两种方法获得的凝胶具有非常不同的微观结构。实验证明,利用SAXS技术研究甲基改性凝胶的分形特征是获得凝胶徽观结构的有力工具。
简介:InspiteofthecurrentprevalenceoftheCVD-basedprocesses,theelectricarcremainsaninterestingprocessforthesynthesisofcarbonnanoforms,thankstoitsversatility,robustnessandeasiness.Italsoallowsperformingin-situsubstitutionofcarbonatomsbyhetero-elementsinthegraphenelattice.Ourworkaimstoestablishacorrelationbetweentheplasmaproperties,typeandchemicalcomposition(andthesubstitutionrate)oftheobtainedsingle-wallcarbonnanotubes.TheplasmawascharacterizedbyopticalemissionspectroscopyandtheproductswereanalyzedbyhighresolutiontransmissionelectronmicroscopyandcorelevelElectronEnergy-LossSpectroscopy(EELS).Resultsshowthatahighboroncontentleadstoaplasmatemperaturedecreaseandhinderstheformationofnanotubes.Thiseffectcanbecompensatedbyincreasingthearccurrentand/oryttriumcontent.Theoptimalconditionsforthesynthesisofboron-and/ornitrogen-substitutednanotubescorrespondtoahighaxialplasmatemperatureassociatedtoastrongradialgradient.EELSanalysisconfirmedthattheboronincorporatesintothegraphemelattice.
简介:利用角分辨紫外光电子谱对乙烯和乙炔气体在Ru(1010)表面的吸附及与K的共吸附的研究结果表明:当衬底温度超过200K,乙烯即发生脱氢反应,σCH和σCC能级均向高结合能方向移动。在室温下,σCH和σCC能级位置与乙炔在Ru(1010)表面的吸附时的分子能级完全一致。乙烯发生脱氢反应后的主要产物为乙炔。衬底温度从120K到室温,Ru(1010)表面上乙炔的σCH和σCC能级均未发现变化。室温下乙炔仍然可以在Ru(1010)表面以分子状态稳定吸附。在有K的Ru(1010)表面上,室温时σCC谱峰几乎。碱金属K的存在促进了乙炔的分解。