简介：Afteraconciseintroductionofhydrogenbondingeffectsinsolute-soluteandsolute-solventbonding,thedesignofpolymericadsorbentsbasedonhydrogenbonding,selectivityinadsorptionthroughhydrogenbonding,andcharacterizationofhydrogenbondinginadsorptionandseparationwerereviewedwith28references.

简介：Theadsorptionisothermsofcaffeinefromaqueoussolutionontothreehydrogendonatingadsorbents-hydroxypolystyrene,polystryene-azo-pyrogallol,andD72resin-weremeasured.TheadsorptionenthalpiescalculatedfromtheisothermsaccordingtotheClausisu-Clapeyronequationwere-24-36kJ/mol,-32-37kJ/mol,and-19-24kJ/molrespectively.Thesevaluesimpliedthattheadsorptionprocesseswerebasedonhydrogenbonding.Furthermore.themechanismoftheadsorptionofcaffeineontoD72resinwasstudiedbyIRspectraandthesmallmolecularmodelexperiments,andtheresultsshowedthattheadsorptionofcaffeineontohydrogendonatingadsorbentswasbasedonhydrogenbonding.

简介：Twohydrogen-bondingadsorbents-macroporouscrosslinkedpoly(P-nitrostyrene)andpoly(p-vinylbenzylamide)-weresynthesized,andtheadsorptionpropertyofphenolfromcyclohexanesolutionontotheadsorbentswasstudied,ThedifferentialadsorptionheastsforvariedadsorptioncapacitiescalculatedfromtheadsorptionisothermsaccordingtotheClaperyron-Clausiusequationlayintherangeofhydrogenbondenergy(8-50kJ/mol),Theadsorptioncapaccityofo-nitrophenolincyclohexanewasmochlessthanthatofphenolunderthesamecondition.Theadsorptioncapacityofphenolfromcyclohexaneontopolyacrylonitrilewasmuchlessthanthatontopoly(p-nitrostyrene)orpoly(p-vinylbenzylamide),Alltheseresultsrevealedthatadsorptionofphenolfromcyclohexanebypoly(p-nitrostyrene)orpoly(p-vinylbenzylamide)isbasedonhydrogen-bonding.