简介：采用水热法合成了一个新的分子式为[Pb（phen）2（NO3）]·NO3的金属-有机配合物（phen=1,10-邻啡啰啉）,并对其进行了元素分析、红外光谱表征和X射线单晶衍射的结构解析.该配合物（C24H16N6O6Pb）属于单斜晶系,空间群为P21/n,晶体学数据：a=16.7035（12）,b=7.7341（5）,c=18.1198（13）,β=98.1860（10）,V=2317.0（3）3,Mr=691.62,Dc=1.983g/cm3,μ（MoKα）=7.337mm-1,F（000）=1328,Z=4.直接法解析原子位置的结果显示：R=0.0269,wR=0.0533.该配合物具有零维网状结构.
简介：BondingofAl2O3tocuisperformeddirectlyusingTifoilattemperatureof1273K.Themicrostructureofthejointinterfaceisinuestigatedthroughscanningelectronmicroscope（SEM）,electron.probemicroanalysis（EPMA）andX-raydiffraction（XRD）.theeffectoftheinitialtifoilthicknessonthereactionlayerthicknessandthejointStrengthareinvestigated.
简介：Anewμ3-Otriiron（Ⅲ）complex[Fe3O（OBz）6（CH3OH）3]（NO3）（CH3OH）2（HOBZ=benzoicacid）hasbeensynthesized,itsstructurehasbeendeterminedandvariabletemperaturemagneticsusceptilityhasalsobeenmeasured.Inthemolecule,threeironatomsformedanequilateraltrianglewithu3-Oincenter.ThefittingtothemagneticsusceptibilityshowedthatanintramolecularantiferromagneticexchangeinteractionoccurredbetweenironatomswithJ=-25.51cm-1,andaweakerintermolecularantiferromagneticexchangeinteractionoccurredwithzJ’=-2.30cm-1.
简介：Thesinglecrystalofthecomplex[Sc（NO3）3（H2O）2]·（15C5）hasbeenpreparedinacetonitrile.Thenewcomplexhasbeencharacterizedbyelementalanalysis,IRspectra,solubilityandmolarconductancemeasurements.ThestructureofthecomplexisdeterminedbysinglecrystalX-raydiffractionanalysis.
简介：ThecrystalstructureofDi-nitratobis（ethylcaprolactam）uranyl（Ⅱ）UO2[CH2（CH2）4CONC2H5]2（NO3）2wasestablishedbyasingle-crystalX-raydiffractionstudy.Itistriclinie,spacegroupP1,witha=7.171（2）,b=8.655（3）,c=10.182（5）A,α=78.27（3）,β=70.63（3）,γ=81.76（3）°,V=581.7（4）A3,Z=l,Dc=1.94g.cm-3.FinalRvalueis0.0218.Theresultrevealsthaturanylioniscoordinatedtosixoxygenatoms,twoofthemarefromtwocarbonylgroupsofethylcaprolactamandtheotherfourarefromtwonitrategroups.
简介：Kineticsofchloride/sulfate,chloride/nitrateandnitrate/sulfateforwardexchangesandreverseexchangesatsolutionconcentrationsof1N,0.2Nand0.02Non201×7strongbaseanionexchangeresin,respectively,havebeenexaminedat25℃.Itisfoundthattheforwardandthereverseexchangeratesofthetwogivenionsatlowsolutionconcentration,respectively,underidenticalconditionscanbecontrolledbydifferentmechanisms,whilethoseathighsolutionconcentrationareallcontrolledbyparticlediffusion.Theternaryexchangeratesofsulfate/(chloride+nitrate)andnitrate/(chloride+sulfate)havealsobeenexamined.
简介：TherelationshipofelectricalpropertiesofMn-dopedBa0.92Ca0.08TiO3PTCR(positivetemperaturecoefficientresistance)ceramicswithtwosinteringscheduleswasdiscussed.UsingTEM(transmissionelectronmicroscope)combinedwithEDS(energydispersiveX-rayspectrometer),theMnionsdistributedatgrainboundarieswereanalyzed.TheresultsshowthatthePTCReffectofMn-dopedPTCRceramicsismoredependentonthesinteringschedulethanthoseofMnfree.ThephenomenonmaybecausedbythevalencestatesvarianceofMnionssegregatedatthegrainboundaries.
简介：研究了ＹＢａＣｕ３Ｏ６～７超导催化剂上ＣＯ２的加氢制醇反应。考察了温度、压力和空速等条件对催化剂反应性能的影响。反应的主要产物是甲醇、ＣＯ和少量甲醚。利用ＸＰＳ、ＸＲＤ和ＡＦＭ等技术对催化剂的结构、铜的存在状态和反应活性位进行表征发现，在反应过程中，ＹＢａ２Ｃｕ３Ｏ６～７由ｏｒｔｈｏｍｂｉｃ相转变为ｔｅｔｒａｇｏｎａｌ相。反应活性位可能是Ｃｕ（Ｉ）物种。反应后催化剂颗粒的分散程度明显提高
简介：VariousopticalluminescencespectroscopictechniqueswereusedtocharacterizethehighTcsuperconductorYBa2Cu3Ox.TheemissionbandsrevealthatCu3+coexistwithCu2+andCu+inthismaterial.
简介：ＳｃａｎｎｉｎｇＥｌｅｃｔｒｏｎＭｉｃｒｏｓｃｏｐｙＳｔｕｄｉｅｓｏｆＹＢａ＿２Ｃｕ＿３Ｏ＿（７－δ）ＳｕｐｅｒｃｏｎｄｕｃｔｏｒｓＳｈａＷｅｉ（沙维）（ＤｅｐａｒｔｍｅｎｔｏｆＣｉｖｉｌＥｎｇｉｎｅｅｒｉｎｇ，ＴｈｅＱｕｅｅｎ′ｓＵｎｉｖｅｒｓｉｔ...
简介：本文通过高分辨X射线衍射及掠入射(GID)的实验方法对生长在SrTiO3衬底上的LLa2/3Ca1/3MnO3和YBaCu3O7单层膜及YBa2Cu3O7-x/La2／3Ca1／3MnO3异质结构双层薄膜的微结构进行了研究。结果发现，所有薄膜都呈c向生长。由于热膨胀系数的不同而引起的热应力使得LCMO膜的晶格参数与靶材的相差较大。La2/3Ca1/3MnO3在单层腹及双层膜中都由靶材的立方结构变成了薄膜状态的四方结构。YBa2Cu3O7在单层膜及双层膜中都由靶材的正交结构变成了薄膜状态的四方结构。La2/3Ca1/3MnO3膜与YBa2Cu3O7膜在不同的样品中处于不同的应力状态。
简介：AnewlayeredCu-basedoxychalcogenideBa3Fe2O5Cu2S2hasbeensynthesizedanditsmagneticandelectronicpropertieswererevealed.Ba3Fe2O5Cu2S2isbuiltupbyalternativelystacking[Cu2S2]2-layersandironperovskiteoxide[（FeO2）（BaO）（FeO2）]2-layersalongthecaxisthatareseparatedbybariumionswithFe3+fivefoldcoordinatedbyasquare-pyramidalarrangementofoxygen.Fromthebondvalencearguments,weinferredthatinlayeredCuCh-based（Ch=S,Se,Te）compoundsthe+3cationinperovskiteoxidesheetprefersasquarepyramidalsite,whilethelowervalencecationprefersthesquareplanarsites.Thestudiesonsusceptibility,transport,andopticalreflectivityindicatethatBa3Fe2O5Cu2S2isanantiferromagneticsemiconductorwithaNe′eltemperatureof121Kandanopticalbandgapof1.03eV.Themeasurementofheatcapacityfrom10Ktoroomtemperatureshowsnoanomalyat121K.TheDebyetemperatureisdeterminedtobe113K.TheoreticalcalculationsindicatethattheconductionbandminimumispredominantlycontributedbyO2pand3dstatesofFeionsthatantiferromagneticallyarrangedinFeO2layers.TheFe3dstatesarelocatedatlowerenergyandresultinanarrowbandgapincomparisonwiththatoftheisostructuralSr3Sc2O5Cu2S2.
简介：介绍一种金属/合金的生产方法,用于恒电流和恒电位条件下由混合硫化物(Cu2S,NiS)生产Cu-Ni合金,称为直接电化学还原(DER)。研究槽电压和槽电流等工艺参数对还原得到的化合物组成的影响,以生产工业所需的CuNi10,CuNi20和CuNi30等合金。在1200°C下采用循环伏安法(CV)考察Cu2S和NiS在CaCl2熔体中的电化学行为。根据CV研究结果,Cu2S的阴极还原是一步完成的,即Cu2S?Cu;NiS的阴极还原则分两步进行,即NiS?Ni3S2?Ni。恒电流研究表明,在10A电流下电解15min,可制备出最高硫含量为320×10-6的高纯CuNi10合金。扫描电子显微镜以及能量色散X射线能谱和光学发射光谱(OES)测试结果表明,在2.5V电压下直接电化学还原15min,可制备出杂质含量低(即硫含量小于60×10-6)的所选成分的Cu-Ni合金。
简介：FieldlysimetermethodwasemployedtoinvestigatethedownwardmovementandleachingofNappliedtosummercorn(ZeamayL.)ondrylandsoilinBeijing,AN-fertilizer(120kgNhm^-2)andacontroltreatmentwerarrangedforthestudy.Soilsolutionwascollectedatdepthsof20,40,60,120and170cm,whileleachtewasollectedatthebottom(220cm)ofthelysimeter,TheresultsshowedthatthedownwardmovementofNO3^-Ninsoilprofilewasgreatlyaffectedbyrainfallpattern.ThepeakofleachedNO3^-Nfrombothtreatmentscoincidedwiththepeakoftherainfall.Inaddition,leachedNO3^-Nfrombothtreatmentsandrainfallweresignificantlycorrelated(P<0.05).TheamountofleachedNO3^-NwasnotgreatintheN-fertilizertreatment,TheresultsalsosuggestedthatNfertilizationcouldcauseNO3^--Ncontaminationofgroundeaterduringtherainyseason.
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![零维配合物[Pb（phen）<b style='color:red'>2</b>（<b style='color:red'>NO3</b>）]·<b style='color:red'>NO3</b>的水热合成及晶体结构](/image/thesis0 "零维配合物[Pb（phen）<b style='color:red'>2</b>（<b style='color:red'>NO3</b>）]·<b style='color:red'>NO3</b>的水热合成及晶体结构")
![The structure and magnetic properties of μ<b style='color:red'>3</b>-oxotriiron（Ⅲ） complex [Fe<b style='color:red'>3</b>O（OBz）6（CH<b style='color:red'>3</b>OH）<b style='color:red'>3</b>]（<b style='color:red'>NO3</b>）（CH<b style='color:red'>3</b>OH）<b style='color:red'>2</b>](/image/thesis4 "The structure and magnetic properties of μ<b style='color:red'>3</b>-oxotriiron（Ⅲ） complex [Fe<b style='color:red'>3</b>O（OBz）6（CH<b style='color:red'>3</b>OH）<b style='color:red'>3</b>]（<b style='color:red'>NO3</b>）（CH<b style='color:red'>3</b>OH）<b style='color:red'>2</b>")
![STUDIES ON RARE EARTH COMPLEXES WITH CROWN ETHERS ⅩⅧ——Synthesis,Characterization and Crystal Structure of[Sc（<b style='color:red'>NO3</b>）<b style='color:red'>3</b>（H<b style='color:red'>2</b>O）<b style='color:red'>2</b>]·（15-Crown-5）](/image/thesis5 "STUDIES ON RARE EARTH COMPLEXES WITH CROWN ETHERS ⅩⅧ——Synthesis,Characterization and Crystal Structure of[Sc（<b style='color:red'>NO3</b>）<b style='color:red'>3</b>（H<b style='color:red'>2</b>O）<b style='color:red'>2</b>]·（15-Crown-5）")
![CRYSTAL STRUCTURE OF DI - NITRATOBIS（ETHYLCAPROLACTAM）URANYL（Ⅱ） UO<b style='color:red'>2</b>[CH<b style='color:red'>2</b>（CH<b style='color:red'>2</b>）4CONC<b style='color:red'>2</b>H5]<b style='color:red'>2</b>（<b style='color:red'>NO3</b>）<b style='color:red'>2</b>](/image/thesis6 "CRYSTAL STRUCTURE OF DI - NITRATOBIS（ETHYLCAPROLACTAM）URANYL（Ⅱ） UO<b style='color:red'>2</b>[CH<b style='color:red'>2</b>（CH<b style='color:red'>2</b>）4CONC<b style='color:red'>2</b>H5]<b style='color:red'>2</b>（<b style='color:red'>NO3</b>）<b style='color:red'>2</b>")
