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26 个结果
  • 简介:UsingtheefectiveHamiltonianmethod,weanalyzetheB0-ˉB0mixingintheextensionofthestandardmodel(SM)wherebaryonnumberandleptonnumberarelocalgaugesymmetries.ThenumericalresultsindicatethecorrectionfromtheextraparticlestothemassdiferencemBissignificant.Thereisa60%enhancementcomparedtotheSMpredictionformBatmost,whichagreeswiththecurrentexperimentalresult.

  • 标签: 重子数 混合 轻子 有效哈密顿方法 标准模型 计算结果
  • 简介:WestudyproductionofthetetraquarkstateTccviavirtualphotonattheB-factoriesintheQCDfactorizationframework.WepredictthecrosssectionoftetraquarkstateproductionintheleadingorderattheB-factories.

  • 标签: TCC 工厂 夸克 生产 QCD因子化 虚光子
  • 简介:Inthispaper,blendmembranesfrompolyvinylacetate(PVAc)andblockcopolymerpoly(amide-12-b-ethyleneoxide)(Pebax1074)arepreparedbysolutioncastingandsolventevaporationmethod.Althoughtheyarehomogeneousonamacro-scale,theobservationsfromDSCandSEMindicatemicro-phaseseparationforPVAc/Pebax1074blendmembranes.WiththeincreaseofPebax1074content,gaspermeabilitiesofCO2,H2,N2andCH4allincreasegreatly.PVAc/Pebax1074blendmembraneswithhighPVAccontentareappropriateforCO2/CH4separation.Thetemperaturedependenceofgaspermeabilityisdividedintorubberyregionandglassyregion.Theactivationenergiesofpermeationinrubberyregionaresmallerthanthoseinglassyregion,andtheyalldecreasewithincreasingPebax1074content.ForN2,H2andCH4,theirgaspermeationpropertiesaremainlyinfluencedbythedual-modesorptionandhydrostaticpressureeffect.ButforCO2,itspermeabilityincreaseswiththeincreaseofpressureduetoCO2-inducedplasticizationeffect,whichismoreobviousforPVAc/Pebax1074blendmembraneswithhighPVAccontent.

  • 标签: polyvinyl acetate poly(amide-12-b-ethylene oxide) blend membrane
  • 简介:Directconversionoffructose-basedcarbohydratesto5-ethoxymethylfurfural(EMF)catalyzedbyLewisacidinethanolwasinvestigated.ItwasfoundthatBF3(Et)2Owasfavorablefor5-hydroxymethylfurfural(HMF)etherificationtoEMF.BF3(Et)2OcombinationwithAlCl36H2Owiththemolarratioof1wasaneffectivecatalystsystemforsynthesisofEMFfromfructose-basedcarbohydrates.55.0%,45.4%and23.9%ofEMFyieldswereobtainedfromfructose,inulinandsucroseunderoptimizedconditions,respectively.

  • 标签: 碳水化合物 直接转换 酸催化 果糖 乙醇 羟甲基糠醛
  • 简介:Micro-mesoporouscompositemolecularsievesH-ZSM-5/MCM-41werepreparedbythehydrothermaltechniquewithalkali-treatedH-ZSM-5zeoliteasthesourceandcharacterizedbyscanningelectronmicroscopy,transmissionelectronmicroscopy,energydispersivespectroscopy,X-raydiffraction,N2adsorption-desorptionmeasurementandNH3temperature-programmeddesorption.ThecatalyticperformancesforthemethanoldehydrationtodimethyletheroverH-ZSM-5/MCM-41wereevaluated.Amongthesecatalysts,H-ZSM-5/MCM-41preparedwithNaOHdosage(nNa/nSi)varyingfrom0.4to0.47presentedexcellentcatalyticactivitywithmorethan80%methanolconversionand100%dimethyletherselectivityinawidetemperaturerangeof170—300℃,andH-ZSM-5/MCM-41preparedwithnNa/nSi=0.47showedconstantmethanolconversionofabout88.7%,100%dimethyletherselectivityandexcellentlifetimeat220℃.Theexcellentcatalyticperformanceswereduetothehighlyactiveanduniformacidicsitesandthehierarchicalporosityinthemicro-mesoporouscompositemolecularsieves.ThecatalyticmechanismofH-ZSM-5/MCM-41forthemethanoldehydrationtodimethyletherprocesswasalsodiscussed.

  • 标签: HIERARCHICAL POROSITY H-ZSM-5 composite molecular SIEVE
  • 简介:为实现2×5GW级双路输出超宽谱高功率微波驱动源的小型化,研制了一种初级脉冲功率源——与双筒脉冲形成线(Blumlein线)相配一体化的带有开路磁芯的Tesla变压器.通过对Tesla变压器的理论分析,并根据简化的磁路模型得出了Tesla变压器初、次级线圈电感等电参数的估算方法,给出了Tesla变压器磁芯截面的估算和磁芯制作方法.实验结果表明,Tesla变压器最大输出电压为880kV,充电时间约为20μts,耦合系数约为0.95,与理论值吻合较好.

  • 标签: TESLA变压器 初级线圈 次级线圈 开路磁芯
  • 简介:利用基于密度泛函的第一性原理对Zr5Te3化合物晶格常数、形成焓、弹性常数、以及电子态密度等性质进行了计算。在该研究中,为了获得Zr5Te3化合物的结构稳定性,考虑了Cr5B3、W5Si3以及Mn5Si3等三种结构类型,计算的形成焓表明:具有Cr5B3结构类型的Zr5Te3最稳定,其次是Mn5Si3型,最后才是W5Si3型。也对该化合物的电子态密度和电荷密度差进行了计算,利用徳拜模型计算了其在高温高压下的体积、体积模量、热熔以及热膨胀等的热物理性质。

  • 标签: 热物理性质 弹性性质 电子结构
  • 简介:Removalofcarbonylsulfide(COS)fromCO2streamissignificantfortheproductionandutilizationoffoodgradeCO2.ThisstudyinvestigatestheadsorptionperformanceofAg/NaZSM-5asadsorbentpreparedbyincipientwetnessimpregnationfortheremovalofCOSfromaCO2streaminafixed-bedadsorptionapparatus.Effectsofvariousconditionsonthepreparationofadsorbent,adsorptionanddesorptionwereintensivelyexamined.TheresultsrevealedthatCOScanberemovedtobelow1×10-9fromaCO2stream(1000ppmCOS/CO2)usingAg/NaZSM-5(10wt%AgNO3)withanadsorptioncapacityof12.86mg·g-1.Theadsorbentcanbefullyregeneratedusinghotairat450C.Theadsorptionabilityremainedstableevenaftereightcyclesofregeneration.

  • 标签: CARBONYL SULFIDE adsorption π-complexation COMPLETELY regeneration
  • 简介:COandformaldehyde(HCHO)oxidationreactionswereinvestigatedovermesoporousAg/Co3O4catalystspreparedbyone-pot(OP)andimpregnation(IM)methods.Itwasfoundthattheone-potmethodwassuperiortotheimpregnationmethodforsynthesizingAg/Co3O4catalystswithhighactivityforbothreactions.ItwasalsofoundthatthecatalyticbehaviorofmesoporousCo3O4andAg/Co3O4catalystsforthebothreactionswasdifferent.AndtheadditionofsilveronmesoporousCo3O4didnotalwaysenhancethecatalyticactivityoffinalcatalystforCOoxidationatroomtemperature(20C),butcouldsignificantlyimprovethecatalyticactivityoffinalcatalystforHCHOoxidationatlowtemperature(90C).Thehighsurfacearea,uniformporestructureandtheprettygooddispersiondegreeofthesilverparticleshouldberesponsiblefortheexcellentlow-temperatureCOoxidationactivity.However,forHCHOoxidation,theadditionofsilverplayedanimportantroleintheactivityenhancement.AndthesilverparticlesizeandthereducibilityofCo3O4shouldbeindispensableforthehighactivityofHCHOoxidationatlowtemperature.

  • 标签: MESOPOROUS materials Co3O4 AG CO OXIDATION
  • 简介:利用质谱法定量分析了^6Li(n,α)T反应中伴随产生的^4He核,得到了产氚量。采用自膨胀密封方法在常温下定量制备了密封锂铅合金靶。靶件在西安脉冲堆的跑兔辐照通道内辐照了2h,冷却15d后进行测量。建立了去除氢同位素干扰的气体样品处理平台,并以含氢的模拟标准气进行了验证。研究并建立了测量。He的在线同位素稀释法,并用空气进行了验证。靶件在700℃被熔融后释放^4He,首次熔融的^4He释放率达到99.9%,产氚量测量结果的不确定度小于6%。

  • 标签: ^6LI ^4He 质谱
  • 简介:Inordertoinvestigatethefiresuppressioneffectivenessofwatermistwithmetalchlorideadditives,ultrafinewatermistsofthesesaltswithdiametersabout10μmwereintroducedintoCH4/airnon-premixedflameinthecupburner.Resultsshowedthatthesedropletshardtomakeitselftotheflamefrontunderthecupburnerflowconditionsfunctionedasacarrierofthevaporizedsolidparticlesoritsdecomposedmaterials.Themetalchlorideimprovedfiresuppressionefficacyofwatermistwhichwereaffectedbythetypeandconcentrationofmetalchloride.Onamassbasis,thereisafiresuppressioneffectivenessrelationshipofMgCl2

  • 标签: additive water MIST FIRE suppression CH4
  • 简介:MesoporousLiFePO4/Ccompositescontaining80wt%ofhighlydispersedLiFePO4nanoparticles(4-6nm)werefabricatedusingbimodalmesoporouscarbon(BMC)ascontinuousconductivenetworks.TheuniqueporestructureofBMCnotonlypromisesgoodparticleconnectivityforLiFePO4,butalsoactsasarigidnano-confinementsupportthatcontrolstheparticlesize.Furthermore,thecapacitieswereinvestigatedrespectivelybasedontheweightofLiFePO4andthewholecomposite.Whencalculatedbasedontheweightofthewholecomposite,itis120mAh·g-1at0.1Cofthehighloadingelectrodeand42mAh·g-1at10Cofthelowloadingelectrode.TheelectrochemicalperformanceshowsthathighLiFePO4loadingbenefitslargetapdensityandcontributestotheenergystorageatlowrates,whiletheelectrodewithlowcontentofLiFePO4displayssuperiorhighrateperformance,whichcanmainlybeduetothesmallparticlesize,gooddispersionandhighutilizationoftheactivematerial,thusleadingtoafastionandelectrondiffusion.

  • 标签: LiFePO4 HIGH loading fast ion diffusion