Study on Modified Y Zeolites and Their Behaviors in Selective Adsorptive Desulfurization of FCC Gasoline (Ⅰ)

(整期优先)网络出版时间:2009-04-14
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<正>NaYzeolitewasmodifiedthroughdealuminationwithoxalicacid,andtheHYzeolitewasobtainedbycalcinationofthemodifiedNaYzeolite.Thezeolitemoldingprocesswascarriedoutatambienttemperature(25℃),andtheinfluenceofsolid/fuelmassratioandadsorptivedesulfurizationtimeontheHYzeolitewereinvestigatedthroughtestsonstaticselectiveadsorptivedesulfurizationofFCCgasolinecontainingorganicsulfurcompounds(withaScontent=135ppm).ThesulfurcontentandsulphidetypesintheFCCgasolinewereanalyzedbyaGC2010sulfuranalyzerandaGC-SCDchromatograph.ThetestresultsshowedthatthemoldedHYzeolitewasbetterthantheunmoldedHYzeolite.AtastaticadsorptivedesulfurizationtimeonthemoldedHYzeoliteequatingto6hours,asolid/fuelmassratioof1:3,thesulfurcontentofFCCgasolinewasdecreasedto30ppm,andthedesulfurizationratewasequalto78%.WhenthebreakthroughpointofthemoldedHYwasequalto50ppm,themoldedHYzeolitewascapableofadsorbing4.86mgofsulfurpergramofadsorbent.AndtheregenerationrateofmoldedHYzeolitewasequalto98%.