NETWORK CROWN ETHER POLYMERS WITH CENTRIC FUNCTIONAL GROUP (Ⅳ) SYNTHESIS OF NETWORK CROWN ETHER POLYMER WITH PENDANT DIETHYLAMINO THIAALKYL GROUP AND ITS PLATINUM COMPLEX

Thetitlepolymerwaspreparedfrom5-diethylamino-3-thia-pentylglycidyletheranddiethyleneglycolbisglycidyletherviaring-openingcopolymerization.Itwasfoundthatthisreactioncouldbecatalyzedbysodium,butnotLewisacid.Theobtainedpolymercancoordinatewithplatinumcompound,andtheplatinumcomplexisanewkindofcatalystforthehydrosilylationofolefinswithtriethoxysilane.