ThisstudypresentsanovelprocessofinsitusurfacemodificationofCaCChnanoparticlesusingamultipleorificedispersionmicroreactor.CO2/Ca（OH）2precipitationreactionwasemployedtoprepareCaCO3nanoparticleswithsodiumstearatesurfactant.SynthesizedCaCChproductswerecharacterizedbythermogravimetricanalysis（TGA）,infra-red（IR）,X-raydiffraction（XRD）,transmissionelectronmicroscopy（TEM）andBrunauer-Emmet-Telleranalysis（BET）.Theeffectofvariousoperationparametersonnanoparticlesandthedosageofsodiumstearateweredetermined.Theresultsshowedthatthepreparationprocesscouldbepreciselycontrolledwithefficientmasstransferprocess.Theparticleswerehighlyhydrophobicwithacontactangleof117andmonodispersewithanaveragesizeof30nm.Theadsorptionsofsodiumstearateandcalciumiononsolidparticlesduringtheinsitusurfacemodificationprocesswereinvestigated.
