摘要
Forthegoalofsulfurrecovery,mostmethodsareaimedatthetailgaswithhigh-concentrationH2S,butfeweffectivemethodsareusedforlow-concentrationH2S.Inthiswork,Low-concentrationH2Scouldbepurifiedwellbyliquidphasecatalyticoxidation(LCO),andthesulfurresourcecouldalsoberecovered.TheabsorptionsolutionwaspreparedbyFeCl3andsulfosalicylicacid.Undertheexperimentalconditions,theconversionofH2StoScouldbemaintainedabove94%at60℃.InordertoenhancetheeconomicalefficiencyofLCOmethod,theabsorptionsolutionwasmodifiedbydopingCe,andaseriesofexperimentsweredesignedtoinvestigateitsperformance.TheresultsshowedthattheconversionofH2Shadnoobviousimprovement,butabove98%conversioncouldbegainedat60℃,andtheH2Sconversionratewasenhanced.TheoptimumadditionqualityofCe(NO3)3was0.08gto50mlFe3+solution.
出版日期
2007年03月28日(中国期刊网平台首次上网日期,不代表论文的发表时间)