简介：Thephotoinitiatingsystemcomposedof1-ethyl-3’-methylthiacyaninebro-mide(C-I),2-chlorohexaarylbiimidazole(o-Cl-HABI)and3-mercapto-4-methyl-4H-1,2,4-triazole(MTA),whichactassensitizer,initiatorandhydrogen-donorrespectively,canbeusedtoinitiatethepolymerizationofmethylmethacrylate(MMA).Thekineticstudywascarriedoutintrichloromathanesolutionat30℃byusingdilatometry.Therelationbe-tweenthepolymerizationrateandtheconcentrationsofC-I,o-Cl-HABI,MTAandMMAwasstudied.

简介：

简介：

简介：Threepolymericadsorbentswithhydrogenbondingacceptors,methylamine,N-methyl-acetamideandaminotri(hydroxymethyl)methanemodifiedresinsaresynthesizedfromchloromethylatedX-5resin.AdsorptionisothermsofphenolandtheophyllineontothethreemodifiedresinsandtheoriginalX-5resinfromaqueoussolutionaremeasured.TheresultsshowthatadsorptionofcompoundswithhydrogenbondingdonorontomethylamineandN-methylacetamidemodifiedresinsisenhancedascomparedwiththatontoX-5resin,andadsorptionmechanismbetweentheadsorbentsandtheadsorbatesismainlybasedonhydrogenbondingandhydrophobicinteraction.Whileadsorptionofcompoundswithhydrogenbondingdonorontoaminotri(hydroxymethyl)methanemodifiedresinisloweredascomparedwiththatontoX-5resin,andadsorptionmechanismbetweentheadsorbentandtheadsorbatesismainlybasedonhydrophobicinteraction.

简介：在这个工作，综合体新热地稳定(amide-imide)poly，有在n丁基甲基imidazolium溴化物的悬挂的2-pyridyl-1,3,4-oxadiazole单位的s作为反应媒介被报导了。新二羟基的酸从肼的反应被导出，2-(5-(3,5-diaminophenyl)-1,3,4-oxadiazole-2-yl)pyridine(POBD)，和trimellitic酸酐。聚合物在丁基甲基imidazolium溴化物从diimide二酸(DIDA)和不同的芳香的肼的反应被准备，[bmim][Br]，面对triphenyl亚磷酸盐(TPP)作为没有需要任何额外的部件的压缩代理人。poly准备了(amide-imide)s被FTIR描绘，元素的分析，并且通过模型混合物的合成。准备聚合物是可溶的在极并且aprotic溶剂例如DMF，DMSO，NMP和DMAc。聚合物答案的固有的粘性在在0.125g/dL的集中在集中的H2SO4测量在的0.521.33dL/g的范围(25

简介：

简介：Poly(methylmetacrylate)(PMMA)/Y0.0025Si0.025Ba0.9725(Ti(0.9)Sn0.1)O3(YBTS)composites在YBTS的不同重量比率被准备(0wt%，5wt%，10wt%和20wt%YBTS)招待以便在PMMA的电、光的性质上调查YBTS增加的效果。电的性质(阻抗，绝缘的经常的绝缘的损失和交流电导率)在频率范围被学习10kHz-1MHz并且在温度范围20鈥?0掳C。在增加YBTS的内容之上陶器，我们在在绝缘的经常的、绝缘的损失和PMMA的交流电导率的阻抗和增加观察了减小主人。我们也发现在高YBTS内容的松驰过程由于在离子的传导性的松驰。吸收系数(伪)在波长范围被决定了230鈥?在为所有YBTS-PMMAcomposites的房间温度的00nm。而且，YBTS的增加陶器高度特别在300nm下面提高PMMA主人的紫外吸收。对PMMA主人陶器的20wt%YBTS的增加减少从5eV的光精力差距到3.41eV。关联在之间电，光并且SEM结果被报导。关键词电-光-PMMA，陶器-铁电体-Composites

简介：Highqualitypoly(5-cyanoindole)(P5CI)filmswereelectrosynthesizedbydirectanodicoxidationof5-cyanoindoleonstainlesssteelsheetinthemixedelectrolytesofborontrifluoridediethyletherate(BFEE)anddiethylether(EE)(byvolume1:1)+0.05molL~(-1)Bu_4NBF_4.Thefilmformedcanbepeeledofftheelectrodeintofreestandingfilms.TheadditionofEEintoBFEEcanimprovethesolubilityofmonomer.P5CIfilmsobtainedfromthismediumshowedexcellentelectrochemicalbehaviorwithconductivityof10~(-2)Scm~(-1).Structuralstudiesshowedthatthepolymerizationof5-cyanoindoleoccurredatthe2,3position.As-formedP5CIfilmswerethoroughlysolubleinstrongpolarorganicsolventdimethylsulfoxide(DMSO)whilepartlysolubleintetrahydrofuran(THF)oracetone.FluorescencespectralstudiesindicatedthatP5CIwasagoodblue-lightemitter.

简介：Polymer-supportedRCpCpTiCl2(Cp=η^5-C5H4;RCp=η^5-RC5H4)havebeenpreparedandreducedbyi-C3H7MgBrinsitu，thenusedincatalyticisomerizationof1,5-hexadiene.Theisomerizationof1,5-hexadieneleadstoamixtureofcyclicandlinearproducts.Theratioofcyclictolinearproductdependsonthenatureofthesupporterandthesubstituentonthecyclopentadienylring.Theformercontributesthemost,forexample,silicasupportedCp2TiCl2gavecyclic-linearratioof99/1,whileforpolymer-supportedCp2TiCl2species,linearcompoundsarethemajorproductsandtheratioofcyclictolinearproductchangeswithdifferentRgroupsonthecyclopentadienylring.

简介：Linearpolysiloxaneswithpendantbenzo-15-crown-5moietieshavebeensynthesizedfrom3′-or4′-allylbenzo-15-C-5viahydrosilylationofmethyldichlorosilane,followedbypolycondensationwithsilanol-terminatedpolydimethylsiloxane.Itwasfoundthatthepolysiloxanescouldbeusedascarriersinbulkliquidmembranetotransportions.Factorsinfluencingtransportratehavebeeninvestigated.

简介：Ourobjectivesweretodevelopanewchemicalmethodforthepolymerizationofpyrrole.CuCl2dissolvedinC2H5OHsolventisprimarilyusedfortheinitiationpolymerizationofpyrrole.ThepolymerswithdifferentyieldandconductivitywereobtainedbyraringtheinitialconcentrationofCu2+.TheinitialconcentrationsofCu2+variedfrom1.2×10-4moleto6.48×10-3moleCu2+with2.16×10-2molepyrrole.Thepolypyrroleobtainedwascharacterizedwithelementalanalyzer,XPS,IRspectroscopy,Four-pointprobeandSEM.

简介：Inthispaper,radiation-inducedcrosslinkingmechanismandcharacterizationofthecrosslinkingdensityofF-40andF-4byX-rayphotoelectronspectroscopy(XPS)havebeenstudied.ThedoseofgelationofF-40obtainedfromXPSis4.1×10~4Gy.ItisfoundthatcrosslinkingdensityisthelargestintherangeofcertaindoseforF-40andF-4.

简介：TheimmunomodulatingeffectsofF12onmouseperitonealmacroplhageswasintendedtobestudiedwithdifferentdosesof20,40,80,and120mg/Kg.F12increasedperoxidaseactivityindexcdependentmammerfrom0.02±0.001,to0.175±0.038,0.211±0.041,0.137±0.045and0.078±0.036,respectively,increasedcytotoxicityfrom127.33±22.96to162.74±19.53,237.30±25.15,178.62±36.22and158.66±42.75dpm,respectively,promotedphagocyticactivityfrom0.03±0.01to0.21±0.016,0.43±0.041,0.40±0.032and0.30±0.160^b,Furthermore,F12inaconcentrationof15,30,60,120ug/mlenhancedIL-1productionfrom0.15±0.02to0.20±0.005^b0.21±0.02,0.22±0.005,0.24±0.002and0.22±0.02,respectively,ThusF12canbeconsideredasaneffectivestimulatorofmacrophages.

简介：Poly(3-hydroxybutyrate-co-3-hydroxyvalerate)/Organophilicmontmorillonite(PHBV/OMMT)nanocompositeswerepreparedandthebiodegradabilityofthePHBV/OMMTnanocompositeswasstudiedbyacultivationdegradingmethodinsoilsuspension.TherelationshipbetweenstructureandbiodegradabilityofPHBV/OMMTnanocompositeswasinvestigated.TheresultsshowedthatthebiodegradabilityofPHBV/OMMTnanocompositesdecreasedwithincreasingamountofOMMTanditwasrelatedtothenumberofPHBVdegradingmicroorganismsindegradationenvironment,theanti-microbialpropertyofOMMTandthedegreeofcrystallinityofthenanocomposites.

简介：TheencapsulationofstearicacidcoatednanometerCaCO3byapolystyrene(PS)networkviaemulsionpolymerizationisdescribed,whereγ-methacryloxypropyltrimethoxysilane(MPS)wasusedasanefficientcrosslinker.TheimportantfactorssuchasthetypeandamountofsurfactantandinitiatorandthecontentofCaCO3areinvestigatedaswellastheroleofMPS.IthasbeenshownthatlittlePSwasextractablewithonly0.6wt%ofMPS(relativetostyrene).Thecationicsurfactantcetyltrimethylammoniumbromide(CTAB)provedmoreeffectivethantheanionicsurfactantsodiumdodecylsulfonate(SDS).Theyieldrises,particlesbecomesmallerandsizedistributionbroadenswithincreasedamountofCTAB.Itisalsofoundthateither2,2′-azobis(isobutyronitrile)(AIBN)orammoniumpersulfate(APS)issuitableforattaininghighmonomerconversion.WithincreasedamountofCaCO3,theencapsulationratiocanbevariedfrom17.9to3.6,whilemonomerconversionandyielddecreaseslightly.FT-IRspectraoftheproductsafterextractionindicatetightencapsulationbetweenPSandCaCO3,andTEMphotographsofcompositeparticleswithwell-definedcore-shellstructuregivedirectevidenceofencapsulation.

简介：The1,1'-binaphtholbasedoligomers3and7with3,3'-acetylene-phenylene-acetylenespacerwerepreparedfromBINOL1.ThehighopticalrotationvalueandCDspectrademonstratedthemainchainchiralityoftheoligomermolecule.TheUV-VISandfluorescentspectraevidencethecharacteristicsofconjugatedstructure.Incomparisonwitholigomer2bearing3,3'-acetylenespacer,theoligomers3and7havelongerefficientconjugationsegment,andtheirfluorescentquantumyields(φ)increased(0.60-0.65versus0.14).Extendingtheeffectiveconjugationsegmentwouldimprovethephotophysicalpropertiesofchiralconjugatedpolymers.``

简介：Theeffectsofinterfacialmodifieronthemechanicalpropertiesofkaolin-filledpolyamide6(PA6)havebeenstudied.Theinterracialinteractionbetweenpolyamide6andkaolinhasbeencharacterizedbymeansofinfraredspectroscopy(IR)andscanningelectronmicroscopy(SEM).TheresultsshowthattheroleoftheinterracialmodifierliesinforminganelasticinterlayerwithgoodadhesionbetweenkaolinandPA6.Acompositewithhighimpactstrength,hightensilestrengthandhighelasticmoduluscanbeobtainedbyinsertingtheelasticinterfacialmodifierintotherigid-particle-filledpolymersystem.

简介：Blendsofpoly(3-hydroxybutyrate-co-3-hydroxyhexanoate)(PHBHHx)andpoly(butylenesuccinate-adipate)(PBSA),bothbiodegradablesemicrystallinepolyesters,werepreparedwiththeratioofPHBHHx/PBSArangingfrom80/20to20/80bymeltmixingmethod.Differentialscanningcalorimetry(DSC),thermogravimetryanalysis(TGA),dynamicmechanicalthermalanalysis(DMA),polarizingopticalmicroscopy(POM)andwideangleX-raydiffractometer(WAXD)wereusedtostudythemiscibilityandcrystallizationbehaviorofPHBHHx/PBSAblends.ExperimentalresultsindicatethatPHBHHxisimmisciblewithPBSAasshownbythealmostunchangedglasstransitiontemperatureandthebiphasicmelt.

简介：Inthispaper,thetwoeffluentsfromPBA(3-phenoxy-benzaldehyde)productionprocessweretreatedbypolymericadsorbentCHA-111.PBAorPBC(3-phenoxy-benzoicacid)wasrecoveredfromthewastewaterintheprocessofneutralization.Asasecondarytreatmentmethod,adsorptionwithCHA-111showedbetterefficiencythanphotocatolyticdecompositionandsolventextraction.Theoptimaltechnologicalparameterswere:adsorption:currentvelocity:2.0BV/hr(bedvolumeperhour),roomtemperature;desorption:currentvelocity:2.0BV/hr(bedvolumeperhour),roomtemperature;desorption:currentvelocity:1.0BV/hr,80℃,8%sodiumhydroxideaqueoussolutions.Inconclusion,99.9%CODintheneutralizingwastewaterand98.4%CODinthehydrolysiswastewaterareremovedsuccessfully.

简介：Wastewaterfromproductionprocessof2,3-acidwastreatedbyadsorptionusingmacroporousresinNDA-708.Afteronlyone-steptreatmentbyresinadsorption,removalefficiencyofthreekindsofnaphthalenechemicalswasabove99%;removaleficiencyofCODcrwasabove96%.Underproperoperatingcondition,desorptionefficiencywasaround100%.Therunningrecordsoftheindustrialfacilityshowedthatthenaphthlenechemicalsindesorptioneffluentcouldbereusedwithoutobviousinfluenceonthequalityoftheproduct.