简介:目的:喷雾气液吸收化学反应广泛存在于能源、化学和环境工程中。比如在能源环境领域,湿法烟气脱硫(WFGD)中的碱性喷雾吸收脱除气体污染物,乙醇胺(MEA)吸收脱除CO_2酸性气体。对这类反应的表征,有利于控制和改善污染物脱除效率。本文尝试利用气液吸收沉淀反应过程中液滴折射率的变化来原位表征反应进程。创新点:1.基于彩虹折射法,首次对气液吸收沉淀反应的原位表征进行探究;2.通过若干实验和详细的传热计算分析,成功验证了其可行性和有效性。方法:1.通过与Abbe折射仪对比,确定全场彩虹测量的准确性(图3和公式(5));2.搭建全局彩虹技术(GRT)测量系统进行喷雾测量实验(图2),并记录反应过程中的彩虹图像和离线采样液滴用于显微分析(图4和5);3.对涉及到的气液吸收沉淀反应进行传热计算和分析(公式(7)~(13))。结论:1.初步表明了利用溶液折射率表征Ca(OH)_2质量分数的可行性。2.实验结果表明GRT的测量结果精确;反应后液滴折射率减少并趋向于水,反应进程可体现在彩虹角(即折射率)的变化上。3.不同浓度Ba(OH)_2吸收CO_2的反应进一步证明了该方法原位表征气液吸收沉淀反应的可行性。4.反应的传热计算和分析表明反应热所造成的温度升高可以忽略,验证了该方法的有效性。
简介:Basedonloadseparationtheory,theloadseparationparameterSpbmethodisaneffectiveapproachforestimatingtheJ-resistancecurvefromrecordsofloadversusdisplacementdirectly,usingonesharpcrackedspecimenandanadditionalreferencebluntcrackedspecimen.However,theeffectofthereferencebluntcrackedspecimenonJ-resistancedeterminationwasnotexplicitlyconsideredinpastwork.Inthispaper,amodifiedloadseparationparameterSpbmethodwasdevelopedtoeliminatethiseffect,andthenauniqueestimationofinstantaneouscracklengthforonesharpcrackedspecimencouldbeobtained.Furthermore,aforcedbluntingcalibrationmethodwasalsoadoptedtodeterminetheinstantaneouscracklengthintheloadinseparableregion,referringtoanormalizationmethod.ExperimentsonsteamturbinerotatorsteelCr2Ni2MoVwerecarriedouttoestimateJ-resistancecurvesusinganunloadingcompliancemethod.Byremovingunloadandreloaddatafromload-displacementrecords,theJ-resistancecurveforthesamesharpcrackedspecimenwasestimatedusingthemodifiedseparationparameterSpbmethod.TheresultsindicatethatthemodifiedSpbmethodcompletelyeliminatestheeffectofthereferencebluntcrackedspecimenontheinstantaneouscracklengthdeterminationofthesharpcrackedspecimen.However,differentJ-resistancecurvesinasmallrangeofcrackextensionarepresentwhendifferentbluntingcoefficientsareusedinthebluntinglineequation.TheJ-resistancecurveobtainedfromthemodifiedSpbmethodagreeswellwiththatobtainedfromthecompliancemethod.
简介:Inthiswork,syngasmethanationoverNi-W/TiO2-SiO2catalystwasstudiedinafluidized-bedreactor(FBR)anditsperformancewascomparedwithafixed-bedreactor(FIXBR).Theeffectsofmainoperatingvariablesincludingfeedstockgasesspacevelocity,cokecontent,bedtemperatureandsulfur-tolerantstabilityof100hlifewereinvestigated.ThestructureofthecatalystswascharacterizedbyXRD,N2adsorptiondesorptionandTEM.Itisfoundthatundersamespacevelocityfrom5000h1to25000h1FBRgaveahigherCH4yield,lowercokecontent,andlowerbedtemperaturethanthoseobtainedinFIXBR.Ni-W/TiO2-SiO2catalystpossessedexcellentsulfur-tolerantstabilityonthefeedstockgaseslessthan500ppmH2SinFBR.ThecarbondepositsformedonthespentcatalystwereintheformofcarbonfibersinFBR,whileintheformofdenseaccumulationdistributionappearanceinFIXBR.
简介:JUNA(JinpingUndergroundlaboratoryforNuclearAstrophysics)isplaningtomeasurethe13C(α,n)16OandsomeotherimportantreactionsatorclosetostellarenergiesusingintenseheliumbeamoutofanECRdrivenacceleratorinJinpingUndergroundlaboratory[1].Deuteriumimpurityinionsourcewillproducessignificantamountofneutrons,limitingthebackgroundlevel.Tocontrolthedeteriumimpurity,wehavedevelopedamethodtomeasurethedeuteriumimpuritywithinHeliumbeamusingthed(d,p)treaction.
简介:Probingtheopticalpropertiesofmolybdenumdisulfide(MoS2)isvitaltoitsapplicationinplasmon-enhancedspectroscopy,catalysts,sensing,andoptoelectronicdevices.Inthispaper,wetheoreticallystudiedtheRamanandfluorescencepropertiesofmonolayerMoS2usingtip-enhancedspectroscopy(TES).Inthestrong-couplingTESsystem,theRamanandfluorescenceenhancementfactorscanbeturnedtoashighas4.5×108and3.3×103,respectively,byoptimizingthetip–MoS2-filmdistance.OurtheoreticalresultsnotonlyhelptodeeplyunderstandtheTESpropertiesofmonolayerMoS2,butalsoprovidebetterguidanceontheapplicationsofthenoveltwo-dimensionalmaterial.
简介:Asafundamentalpropertyofnuclei,atomicmassesarewidelyusedinmanydomainsofscienceandengineering.Areliableatomicmasstablederivedfromtheexperimentaldata,wheretheatomicmassesandtherelevantexperi-mentalinformationcanbefoundconveniently,isinhighdemandbytheresearchcommunity.Tomeetthedemands,theAtomicMassEvaluation(AME)wasinitiatedin1950'sandaseriesofAMEmasstableshavebeenpublishedeversince.CurrentlytheAMEservestheresearchcommunitybyprovidingthemostreliableandcomprehensiveinformationrelatedtotheatomicmasses.ThenewatomicmassevaluationAME2016waspublishedintheMarchissueofChinesePhysicsCastwocom-plementarypapers[1;2].
简介:134Csabranchingpointins-processpathwhichisshowninFig.1.Thebranchingratioisdefinedasfβ=λβ/(λβ+λn).Itcouldbededucedfromtheabundanceof134Baand136Basince136Bagoesthroughbothdecayandneutroncaptureof134Cswhile134Baonlyexperiencesdecaychannel[1].Duetoboth134Baand134Baarepures-processnuclei,thisbranchingpointisagoodapproachtodeterminethes-processparameters.Withtemperaturedependentβ-decayrateof134Cs,thetemperatureofs-processcouldbededuced.
简介:Multimediastreamingservedthroughpeer-to-peer(P2P)networksisboomingnowadays.However,theend-to-endstreamingqualityisgenerallyunstableduetothevariabilityofthestateofserve-peers.Ontheotherhand,proxycachingisabandwidth-efficientschemeforstreamingovertheInternet,whereasitisasubstantiallyexpensivemethodneedingdedicatedpowerfulproxyservers.Inthispaper,wepresentaP2PcooperativestreamingarchitecturecombinedwiththeadvantagesofbothP2Pnetworksandmultimediaproxycachingtechniquestoimprovethestreamingqualityofparticipatingclients.Inthisframe-work,aclientwillsimultaneouslyretrievecontentsfromtheserverandotherpeersthathaveviewedandcachedthesametitlebefore.Inthemeantime,theclientwillalsoselectivelycachetheaggregatedvideocontentsoastoservestillfutureclients.Theassociateprotocoltofacilitatethemulti-pathstreamingandadistributedutility-basedpartialcachingschemearedetailedlydis-cussed.Wedemonstratetheeffectivenessofthisproposedarchitecturethroughextensivesimulationexperimentsonlarge,Inter-net-liketopologies.
简介:HL-2Atokamak(majorradiusR=165cm,minorradiusα=38-45cm)wassuccessfullyachievedsingle-nulldivertordischargewithgoodcontrolloftheplasmacurrentandpositioninexperiment.Parametersachievedinthiscompaignwereasfollows:toroidalmagneticfieldBT=1.4T,plasmacurrentIp=168kA,plasmaelectrondensityne=1.7×10^19/m^3,plasmaexisttimetp=920ms.