简介:ResultsofinelasticneutronscatteringexperinientsandabinitiomoleculardynamicssimulationsforGeTe一theparentcompoundofphase-changematerialsarereported.TheinelasticneutronspectraofGeTepowdersampleshavebeendeterminedinthetemperaturerangeextendingfrom300to700K.Thephononpeaksundergothermalshiftsresultingfromanharmoniceffectsbeingweakerforacousticthanopticmodes.AsmallconcentrationoffreechargecarriesarisingfromthepresenceofGe-vacancieswasfoundnottoaffectsignificantlytheneutronweightedphonondensitiesofstatesofGeTe.Thespectralpatternchangesqualitativelyacrossthestructuralphasetransition,butthelocalstructureofGeTeremainshardlyaffected,asconfirmedbytheanalysisoftemperaturedependenceofthepairdistributionfunctionobtainedfromabinitiomoleculardynamicsinvestigations.Thepresenttheoreticalstudiessupportinawideextentourexperimentalobservationsandalsothoseprovidedbylocalprobemethods.
简介:Phase Transitions in Sodium ClustersPhaseTransitionsinSodiumClusters¥ZhangFengshou;E.SuraudandR.GlowinskiMostofthetheoretical...
简介:Thesolid-phasesynthesisofisoxazolineson2-polystyrylsulfonamidoethanolresinisreported.2-Polystyrylsuifonamidoethanolresin1wasreactedwithacryloylchloridetoafford2-polystyrylsulfonylamidoethylacrylateresin2,whichwasfurtherreactedwithbrominatedaldoximesby[3+2]cycioadditiontogiveisoxazolineresin4.Resin4wastreatedwithaqueous6mol/LHCIsolutiontoobtainisoxazolinesingoodyieldandpurity.
简介:Anovelmethodforconvertinganarrayofout-of-phaselasersintooneofin-phaselasersthatcanbetightlyfocusedispresented.Themethodexploitssecond-harmonicgenerationandcanbeadaptedfordifferentlaserarraysgeometries.Experimentalandcalculatedresults,presentedfornegativelycoupledlasersformedinasquare,honeycomb,andtriangulargeometriesareingoodagreement.
简介:我们理论上学习光参量的扩大(OPA)或二根弄歪阶段的激光横梁抽的啁啾的脉搏OPA(OPCPA)的阶段特征。由于空间走离开,在two-beam-pumped,光参量的扩大(TBOPA)将两个都泵阶段失真是部分转了在单个晶体发信号以便降级信号横梁质量,它将在高精力的OPCPA更严肃。有补偿walkoff的水晶对的一种OPA配置为减少在第一个阶段经验丰富的信号阶段失真并且通过第二晶体保证二泵阶段失真的信号阶段独立人士被表明,因此维持信号横梁质量。如此的TBOPA类似于借助于消除它的敏感到泵横梁的阶段和数字的常规量激光放大器。[从作者抽象]
简介:ImprovementofPhaseMeasurementSystemforHIRFL¥ZhangJianhua;LiJiandHuangZhengrongPhasemeasurementisveryimportantforacceleratorop...
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简介:Moleculardynamics(MD)simulationsoftheconsecutivecompression-decompressioncyclesofhexagonalzincsulfide(wurtzite)nanoparticlespredictanirreversiblephasetransformationtothecubicpolymorph.Thephasetransformationcommencesatthecontactareabetweentheparticleandtheindenterandproceedswiththenumberofcompressioncycles.Dislocationsarevisibleforaparticlesizeabove5nm.ResultsfromwetgrindinganddrypowdercompressionexperimentsonacommercialwurtzitepigmentagreequalitativelywithMDsimulationpredictions.X-raydiffractionpatternsrevealthattheamountofcubicpolymorphinthecompressedsamplesincreaseswithpressureappliedtothepowder.Incomparisonwithpowdercompression,wetmillingleadstoamorepronouncedphasetransformation.Thisoccursbecausetheparticlesareexposedtoalargenumberofstresseventsbycollisionwiththegrindingmedia,whichleadstotheformationofdefectsandnewsurfacecrystallitesbyparticlefracture.AccordingtotheMDsimulations,phasetransformationisexpectedtooccurpreferentiallyinsurfacecrystallitesbecausetheyexperiencethehighestmechanicalload.Becauseofthephasetransformation,thewetgroundandcompressedsamplesexhibitalowerphotoluminescenceintensitythanthefeedmaterial.Incomparisonwithpowdercompression,millingreducesthephotoluminescenceintensitymoresubstantially.Thisoccursbecauseahigherdefectconcentrationisformed.Thedefectscontributetothephasetransformationandphotoluminescencequenching.
简介:Theso-called"phasedifference"iscommonlyintroducedasaphenomenologicalparameterinRamantensortheory,soastofittheexperimentaldatawell.Althoughphasedifferenceiswidelyrecognizedasanintrinsicpropertyofcrystals,itsphysicsstillremainsambiguous.Recently,Kranertetal.havepresentedanewformalismtoexplaintheoriginofphasedifferencetheoretically.Here,wesystematicallyconductedexperimentalresearchwithpolarphononsinwurtzitecrystals,theresultsofwhichstronglysurestthatthephasedifferenceshouldbepredeterminedinaRamantensor,ratherthanbetreatedasRamantensorelementstraditionallyorasanintrinsicproperty.OnthegroundsofpinpointingexistinglogicalflawsinRamantensorstudy,weprovidealogicallyclearparadigm.
简介:Thisworkbrieflysummarizedtherecentresearcheffortsmadeonthephaseheattransferprocessesinvolvingbiologicalaggregates,withparticularattentiononthecorrelationofaggregatestructureandstateofwaterwiththeprocessefficiency.Thephasechangeprocessesincludeboiling,drying,freezing,sintering,pyrolysis,andsupercriticalextraction,whiletheformerthreewerediscussedinsomedetail.
简介:PolymerPhysicsLaboratory,InstituteofChemistry,TheChineseAcademyofSciences,Beijing100080,China