简介:Anewcompositioncontentquaternary-alloy-basedphasechangethinfilm,Sb-richAglnSbTe,hasbeenpreparedbyDC-magnetronsputteringonaK9glasssubstrate.Afterthefilmhasbeensubsequentlyannealedat200℃for30min,itbecomesacrystallinethinfilm.Thediffractionpeakofantimony(Sb)areobservedbyshallow(0.5degree)x-raydiffractioninthequaternaryalloythinfilm.Theanalysesofthemeasurementfromdifferentialscanningcalorimetry(DSC)showthatthecrystallizationtemperatureofthephasechangethinfilmisabout190℃andincreaseswiththeheatingrate.ByKissingerplot,theactivationenergyforcrystallizationisdeterminedtobe3.05eV.Thereflectivity,refractiveindexandextinctioncoefficientofthecrystallineandamorphousphasechangethinfilmsarepresented.Theopticalabsorptioncoefficientofthephasechangethinfilmsasafunctionofphotonenergyisobtainedfromtheextinctioncoefficient.Theopticalbandgapsoftheamorphousandcrystallizationphasechangethinfilmsare0.265eVand1.127eV,respectively.
简介:TheelectronicpropertiesandtopologicalphasesofThXY(X=Pb,Au,Pt,PdandY=Sb,Bi,Sn)compoundsinthepresenceofspin–orbitcoupling,usingdensityfunctionaltheoryareinvestigated.TheThPtSncompoundisstableintheferromagneticphaseandtheotherThXYcompoundsarestableinnonmagneticphases.Bandstructuresofthesecompoundsintopologicalphases(insulatorormetal)andnormalphaseswithingeneralizedgradientapproximation(GGA)andEngel–Voskogeneralizedgradientapproximation(GGAEV)arecompared.TheThPtSn,ThPtBi,ThPtSb,ThPdBi,andThAuBicompoundshavetopologicalphasesandtheotherThXYcompoundshavenormalphases.Bandinversionstrengthsandtopologicalphasesofthesecompoundsatdifferentpressurearestudied.Itisseenthatthebandinversionstrengthsofthesecompoundsaresensitivetopressureandforeachcompoundasecond-orderpolynomialfittedonthebandinversionstrengths–pressurecurves.
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简介:做Si的Ge(2)sb(2)Te(5)电影被dc劈啪作响magnetronco与Ge2Sb2Te5和Si目标准备了。在在两结晶化温度和阶段转变温度fromface-centred-cubic(fcc)的增加的Te(5)电影结果分阶段执行到的Ge(2)sb(2)的Si的增加六角形(十六进制)阶段。Ge2Sb2Te5电影的抵抗力显示出重要增加,Si做。当在这部电影做Si的11.8at.%时,在退火的460度C以后的抵抗力与undopedGe2Sb2Te5电影相比从64~99终止从1~11m终止(.)厘米和动态抵抗增加增加。这对写阶段变化随机存取记忆的当前的减小很有用。
简介:Inthispapertheelasticconstantsofgraphiteatelevatedtemperaturewereexperimentallyinvestigatedbyusingthevirtualfieldsmethod(VFM).Anewmethodwaspresentedforthecharacterizationofmechanicalpropertiesatelevatedtemperature.Thethree-pointbendingtestswereperformedongraphitematerialsbyanuniversaltestingmachineequippedwithheatingfurnace.Basedontheheterogeneousdeformationfieldsmeasuredbythedigitalimagecorrelation(DIC)technique,theelasticconstantswerethenextractedbyusingVFM.Themeasurementresultsoftheelasticconstantsat500℃wereobtained.Theeffectontheexperimentalresultswasalsoanalyzed.Thesuccessfulresultsverifythefeasibilityofusingtheproposedmethodtomeasurethepropertiesofgraphiteathightemperature,andtheproposedmethodisbelievedtohaveagoodpotentialforfurtherapplications.
简介:HighlytexturedHeusleralloyMn46Ni42Sn11Sb1ribbonswerepreparedbymeltspinning.TheannealedhighMncontentMn46Ni42Sn11Sb1ribboncross-sectionmicrostructure,crystalstructure,martensitictransformation(MT),andmagnetoresistance(MR)propertieswereinvestigated.TheMRintheannealedribbonwasassessedbythemagneticfielddirectionperpendiculartotheribbonsurfacewiththemagneticfieldupto30kOe.Thelargenegativevalueof25%forMRwasobtainedat244K.Theexchangebias(EB)effectsoftheas-spunandannealedribbonswereinvestigated.Afterannealing,theEBeffectshavebeenimprovedbyabout25Oeatthetemperatureof50K.Themagnetizationshaveincreasedapproximatelyby10%morethantheas-spunribbon.
简介:我们在Mn50Ni40SnSbx(x=1,2,3,和4)合金。所有准备样品在房间温度与空间组一起展出B2类型结构。Sb的替换增加原子价电子集中并且减少联合起来的房间体积。作为结果,当x增加,magnetostructural转变向更高的温度很快变。在在不同磁场变化下面的磁性的熵的变化在这转变附近被探索。等温的磁化曲线展出典型metamagnetic行为,显示magnetostructural转变能被一个磁场导致。悦耳的martensitic转变和磁性的熵变化建议那Mn50Ni40SnSbx合金是应用在的吸引人的候选人固态制冷。
简介:Anewcompoundbasedonpolyoxovanadate[{Ni(en)2}2Sb8V14O42]·5.5H2O(en=ethylenediamine)(1)wassynthesisedhydrothermallyasblackrhombuscrystals.Compound1crystallizedinthemonoclinicsystemwithspacegroupP21/n,Z=4,a=1.46953(9)nm,b=1.28623(8)nm,c=1.76008(11)nm,β=105.7230(10)°.Intheasymmetricunit,cluster{Sb8V14O42}canbeconsideredasanSbderivativeofthe{V18O42}unit.Each{Sb8V14O42}clusterasabuildingblockinterconnectedtofourotherneighboringunitsby{Ni(en)2}bridginggroupswhicharelinkedthroughtheterminaloxygenatomsofthepolyoxoanions,formingatwodimensionalnetwork.
简介:研究了电感耦合等离子体原子发射光谱(ICP-AES)法测定南红玛瑙中As、Cd、Cr、Pb、Sb元素含量的分析方法。通过对前处理方法的选择、分析线的选择、基体干扰方面的研究,确定了分析条件,并对比研究了标准曲线法与标准加入法在测定方面的异同。标准加入法与标准曲线法的测定结果相近,但标准曲线法的测定结果总是比标准加入法的测定结果小。在标准加入法中,各元素加标回收率在93.6%~103%,测定值的相对标准偏差(RSD,n=6)小于10%;在标准曲线法中,各元素加标回收率在90.2%~103%,各元素的相对标准偏差(RSD,n=6)也均小于10%。基体效应对标准曲线法测定存在一定的影响,但不十分明显。标准加入法可以很好地减轻基体效应的干扰,但不可大批量测定样品。因此,在分析控制质量要求允许范围内,可采用标准曲线法对南红玛瑙中剧毒元素As、Cd、Cr、Pb、Sb的含量进行测定。