简介:Tris)(η5-cyclopentadienyl-μ-carbonyl-iron)-μ3-nitrosylclusterwasobtainedfromthereactionofcyclopentadienyldicarbonylirondimerwithnitrogenmonoxideinxylene.Theclusterwascharacterizedbyelementalanalyses,IR,MSand1HNMR.Thecrystalstructureof[(η5-C5H5)(μ-CO)Fe]3(μ3-NO).C4H8OwasdeterminedbyX-raydiffractionanalysis.ItcrystallizesintheorthorhombicspacegroupPnma,a=9.053(2),6=10.545(2),c=22.525(4)A,V=2150.3(7)A3,Z=4,Dc=1.68g.cm-3;structuresolutionandrefinementbasedon1141reflectionswithI>3.0(I)(MoKa,A=0.71073A)convergedatR=0.0540.Theinfraredabsorptionbandat1325cm-1oftheμ3-NOinthecluster,whichisredshifted,showsthatμ3-NOisactivated.
简介:Linearpolysiloxaneswithpendantbenzo-15-crown-5moietieshavebeensynthesizedfrom3′-or4′-allylbenzo-15-C-5viahydrosilylationofmethyldichlorosilane,followedbypolycondensationwithsilanol-terminatedpolydimethylsiloxane.Itwasfoundthatthepolysiloxanescouldbeusedascarriersinbulkliquidmembranetotransportions.Factorsinfluencingtransportratehavebeeninvestigated.
简介:Ourobjectivesweretodevelopanewchemicalmethodforthepolymerizationofpyrrole.CuCl2dissolvedinC2H5OHsolventisprimarilyusedfortheinitiationpolymerizationofpyrrole.ThepolymerswithdifferentyieldandconductivitywereobtainedbyraringtheinitialconcentrationofCu2+.TheinitialconcentrationsofCu2+variedfrom1.2×10-4moleto6.48×10-3moleCu2+with2.16×10-2molepyrrole.Thepolypyrroleobtainedwascharacterizedwithelementalanalyzer,XPS,IRspectroscopy,Four-pointprobeandSEM.
简介:Halfsandwichirondicarbonylcomplex[η5-C5H3(t-Bu)2]Fe(CO)2Cl(1)reactswith1,2-dilithiumdiselenocarboraneLi2Se2C2B10H10(2)togiveabinuclearironcarboranecomplex[η5-C5H3(t-Bu)2]2Fe2(CO)3*Se2C2B10H10(3).TheX-raydiffractionanalysisofcomplex3revealsthatoneoftheironatomsischiral.
简介:ThehydrolysisofcephanoneinTritonX-100micelleandTritonX-100/n-C5H11OH/H2O(O/W)microemulsionwerestudiedbymeansofUV-Visabsorptionspectroscopy.Theresultsshowthatcomparedwithwater,TritonX-100micelleandTritonX-100/n-C5H11OH/H2O(O/W)microemulsioncaninhibitthehydrolysisofcephanone.TheinhibitioneffectsofTritonX-100micelleandTritonX-100/n-C5H11OH/H2O(O/W)microemulsiononthehydrolysisofcephanonearerelatedtothelocationofcephanoneintheinterphasesofTritonX-100micellesandTritonX-100/n-C5H11OH/H2O(O/W)microemulsiondroplets.
简介:Twooxo-vanadium(IV)complexes,[VO(C2O4)(2,2′-bipy)(H2O)]·C2H5OH(1)andVO(C2O4)(phen)(H2O)(2),where2,2′-bipy=2,2′-bipyridyl,phen=1,10-phenanthroline,weresynthesizedaspotentialfunctionalmodelsofvanadiumhaloperoxidases(VHPOs)inmixedsolventofethanolandwateratroomtemperature.Thecomplexeswerecharacterizedbyelementalanalysis,infrared(IR),UV-VisandX-raycrystallography.Structuralanalysesshowedthatvanadiumatomwascoordinatedbyaterminaloxygen,oneoxygenatomfromcoordinatedwater,twooxygenatomsfromthecarboxylategroupofoxalicacid,andtwonitrogenatoms(N1andN2)from2,2′-bipy/phen.Centralvanadiumatomsincomplexes1and2werebothinadistorted-octahedralenvironment,andsomeintermolecularhydrogenbondinglinkageswerealsoobservedineachcomplex.BrominationreactionactivityofthetwocomplexeswasevaluatedwithphenolredasorganicsubstrateinthepresenceofH2O2,Br-andphosphatebuffer,indicatingthattheycanbeconsideredasapotentialfunctionalmodelofVHPO.Inaddition,thermalanalysiswasalsoperformedanddiscussedindetail.
简介:定义了向量筐函数的C-Stieltjes近似可表示算子,并研究了它的性质。另外,我们定义了向量值函数的近似C-Stieltjes积分,并证明了它的收敛定理。
简介:Directconversionoffructose-basedcarbohydratesto5-ethoxymethylfurfural(EMF)catalyzedbyLewisacidinethanolwasinvestigated.ItwasfoundthatBF3(Et)2Owasfavorablefor5-hydroxymethylfurfural(HMF)etherificationtoEMF.BF3(Et)2OcombinationwithAlCl36H2Owiththemolarratioof1wasaneffectivecatalystsystemforsynthesisofEMFfromfructose-basedcarbohydrates.55.0%,45.4%and23.9%ofEMFyieldswereobtainedfromfructose,inulinandsucroseunderoptimizedconditions,respectively.
简介:IntroductionTherecentdiscoveryofaclassofcarboncontainingmoleculesknownasthefulereneshasproducedaseriesofmaterialswithawideran...
简介:ForagraphG,P(G,λ)denotesthechromaticpolynomialofG.TwographsGandHaresaidtobechromaticallyequivalent,denotedbyG-H,ifP(G,λ)=p(H,λ).Let[G]={H|H-G}.If[G]={G},thenGissaidtobechromaticallyunique.Foracomplete5-partitegraphGwith5nvertices,defineθ(G)=(a(G,6)-2^n+1-2^n-1+5)/2n-2,wherea(G,6)denotesthenumberof6-independentpartitionsofG.Inthispaper,theauthorsshowthatθ(G)≥0anddetermineallgraphswithθ(G)=0,1,2,5/2,7/2,4,17/4.Byusingtheseresultsthechromaticityof5-partitegraphsoftheformG-Swithθ(G)=0,1,2,5/2,7/2,4,17/4isinvestigated,whereSisasetofedgesofG.Manynewchromaticallyunique5-partitegraphsareobtained.
简介:Onenewsesquiterpenecompound,namely,illihenlactoneA(1),andonenewprenylatedC6–C3compound,illihenryioneH(2),alongwiththreeknownsesquiterpenes(3–5)wereisolatedfromthestemsofIlliciumhenryi.Thestructuresof1and2wereelucidatedbyspectroscopicevidenceincludingNMR,HRESIMSandcirculardichroism(CD).Compound2exhibitedaweakinhibitoryratioforbglucuronidasereleaseinducedbyplatelet-activatingfactor(PAF)inratpolymorphonuclearleukocytes(PMNs)invitro.