简介:Theadsorptionof2,4-dinitrophenoland2,6-dinitrophenolonnon-polarandpolaradsorbentswasstudied.TheresultsshowedthattheequilibriumadsorptiondidnotcomplywiththeLangmuirequationandwasnotmono-layeradsorption.ItisofinteresttonoticethattheeffectofpHontheadsorptionof2,4-or2,6-dinitrophenolontoADS-7andADS-21wasverysmall,Theresultisexplainedbyhydrogenbondinginteractionbetween2,4-or2,6-dinitrophenolandtheadsorbentADS-21.ThelargeadsorptioncapacityofdinitrophenolontoADS-21,whichwasabout500mg/gatanequilibriumconcentrationof400mg/L,andthesmalldinitrophenolleakageintheeffluentfromADS-21columnpresentedagoodprospectfortreatmentofwastewatercontainingdinitrophenolwithadsorbentADS-21.
简介:AmmoniumcanchangethetypeofnaturalclinoptilolitefromJinyunofZhejiangProvinceofChina.Thecharacterofexchangeandselectivityofammoniumtypeclinoptilolitetothealkaliandalkaline-earthmetalwereinvestigated,theheatresistanceandnitricacid-resistanceofnaturalclinoptilolitewerediscussed.AlltypesofclinoptilolitewereresearchedbymeansofX-ray,IRspectroscopy,DTAanalyses.Theionexchangewasexperimentedbycolumnoperation,indicatingthatthevalidamountofexchangecapacityofNH4^+typeclinoptilotiesismorethan25mg/g.
简介:TryptophanresiduesofIgGRFfromrheumatoidarthritispatientweremodifiedwithN-Bromosuccinimide(NBS)andtheproductofmodificationwascharacterizedbyUV-spectrum,FluorescenceemissionspectrumandCD-spectrum.ThecorrespondingadsorptioncapacityofimmobilizedssDNAimmunoadsorbentforIgGRFwasenhancedfrom46%to86%,ThisresultindicatesthetryptophanresidueisessentialfortheinteractionbetweenssDN,AandIgGRF.andionic-bondingplaysanimportantroleinadsorption.
简介:Polymersupportedalkyldimethylbenzylammoniumchlorideresindisinfectantusedforthedisinfectionofdrinkingwaterhasbeensynthesized,anditsantibacterialactivitieshavebeendetermined,comparedwiththecommerciallyusedtriiodinedisinfectantresin.Theresindisinfectantwasgeneratedsuccessfullywhenusethecombinationofsurfaceactiveagentsandultrosonic.
简介:PolymericGrignardReagent(PGR)basedonthechloromethylatedpoly(ST-co-DVB)resinhasbeenpreparedbymeansofanthracene-magnesiumcomplexinTHF(Anth-Mg-THF),andpolymermatrixwithlongpolymethylenespacerwassynthesizedviathecouplingreactionbetweenPGRandα,ω-dibromoalkanes.Basedonthestudiesoffactorsaffectingthecoupling,suchascatalyst,reactiontime,thelengthofspaceretc.,thispaperofferstheoptimalreactionconditionsandthreetypicalexperimentprocedures.ThemechanismfortheformationandcouplingreactionofPGRarealsodiscussed.
简介:Anovelbeadfromofploymerofhighsorptioncapacityforureawereobtainedbythereactionofglutaricdialdehydewithchitosandispersedinaceticacidsolution.Thesorptioncapacityreached-82.0mg/gsorbentat37℃andpH7.4Theconcentrationofureainthebuffersolutionwas1300mg/l.Thesorptionofureawasrelatedtothedegreeofcrosslinkingofthesorbent,concentrationofurea,ionicstrengthandtemperature.
简介:Anureaadsorbentwithanaldostructurewasobtainedbytheoxidationofacrosslinkedβ-cyclodextrinpolymer.Thehighestureaadsorptioncapacityreached56.7mg/gin0.05Maqueousphosphatebuffer37℃andpH=7.4,anddecreaseto4.8mg/gininaqueoushumanserumalbumin.Thecompositeadsorbentwaspreparedbytheoxidationofacrosslinkedβ-cyclodextrinanddialyticmembrane.Itwasfoundthatthecompositeadsorbenthasahigherureaadsorptionselectivityandcapacitycomparedtothatoftheoxidationofacrosslinkedβ-cyclodextrinadsorbentwhenureaisinaqueoushumanserumalbumin.
简介:MethodofVSC(VoltageShortedCompaction)canbeusedtodeterminetheintrinsictemperaturedependenceofconductivityofpolycrystallinecompaction.TheexperimentalconditionsandtechnicalkeyforpreparationofVSCdeviceanditsphysicalmodelaswellasitsapplicationsinconductingpolymersarediscussedindetail.
简介:Polyfluoroalkylsubstituted2-hydroxyethylacrylate6wassynthesizedinsixstepsusingglycerolasastartingmaterial.Apreliminaryinvestigationhasbeentakenonthesynthesisandcharacterizationofcopolymersof6and2-hydroxyethylmethacrylate.
简介:Inthispaper,thekineticmomentexpressionsandratelawsarederivedforpellicularionexchangematerialswithvariousgeometricalformsundertheconditionsthationexchangerateiscontrolledbyboththeparticaldiffusionandthefilmdiffusioninfinitesolutionvolume.Inaddition,forstrongacidiccationionexchangefibre,byusingtheequationsobtainedwecalculatedtheparticaldiffusioncoefficientsandthetransfercoefficientsinthefilmunderdifferentexperimentalconditions.
简介:有在170,180和190的温度从0.1wt%到1.0wt%的低过氧化物集中的高密度聚乙烯的Crosslinking反应
简介:Simultaneousfunctionalizationandreductionofgrapheneoxide(GO)isrealizedbyrefluxingofGOsuspensionwithpolyetheramine(D2000)followedbythermaltreatmentat120°C.ComparedtoGO,theD2000-treatedGO(GOD2000)becomeshydrophobic,thermallystableandhighlyconductivewithanelectricalconductivityof11S/m,whichisalmost8ordersofmagnitudehigherthanthatofGO.DuetothehighconductivityandimproveddispersionofGO-D2000,itsepoxynanocompositesexhibitasharptransitionfromelectricallyinsulatingtoconductingwithalowpercolationthresholdof0.71vol%.With3.6wt%GO-D2000,theglasstransitiontemperatureoftheepoxynanocompositeis27Khigherthanthatofneatepoxy.
简介:Anewtypeofseleniouspolymer,silica-boundpolybispropoxyethyl-selenidesilsesquioxane,anditsplatinumcomplexweresynthesizedfrombis-allyloxyethylselenideviahydrosily-lationwithtriethoxysilane,followedbyimmobilizedonfumedsilica,andthenreactingwithpotassiumchloroplatiniteundernitrogenatmosphereinacetone.Itwasfoundthattheplatinumcomplexcancatalyzethehydrosilylationofolefinswithtriethoxysilaneeffec-tivelyTheeffectsofthenatureofthesubstrate,theamountofcomplexused,andthereactiontemperatureonthecatalyticactivitywereinvestigated.