学科分类
/ 2
34 个结果
  • 简介:Theadsorptionof2,4-dinitrophenoland2,6-dinitrophenolonnon-polarandpolaradsorbentswasstudied.TheresultsshowedthattheequilibriumadsorptiondidnotcomplywiththeLangmuirequationandwasnotmono-layeradsorption.ItisofinteresttonoticethattheeffectofpHontheadsorptionof2,4-or2,6-dinitrophenolontoADS-7andADS-21wasverysmall,Theresultisexplainedbyhydrogenbondinginteractionbetween2,4-or2,6-dinitrophenolandtheadsorbentADS-21.ThelargeadsorptioncapacityofdinitrophenolontoADS-21,whichwasabout500mg/gatanequilibriumconcentrationof400mg/L,andthesmalldinitrophenolleakageintheeffluentfromADS-21columnpresentedagoodprospectfortreatmentofwastewatercontainingdinitrophenolwithadsorbentADS-21.

  • 标签: 聚合吸附剂 二硝基苯酚 吸收
  • 简介:N-nitrosaminesarestrongcarcinogensforhumans.Thispapergivesanoverviewofthenitrosmainesincigarettesmokeincludingtheformation,theharmfulness,theanalyticalmethodsofthenitrosmainesandtheadsorptionsanddegradationsofN-nitrosamines.

  • 标签: N-亚硝酸 烟草 解析方法 吸附降解
  • 简介:AmmoniumcanchangethetypeofnaturalclinoptilolitefromJinyunofZhejiangProvinceofChina.Thecharacterofexchangeandselectivityofammoniumtypeclinoptilolitetothealkaliandalkaline-earthmetalwereinvestigated,theheatresistanceandnitricacid-resistanceofnaturalclinoptilolitewerediscussed.AlltypesofclinoptilolitewereresearchedbymeansofX-ray,IRspectroscopy,DTAanalyses.Theionexchangewasexperimentedbycolumnoperation,indicatingthatthevalidamountofexchangecapacityofNH4^+typeclinoptilotiesismorethan25mg/g.

  • 标签: 离子交换 天然倾斜发光沸石 钾盐
  • 简介:TryptophanresiduesofIgGRFfromrheumatoidarthritispatientweremodifiedwithN-Bromosuccinimide(NBS)andtheproductofmodificationwascharacterizedbyUV-spectrum,FluorescenceemissionspectrumandCD-spectrum.ThecorrespondingadsorptioncapacityofimmobilizedssDNAimmunoadsorbentforIgGRFwasenhancedfrom46%to86%,ThisresultindicatesthetryptophanresidueisessentialfortheinteractionbetweenssDN,AandIgGRF.andionic-bondingplaysanimportantroleinadsorption.

  • 标签: 色氨酸残余 免疫免疫球蛋白G 吸附能力 类风湿因子 风湿性关节炎
  • 简介:PLAispresentlyconsideredasthemostattractivecompoundfortemporarytherapeuticapplicationinthebiomedicalfield.Inthispaperwegiveanoverviewofthepresentknowledgeonthedegradationbehavior,processingtechnologyofPLAanditsapplicationinthefixationofbonefracture.

  • 标签: 骨架材料 聚交酯 降解 骨折固定应用
  • 简介:Polymersupportedalkyldimethylbenzylammoniumchlorideresindisinfectantusedforthedisinfectionofdrinkingwaterhasbeensynthesized,anditsantibacterialactivitieshavebeendetermined,comparedwiththecommerciallyusedtriiodinedisinfectantresin.Theresindisinfectantwasgeneratedsuccessfullywhenusethecombinationofsurfaceactiveagentsandultrosonic.

  • 标签: 合成 消毒剂树脂 抗菌活性 季铵阳离子表面活性剂
  • 简介:PolymericGrignardReagent(PGR)basedonthechloromethylatedpoly(ST-co-DVB)resinhasbeenpreparedbymeansofanthracene-magnesiumcomplexinTHF(Anth-Mg-THF),andpolymermatrixwithlongpolymethylenespacerwassynthesizedviathecouplingreactionbetweenPGRandα,ω-dibromoalkanes.Basedonthestudiesoffactorsaffectingthecoupling,suchascatalyst,reactiontime,thelengthofspaceretc.,thispaperofferstheoptimalreactionconditionsandthreetypicalexperimentprocedures.ThemechanismfortheformationandcouplingreactionofPGRarealsodiscussed.

  • 标签: GRIGNARD REAGENT Polymer SUPPORTED Anthracene Coupling
  • 简介:Anovelbeadfromofploymerofhighsorptioncapacityforureawereobtainedbythereactionofglutaricdialdehydewithchitosandispersedinaceticacidsolution.Thesorptioncapacityreached-82.0mg/gsorbentat37℃andpH7.4Theconcentrationofureainthebuffersolutionwas1300mg/l.Thesorptionofureawasrelatedtothedegreeofcrosslinkingofthesorbent,concentrationofurea,ionicstrengthandtemperature.

  • 标签: 合成 交联壳聚糖 尿素分离
  • 简介:Anureaadsorbentwithanaldostructurewasobtainedbytheoxidationofacrosslinkedβ-cyclodextrinpolymer.Thehighestureaadsorptioncapacityreached56.7mg/gin0.05Maqueousphosphatebuffer37℃andpH=7.4,anddecreaseto4.8mg/gininaqueoushumanserumalbumin.Thecompositeadsorbentwaspreparedbytheoxidationofacrosslinkedβ-cyclodextrinanddialyticmembrane.Itwasfoundthatthecompositeadsorbenthasahigherureaadsorptionselectivityandcapacitycomparedtothatoftheoxidationofacrosslinkedβ-cyclodextrinadsorbentwhenureaisinaqueoushumanserumalbumin.

  • 标签: 聚合物 吸附 渗析膜
  • 简介:MethodofVSC(VoltageShortedCompaction)canbeusedtodeterminetheintrinsictemperaturedependenceofconductivityofpolycrystallinecompaction.TheexperimentalconditionsandtechnicalkeyforpreparationofVSCdeviceanditsphysicalmodelaswellasitsapplicationsinconductingpolymersarediscussedindetail.

  • 标签: silver PASTE terminals Probe INTRINSIC COMPACTION
  • 简介:Inthispaper,thekineticmomentexpressionsandratelawsarederivedforpellicularionexchangematerialswithvariousgeometricalformsundertheconditionsthationexchangerateiscontrolledbyboththeparticaldiffusionandthefilmdiffusioninfinitesolutionvolume.Inaddition,forstrongacidiccationionexchangefibre,byusingtheequationsobtainedwecalculatedtheparticaldiffusioncoefficientsandthetransfercoefficientsinthefilmunderdifferentexperimentalconditions.

  • 标签: 速率定律 矩量公式 薄膜离子交换物质
  • 简介:Simultaneousfunctionalizationandreductionofgrapheneoxide(GO)isrealizedbyrefluxingofGOsuspensionwithpolyetheramine(D2000)followedbythermaltreatmentat120°C.ComparedtoGO,theD2000-treatedGO(GOD2000)becomeshydrophobic,thermallystableandhighlyconductivewithanelectricalconductivityof11S/m,whichisalmost8ordersofmagnitudehigherthanthatofGO.DuetothehighconductivityandimproveddispersionofGO-D2000,itsepoxynanocompositesexhibitasharptransitionfromelectricallyinsulatingtoconductingwithalowpercolationthresholdof0.71vol%.With3.6wt%GO-D2000,theglasstransitiontemperatureoftheepoxynanocompositeis27Khigherthanthatofneatepoxy.

  • 标签: 环氧树脂 高导电性 氧化石墨 聚醚胺 还原 功能化
  • 简介:Anewtypeofseleniouspolymer,silica-boundpolybispropoxyethyl-selenidesilsesquioxane,anditsplatinumcomplexweresynthesizedfrombis-allyloxyethylselenideviahydrosily-lationwithtriethoxysilane,followedbyimmobilizedonfumedsilica,andthenreactingwithpotassiumchloroplatiniteundernitrogenatmosphereinacetone.Itwasfoundthattheplatinumcomplexcancatalyzethehydrosilylationofolefinswithtriethoxysilaneeffec-tivelyTheeffectsofthenatureofthesubstrate,theamountofcomplexused,andthereactiontemperatureonthecatalyticactivitywereinvestigated.

  • 标签: Selenaether PLATINUM HYDROSILYLATION CATALYST HYDROSILYLATION POLYSILOXANE