简介:Theinvestigationofelectrochromiceffectofcorona-polednonlinearopticalpolymerfilmsisaneffectivemethodfortheestimationofpolinglevelandtheselectionofpolingconditions.ThepolingelectricfieldEpandorientationalorderparameterΦ,whicharetheimportantparameterstopredictd33ofpoledfilms,canbecalculatedbyasimpleoperationfromthenumberofredshiftofchargetransferabsorptionband.Thecalculatedresultsareingoodagreementwiththeexperimentaldata.
简介:Thestructureandkineticsofthecomplexformedbyhyaluronicacid(HA)andpoly(L-lysine)(PLL)werestudiedbytimeresolvedlaserlightscattering,TEM,andAFM.BecauseHAhasahydrophilicbackbone,thecomplexesformedbyHAandPLLaredifferentfromthoseformedbyoppositelychargedpolyelectrolytesbothhavinghydrophobicbackbones.Insteadofformingstrongaggregatesandevenprecipitates,thecomplexinthepresenceofexcessHAisstableinthestudiedtimeperiod.Moreimportantly,thecomplexspontaneouslyformscore-coronastructurebytherearrangementofHAchains.ThecoreiscomposedofcomplexrichofPLLandthecoronaismainlyHA.FurtheranalysisshowsthatthehydrogenbondformedbyHAcreatesabarrierhinderingthefurtherrelaxationofHAchains.Theautomaticformationofcore-coronastructurebyPLL/HAishelpfulnotonlytounderstandtherelaxationofpolyelectrolyteincomplex,butalsotodevelopdrugcarrierswithdesirableproperties.