简介:Reactionof(MeC5H4)3LnwithHOCH2CH2NMe2intetrahydrofuran(THF)givesthenewcomplexes[(MeC5H4)2Ln(μ-OCH2CH2NMe2)]2(Ln=Sm,Y,Nd)withnitrogenfunctionalizedμ-alkoxideligand.ThecomplexeswerecharacterizedbyelementalanalysisandIR,and[(MeC5H4)2Sm(μ-OCH2CH2NMe2)]2wasstructurallycharacterizedbytheX-raydiffractiontobeadimerformedbytwounsymmetricoxygenbridges.ThecomplexhasatricyclicskeletonwiththeadditionaltwoSm-NbondsviaintramolecularcoordinationofOCH2CH2NMe2.ThecoordinationnumberofthecentralmetalSmisnine.Thetitlecomplexesshowgoodcatalyticactivityforring-openingpolymerizationofε-caprolactone.
简介:wurtziteZnO半导体的电子结构和磁性与稀土元素做了(RE=La,Ce,Pr,下午,Nd,Sm,Eu,Gd,Tb,Dy,惊讶,嗯,Tm和Yb)原子用极化纺纱的密度被学习功能的理论基于完整潜力的线性扩充飞机波浪(FP-LAPW)在Wien2k代码实现了的方法。在这条途径,概括坡度近似(GGA)被用于交换关联(XC)潜在。我们的结果证明在导致的ZnO的RE离子的替换在乐队差距旋转极化的局部性的状态。而且,学习数据管理系统混合物为大多数学习元素在掺杂物集中x=0.625%保留了半metallicity,与在费密水平的100%旋转极化(EF)。这些混合物的全部的磁性的时刻由于在EF,当小导致的磁性的时刻也在另外的无磁性的原子上存在时。最后,远、近的配置之间的精力差别被调查。房间温度强磁性为在近的配置的重新做的ZnO是可能的,这被发现。自从RE-RE分离,足够长(远配置)因为磁性的联合,系统变得顺磁或antiferromagnetic地面状态。
简介:F17以东矿山1172.5分段的回采工艺原设计为下向六角形高低进路胶结充填采矿法,随着矿山生产能力以及压力的逐年增大,按原六角形高低进路回采工艺,面临着诸如充填对采场进路回采进度限制、不能高效科用大型无轨设备等诸多问题。因此,1172.5分段采场回采工艺调整就显得非常必要。本文综合论述了下向水平进路回采工艺的优点,并对该方案与六角形高低进路回采工艺进行了比较。
简介:TheeffectsofUVAphotoirradiatedCe(Ⅳ)dopedTiO2nanoparticle(CDTP)onratcoloncarcinomacellline(C26)growth,cellcycledistribution,andmorphologywerestudiedbyMTTassay,FlowCytometry,andfluorescentstaining.Theresultsindicatethatabout64.6%cellsarekilledafter24hby180μg·ml-1CDTPwhen8minexposedtoUVA,over90%deadfor30mingroup,relativeto18.7%,41.5%ofTiO2atthesameconditionrespectively.Hoe33258stainingofthefixedcellsrevealstypicalapoptoticstructures(apoptoticbodies),andcellsarearrestedinG0/G1phase.
简介:ThereactionofNdCl3withlithiummethylnaphthalenein1:2moleratioinTHFgeneratesblackpowder.Thepowderreactswithcyclooctatetraene(COT)inTHFtoformthetitlecomplex.[Li(THF)4Nd(C8H8)2]·2THFcrystallizesinthemonoclinicspacegroupP2/cwithunit-celldimensionsa=1.7858(7)nm,h=1.3243(4)nm,c=1.8086(6)nm.β=106.52(4)°,V=4.10nm3andDc=1.268g/cm3forZ=4.F(000)=1660,R=0.0774,Rn=0.0733.Thecomplexconsistsofdiscreteion-pairandtwoTHFmoleculesadduct.Intheanion,theneodymiumatomiscoordinatedbytwoCOTrings.ThestructureofthecationshowsthatthelithiumatomisattachedwithTHFmoleculesonly.