简介：采用溶胶-凝胶法，以硝酸铁（Fe（NO3）3·9H2O）和钛酸丁酯（Ti（OBu）4）为原料制备出均匀透明的TiO2-Fe2O3复合异质结构光催化薄膜材料，并将其在不同温度下进行了热处理。利用原子力显微镜（AFM）、紫外-可见分光光度计对试样的表面形貌和透光率进行了表征。考察了不同组成、热处理制度和温度对材料光催化性能的影响，特别是对可见光区的光催化性能的影响，并对其光催化机理进行了探讨。结果表明：TiO2-Fe2O3复合异质结构光催化薄膜的光催化活性比纯TiO2结构薄膜有了明显提高．且向可见光波段偏移。

简介：采用碱熔处理样品，酸化后，移取部分溶液稀释后引入ICP测定ZrO2、TiO2、Fe2O3含量，剩余溶液用强碱分离钛、铁、锰等干扰元素后，EDTA—CuSO4法返滴定Al2O3，终点明显，检测重现性好；

简介：HighactiveandstablegoldcatalystssupportedoncrystallineFe2O3andCeO2/Fe2O3werepreparedviathedeposition-precipitationmethod.ThecatalystwithaAuloadof1.0%calcinedat180°CshowedaCOconversionof100%at-8.9°C,whileAu/CeO2/Fe2O3convertedCOcompletelyat-16.1°C.Evenhavingbeencalcinedat500°C,Au/Fe2O3stillexhibitedsignificantcatalyticactivity,achievingfullconversionofCOat61.6°C.ThecatalystwithalowAuloadof0.5%couldconvertCOcompletelyatroomtemperatureandkepttheactivityunchangedforatleast150h.N2adsorption-desorptionmeasurementsshowthatthecrystallinesupportspossessedahighspecificsurfaceareaofabout200m2/g.CharacterizationsofX-raydiffractionandtransmissionelectronmicroscopyindicatethatgoldspecieswerehighlydispersedasnanoorsub-nanoparticlesonthesupports.Evenafterthecatalystwascalcinedat500°C,theAuparticlesremainedinanano-sizeofabout6―10nm.X-rayphotoelectronspectrarevealthatthesupportedAuexistedinmetallicstateAu0.ThemodificationofAu/Fe2O3byCeO2provedtobebeneficialtotheinhibitionofcrystallizationofFe2O3andthestabilizationofgoldparticlesindispersedstate,consequentlypromotingcatalyticactivity.

简介：Inthispaper,varioustechniquesincludingBET,XRD,SEMandXPSwereusedtostudythesinteringofpureandLa2O3-dopedtitania.Theexperimentalresultsshowthatsinteringoftitaniaproceedsviavolumediffu-sion.Addingoflanthanumoxidedecreasestherateofsinteringandhindersthephasetransitionfromanatasetorutilecrystalbystrongsurfaceinteractionbetweenthemixedcrystals(La4Ti9O24,La0.66TiO2.99)andTiO2.

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简介：A60%Fe/Al2O3catalystwaspreparedbytheco-precipitationmethod.ItwasreducedbyH2toproducemetallicFe,whichwasthensulfidedbyCS2toFe0.96SandFe3S4orphosphidedbytriphenylphosphine(PPh3)inliquidphasestoFe2PandFeP.Itwasfoundthattheironsulfides(Fe0.96SandFe3S4)exhibitedthelowactivityforthehydrodesulfurization(HDS)reactions.TheHDSactivitywasalsolowontheFe(metal)/Al2O3andFe2P/Al2O3catalystssincetheywereconvertedintoFe0.96SandFe3S4duringtheHDSreactions.Incontrast,theFeP/Al2O3wasfoundtobestableandactivefortheHDSreactions.Inparticular,FeP/Al2O3possessedsignificantlysmallerFePparticlesthanFeP/C,leadingtothesignificanthigherHDSactivityofFeP/Al2O3thanFeP/C.

简介：Uniformlysizedα-Fe2O3hexagonalplateletsweresynthesizedbyahydrothermalprocessusingFe(OH)3suspensionandlargeamountofNaOH.ThereactionproductswerecharacterizedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM),transmissionelectronmicroscopy(TEM),selectedareaelectrondiffraction(SAED),andavibratingsamplemagnetometer(VSM).Theresultsshowthatthehexagonalplateletsarefine,monodisperseandconsistingofsingle-crystals.Themagnetichysteresis(M-H)curveofthesamplesmeasuredatroomtemperatureindicatesthattheα-Fe2O3micro-plateletsexhibitferromagneticbehaviorswithrelativelylowcoercivity.

简介：Inthisletter,Fe2O3UFP（UltrafineParticles）hydrosolandorganosolwithhighthirdorderopticalnonlinearsusceptibility（3）havebeenreportedforthefirsttime.ThesurfacialmodificationofFe2O3UFPwithdodecylbenzenesulfonateions（DBS）canenhancethenonlinearopticalresponsethroughinterfacialconfinementofelectronmotion.Theinvolvedmechanismisdiscussed.

简介：TheinfluenceofcalcinationtemperatureonTiO2nanotubes’catalysisforTiO2/UV/O3wasinvestigated.TiO2nanotubes(TNTs)werepreparedviathesol-gelmethodandcalcinedat300—700℃,whichwerelabeledasTNTs-300,TNTs-400,TNTs-500,TNTs-600andTNTs-700,respectively.TNTswerecharacterizedbytransmissionelectronmicroscopy(TEM)andX-raydiffraction(XRD).ItisfoundthatTNTscalcinedat400℃showedthebestthermalstability.Whenthecalcinationtemperatureincreasedfrom400℃to700℃,thespecialstructureoftubeswasdestroyedandgraduallyconvertedintonanorodsand/orparticles.Thetransformationfromanatasetorutileoccurredat600℃,andtherutilephasewasenhancedwhenthecalcinationtemperaturewasincreasedtoover600℃.Thecalcinationtemperature’sinfluenceonTNTs’adsorptionactivityforchemicaloxygendemand(COD)andcatalyticactivityforTiO2/UV/O3wasinvestigatedinlandfillleachatesolution.Inlandfillleachatesolution,theadsorptionactivityofCODdecreasedinthereducedorderofTNTs-300,TNTs-400,TNTs-500,TNTs-600andTNTs-700.Inphotocatalyticozonation,TNTs-400showedthebestcatalyticactivitywhileTNTs-700exhibitedtheworst.Inotherthreeprocesses,theCODremovalofTNTs-300/UV/O3washigherthanthoseofTNTs-500/UV/O3andTNTs-600/UV/O3inthefirst20min,andthenbecameclosetothoseofthelattertwointhefollowing40min.ComparedwithTNTs-300andTNTs-400,TNTs-600hadthebestanti-foulingactivity,whileTNTs-500andTNTs-700hadloweranti-foulingactivitythantheformerthree.Inphotocatalyticozonation,thecalcinationtemperatureof400℃wasappropriatewhenTNTswereobtainedatthesynthesistemperatureof105℃.

简介：随着原油的劣质化和环保法规的日益严格，传统的金属硫化物加氢精制催化剂已经不能满足人们对油品含硫、氮和芳烃的日益苛刻的要求，因此开发新型深度加氢精制催化剂成为一个非常具有挑战性的课题。本论文采用改进的溶胶-凝胶法制备的MoP/TiO2-Al2O3二元复合载体负载磷化钼，以喹啉为模型化合物，并在固定床反应器上对催化剂活性进行评价。

简介：TiO2@ZrO2@Y2O3:有coremultishell结构的Eu3+合成粒子通过layer-by-layer(LBL)的联合被综合自己组装方法和一个solgel过程。获得的样品与扫描电子被描绘显微镜学(SEM)，传播电子显微镜学(TEM)，X光检查光电子光谱学(XPS)，X光检查衍射(XRD)，和荧光spectrophotometry。结果证明合成粒子有coremultishell结构，球形的形态学，和狭窄的尺寸分布。TiO2核心上的ZrO2层的存在能有效地阻止在TiO2核心和Y2O3壳之间的反应；为在在TiO2@ZrO2@Y2O3的TiO2核心和Y2O3壳之间的反应的温度:Eucoremultishell黄磷能被300提高

简介：Theimplantedionrange,thedepthprofileandthefilmsttuctureoftheimplantedlayerwerestudied;thecarrierconcentrationandthemobilityweremeasured;theconductivitymechanismofthefilmimplantedFeintoAl2O3ceramicwasdiscussed.TheconclusionisthattheimplantedFe2+ionsmoveintoAl2O3latticeandreplaceAl3+toformsubs-titutionimpuritiessothattheionimplantedlat-tice,ascomparedwiththeoriginalone,presentsaneffectivenegativechargewhichformsanegativechargecenter.Avacancyisboundarroundit,andanacceptorisintroducedintheforbiddenband.

简介：一条很简单、可控制的途径被建议综合新奇Fe(哦)3/TiO2nanoparticles。与整洁的TiO2相比，Fe(哦)3/TiO2增加了相片的率在6.0在超过五预定的pH的甲基橘子的催化降级，出现相片象P25一样优秀的催化活动。这提高的效果主要被归因于电子scavenger和充实的表面氢氧根组织的铁的氢氧化物存款。

简介：铁磁性微晶玻璃由于具有磁性和生物活性，可以用作磁感应热疗的热种子材料。采用SiO2-Na2O-CaO-P2O5-Fe2O3五元系统，通过共沉淀-熔融法和熔融法两种不同的方法制备铁磁性微晶玻璃，利用XRD确定其晶相并计算晶体的晶格常数和晶粒尺寸，并通过VSM表征样品的磁性能。结果表明，玻璃液在自然冷却的过程中就形成了大量的磁铁矿，不经过热处理过程即可制得具有磁铁矿唯一晶相的铁磁性微晶玻璃并具有生物活性。共沉淀-熔融法制备的样品磁性更强。

简介：归纳了从钛铁矿中分离铁和二氧化钛的方法,包括亚熔盐法、预氧化法、还原锈蚀法;其次,初步总结了目前国内外制备Fe3O4磁性纳米颗粒和TiO2纳米粒子的方法。最后,对Fe3O4/TiO2复合材料的制备方法包括溶胶-凝胶法、微乳液法、均匀沉淀法作了梳理。Fe3O4/TiO2复合纳米材料很好地解决了单独使用TiO2作为废水处理催化剂,在实际应用过程中易随水流失,难以回收利用的问题,具有一定的实用性。

简介：Thenanosizedparticlematerialsofdoped-TiO2withY2O3werepreparedbymeansofsol-geltechniqueforuseinelectrorheological(ER)fluids,andtheircrystalstructuresweremeasuredbyX-raydiffraction(XRD)analysis.TocomparewiththepureTiO2,adistinctenhancementintheshearstressunderdcelectricfieldwasfoundbyusingsuchmaterials.Thiscanbeexplainedbytheincreaseofthedielectriclossanddielectricconstantatlowfrequency.TheeffectsofthecrystalstructureoftheparticlesonthedielectricpropertyandERperformanceofmaterialswereinvestigated.

简介：Basedonthedifferenceofhydroxygroupconfigurationondifferentplanesofα-Fe2O3nanoparticles,usingthespecialadsorptionandcoordinationofphosphateonthe(001)planeofα-Fe2O3,well-crystallizedandwelldispersedα-Fe2O3nanodiskswithdiameterof150–200nmandthicknessof40–80nmweresynthesizedviaahydrothermalmethod.Themagneticpropertiesofsynthesizednanodiskswereinvestigated.Itwasfoundthatthenanodiskspossessedasaturationmagnetization(Ms)of0.38emu/g,aremanentmagnetization(Mr)of0.031emu/gandacoercivityof452.91Oeatroomtemperature.TheMrandcoercivityofsynthesizedα-Fe2O3nanodisksarehigherandtheMsislowerthanthoseofotherpreviouslyreportedα-Fe2O3nanostructures.

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简介：Fe2O3/activecarbon(Fe2O3/AC)nanocompositeswerereadilyfabricatedbypyrolyzingFe3+impregnatedactivecarboninanitrogenatmosphere.Theas-preparedcompositeswerestudiedbyX-raypowderdiffraction(XRD),X-rayphotoelectronspectroscopy(XPS)andtransmissionelectronmicroscopy(TEM).Thecapacitivepropertyofthecompositeswasinvestigatedbycyclicvoltammetry(CV)andgalvanostaticcharge-dischargetest.Physicalcharacterizationsshowthattheγ-Fe2O3finegrainsdispersedintheACwell,withameansizeof21.24nm.Electrochemicaltestsin6mol/LKOHsolutionsindicatethattheas-preparednanocompositesexhibitedimprovedcapacitiveproperties.Thespecificcapacitance(SC)ofFe2O3/ACnanocompositeswasupto188.4F/gthatwasderivedfrombothelectrochemicaldouble-layercapacitanceandpseudo-capacitance,whichwas78%largerthanthatofpristineAC.AsymmetriccapacitorwithFe2O3/ACnanocompositesaselectrodeshowedanexcellentcyclingstability.TheSCwasonlyreducedbyafactorof9.2%after2000cyclesatacurrentdensityof1A/g.

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