简介:SlagcorrosionresistanceofMgOZrO2refractorieswasinvestigatedinthiswork.Theresultsindicatethatinanon-orientedelectricsteelslagsystemwithahighratioofcalciatosilica,theslagresistanceofMgOZrO2refractoriescanbedescribedasfollows:ZrO2reactswithCaOformingcalciumzirconatecompoundwhichstrengthensthematerialandblocksthechanneloftheslaginfiltration;however,inanorientedelectricsteelslagsystemwithahighconcentrationofsilicaandthelowratioofcalciatosilica,theslagcorrosionresistanceofMgOZrO2refractoriesisdifferent;ZrO2reactswithCaOformingthecalciumzirconateandsimultaneouslyonemoreproductC2Saswell;C2Scanimprovecorrosionresistancebyblindingporeandenhancingslagviscosity;therefore,itisexpectedtobethemajorreasonfortheenhancedcorrosionresistanceobservedforMgOZrO2refractories.
简介:Al2O3-MgOcastableshavebeenwidelyusedforworkingliningsofsteelladleduetotheirsuperiorhotstrengthandcorrosionresistance.Inthiswork,effectsofmicrosilica,ultrafinealuminaandMgOfinesadditionsontherheologicalbehaviorofthecastableswereinvestigatedbymeansofIBBrheometerV1.0tomeasuretorque(shearstress)undervaryingshearrates.Theresultsshowthatrheologicalpropertiesofcastablesatvaryingshearratesaresignificantlyimprovedwithincreaseofmicrosilicaadditions(from1mass%to5mass%)andcorrespondingdecreaseinwateraddition;thereisonlylittlechangeinrheologicalbehaviorwithvariationofultrafinealuminaandMgOfinesadditions.Optimumultrafinealuminaandmicrosilicaadditionsarerecommendedforcastableswithgoodrheologicalbehavior.
简介:Cr2O3canbesinteredwellat1500℃incarbon-embeddedconditionorH2atmosphere.Butthehighchromebearingrefractoriescannotreachdensificationwhensinteredat1700℃for10hinweakreducingatmosphereformedbythecombustionoffuel,anditsapparentporosityisabout18%.Thehighchromebearingrefractoriesaremainlyusedincoalgasifiers.Thetemperatureinthefurnaceisabout1500℃andtheproductsareH2andCO,whicharejustthesinteringconditionsofthedensechromerefractorieswithapparentporositylessthan10%.Thehighchromebearingrefractoriesusedincoalgasifiersmaybesinteredagainandthenshrink,destroyingthegasifierlining.Thethermodynamiccalculationshowsthatitissafeaboutthehighchromebearingrefractoriesusedingasifiers.Itisalsoexplainedthatthehighchromebearingrefractoriescan’tbesintereddenselyinweakreducingatmosphereformedbythecombustionoffuel.Thenewsinteringtechnologiescanbeusedtoimprovethebulkdensityofthehighchromebearingrefractories.