学科分类
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1 个结果
  • 简介:Electricalconductionbehaviorofpristineandiodinedopedpolyetherimides(PEI)hasbeeninvestigatedunderbothtransientandsteadystateconditionsintheoperatingtemperaturerange50-200℃atvariouselectricfieldsof12-60kV/cm.Thetransientcurrentsshowthehyperbolicdecaycharacter,andthedecayexponentp(ameasureofcurrentdecayrate)decreaseswithtemperature(7)anddopingconcentration.Theoriginoftransientcurrentshasbeenattributedtothedipolarnatureofcarbonyl((?)C=O)groupsandtheetherlinkagespresentinthemainchainofPEI.Thelowfieldsteadystateconductionisohmicinnature.Themagnitudesofionicjumpdistance(a)valuesdonotfavoranionictypeofconductionasapossibleconductionmechanisminpristineaswellasiodinedopedPEI.TheSchottkycoefficientsestimationsdonotshowthepossibilityofSchottkytypeorPoole-Frenkeltypeconductionmechanismsinthelowtemperatureregion(<120℃),however,inthehightemperatureregion(>120℃)thereisacertainpossibilityofPoole-Frenkeltypeconductionmechanisminbothpristineandiodinedopedsamples.Thedualslopeinthe1gIversus1/Tcurvesforiodinedopedsamplesindicatesthepresenceofmorethanonetypeoftrappinglevels.

  • 标签: 电输运性质 聚醚酰亚胺 碘掺杂 工作温度范围 传导机制 瞬态电流