GRAFTING OF POLY（SODIUM STYRENESULFONATE） ONTO GOLD SURFACE FROM NaNO3 SOLUTION-中国期刊网

摘要 Thechemicalgraftingofthiolterminatedpoly（sodiumstyrenesulfonate）（HS-PSSS）chainsfromsodiumnitrate（NaNO3）saltsolutiontoagoldsurfacewasinvestigatedwithaquartzcrystalmicrobalancewithdissipationmonitoring（QCM-D）indifferentsaltconcentrations.ItwasfoundthatatlowsaltconcentrationgraftingdensityofHS-PSSSwaslowandthegraftedchainsadoptedamushroomconformation.Withtheincreaseofsaltconcentrationpolyelectrolytechainsunderwentatransitiontowardcoiledstateduetoreductionofelectrostaticrepulsionandasaresultmorechainsweregraftedonthesurface.WhenthegraftingdensityreachedacertainlimitafterwhichfurthergraftingcausedrepulsionbetweenalreadygraftedHS-PSSSchainsandasaresultgraftedchainsadoptedabrushconformation.

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GRAFTING OF POLY（SODIUM STYRENESULFONATE） ONTO GOLD SURFACE FROM NaNO3 SOLUTION

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GRAFTING OF POLY（SODIUM STYRENESULFONATE） ONTO GOLD SURFACE FROM NaNO3 SOLUTION

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