Enantioselective hydrogenation of acetophenone by（1S,2S）-DPEN-Ru（Ⅱ）Cl_2（PPh_3）

摘要 Achiralrutheniumcomplex[(1S,2S)-DPEN]-RuCl_2(PPh_3)_2(DPEN=1,2-diphenylethylenediamine,PPh_3=triphenylphosphine)wasencapsulatedinthechannelofAl-MCM-41byelectrostaticadsorptionand1,1-dichlorosilacyclobutanemodification.Thepreparedheterogeneouscatalystshowedthesamecatalyticactivityandenantioselectivityasthecorrespondinghomogeneouscatalystintheasymmetrichydrogenationofacetophenone,andcouldbereusedatleastseventimeswithoutsignificantlossofcatalyticactivityandenantioselectivity.

1Wei Wei;Gao Shou-Bao;Sun Zhao-Peng;Song Yu-Zhi;Meng Qing-Tian. A typical slow reaction H（2S）＋ S2（X3∑g） → SH（X2П）＋S（3P） ona new surface： Quantum dynamics calculations.物理,2014-07.
2肖梦君,李娴,李林飞,谢振华,张耀东,张潺,李东晓,王江涛. 腓骨肌萎缩症2S型IGHMBP2基因变异1例.医药卫生,2022-12.
3何晓康;刘建鹏;张祥;沈咏;邹宏新. Forbidden transition properties of fine-structure 2p3 4S3/2-2p3 2Da/2,s/2 for nitrogen-like ions.物理,2018-08.
4作者：蒋勇 ,陈国梁. LF炉CaO-SiO2-Al2O3渣系脱S工艺实践.,2023-01.
5朱建国. 对位移公式S=1/2at2及S=V0t+1/2at2的新见解.教育学,2017-04.
6周峰. “s1＋s2=0”的妙用.教育学,2004-12.
7廖广睿;平荣刚;杨永栩. Helicity Amplitude Analysis of e^＋e^- ψ（2S） → γχcJ→γ∧∧^-→γpπ^-p^-π^＋＊.物理,2009-05.
8M. LASHKARIZADEH BAMI. Fourier Transforms of Bounded Bilinear Forms on C＊（S1）×C＊（S2） of Foundation ＊-semigroups S1 and S2.基础数学,2008-03.
9WangXiukun. Characterization of the Pharmacology of Recombinant Human GABAA Receptor Complexes Containing A2（α1 isoleucin 148 to valine） or A2（α1 asparatic acid 151 to asparagin） or A2 （α1 threonine 149 to glutamine） in Combination with β2γ2s Subu.药学,2001-01.
10林林;陈坤;王志芳;游宝贵;陈永虎;张慰萍;施朝淑. A white long-lasting phosphor Y2O2S： Tb^3＋ , Sm^3＋： an improvement of Y2O2S：Tb3＋.有色金属冶金,2008-05.

Enantioselective hydrogenation of acetophenone by（1S,2S）-DPEN-Ru（Ⅱ）Cl_2（PPh_3）_2 encapsulated in Al-MCM-41

来源期刊

相关推荐

同分类资源更多

相关关键词

Enantioselective hydrogenation of acetophenone by（1S,2S）-DPEN-Ru（Ⅱ）Cl_2（PPh_3）_2 encapsulated in Al-MCM-41

来源期刊

相关推荐

同分类资源 更多

相关关键词

同分类资源更多